Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral

Päivi Mäki-Arvela; Jyri-Pekka Mikkola; Pasi Virtanen; Hannu Karhu; Tapio Salmi; Dmitry Yu. Murzin

doi:10.1016/S0167-2991(06)80894-3

Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral

Päivi Mäki-Arvela^*, Jyri-Pekka Mikkola, Pasi Virtanen, Hannu Karhu, Tapio Salmi, Dmitry Yu. Murzin

^*Corresponding author for this work

Industrial Chemistry and Reaction Engineering

Research output: Chapter in Book/Conference proceeding › Chapter › Scientific › peer-review

3 Citations (Scopus)

Abstract

The synthesis, characterization and catalytic properties of an ionic liquid supported Pd (0.3 wt.%) catalyst (NB4MPy⁺BF^- ₄Pd (acac)/active charcoal) are discussed. The oxidation state of Pd in a fresh, reduced catalyst was corresponding to Pd^IV, whereas after three-phase citral hydrogenation it was close to Pd^II. Obtained results, including negligible Pd leaching, demonstrated the feasibility of stable ionic liquid supported Pd catalysts preparation, which can be applied in liquid phase hydrogenation reactions.

Original language	English
Title of host publication	Scientific Bases for the Preparation of Heterogeneous Catalysts
Editors	E. M. Gaigneaux, M. Devillers, D. E. De Vos, S. Hermans, P. A. Jacobs, J. A. Martens, P. Ruiz
Publisher	Elsevier
Pages	87-94
Number of pages	8
ISBN (Print)	044452827X, 978-0-444-52827-8
DOIs	https://doi.org/10.1016/S0167-2991(06)80894-3
Publication status	Published - 2006
MoE publication type	A3 Part of a book or another research book

Publication series

Name	Studies in Surface Science and Catalysis
Volume	162
ISSN (Print)	0167-2991

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Mäki-Arvela, P., Mikkola, J-P., Virtanen, P., Karhu, H., Salmi, T., & Murzin, D. Y. (2006). Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral. In E. M. Gaigneaux, M. Devillers, D. E. De Vos, S. Hermans, P. A. Jacobs, J. A. Martens, & P. Ruiz (Eds.), Scientific Bases for the Preparation of Heterogeneous Catalysts (pp. 87-94). (Studies in Surface Science and Catalysis; Vol. 162). Elsevier. https://doi.org/10.1016/S0167-2991(06)80894-3

Mäki-Arvela, Päivi ; Mikkola, Jyri-Pekka ; Virtanen, Pasi et al. / Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral. Scientific Bases for the Preparation of Heterogeneous Catalysts. editor / E. M. Gaigneaux ; M. Devillers ; D. E. De Vos ; S. Hermans ; P. A. Jacobs ; J. A. Martens ; P. Ruiz. Elsevier, 2006. pp. 87-94 (Studies in Surface Science and Catalysis).

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title = "Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral",

abstract = "The synthesis, characterization and catalytic properties of an ionic liquid supported Pd (0.3 wt.%) catalyst (NB4MPy+BF- 4Pd (acac)/active charcoal) are discussed. The oxidation state of Pd in a fresh, reduced catalyst was corresponding to PdIV, whereas after three-phase citral hydrogenation it was close to PdII. Obtained results, including negligible Pd leaching, demonstrated the feasibility of stable ionic liquid supported Pd catalysts preparation, which can be applied in liquid phase hydrogenation reactions.",

author = "P{\"a}ivi M{\"a}ki-Arvela and Jyri-Pekka Mikkola and Pasi Virtanen and Hannu Karhu and Tapio Salmi and Murzin, {Dmitry Yu.}",

year = "2006",

doi = "10.1016/S0167-2991(06)80894-3",

language = "English",

isbn = "044452827X",

series = "Studies in Surface Science and Catalysis",

publisher = "Elsevier",

pages = "87--94",

editor = "Gaigneaux, {E. M.} and M. Devillers and {De Vos}, {D. E.} and S. Hermans and Jacobs, {P. A.} and Martens, {J. A.} and P. Ruiz",

booktitle = "Scientific Bases for the Preparation of Heterogeneous Catalysts",

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Mäki-Arvela, P , Mikkola, J-P , Virtanen, P, Karhu, H, Salmi, T & Murzin, DY 2006, Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral. in EM Gaigneaux, M Devillers, DE De Vos, S Hermans, PA Jacobs, JA Martens & P Ruiz (eds), Scientific Bases for the Preparation of Heterogeneous Catalysts. Studies in Surface Science and Catalysis, vol. 162, Elsevier, pp. 87-94. https://doi.org/10.1016/S0167-2991(06)80894-3

Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral. / Mäki-Arvela, Päivi ; Mikkola, Jyri-Pekka ; Virtanen, Pasi et al.
Scientific Bases for the Preparation of Heterogeneous Catalysts. ed. / E. M. Gaigneaux; M. Devillers; D. E. De Vos; S. Hermans; P. A. Jacobs; J. A. Martens; P. Ruiz. Elsevier, 2006. p. 87-94 (Studies in Surface Science and Catalysis; Vol. 162).

Research output: Chapter in Book/Conference proceeding › Chapter › Scientific › peer-review

TY - CHAP

T1 - Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral

AU - Mäki-Arvela, Päivi

AU - Mikkola, Jyri-Pekka

AU - Virtanen, Pasi

AU - Karhu, Hannu

AU - Salmi, Tapio

AU - Murzin, Dmitry Yu.

PY - 2006

Y1 - 2006

N2 - The synthesis, characterization and catalytic properties of an ionic liquid supported Pd (0.3 wt.%) catalyst (NB4MPy+BF- 4Pd (acac)/active charcoal) are discussed. The oxidation state of Pd in a fresh, reduced catalyst was corresponding to PdIV, whereas after three-phase citral hydrogenation it was close to PdII. Obtained results, including negligible Pd leaching, demonstrated the feasibility of stable ionic liquid supported Pd catalysts preparation, which can be applied in liquid phase hydrogenation reactions.

AB - The synthesis, characterization and catalytic properties of an ionic liquid supported Pd (0.3 wt.%) catalyst (NB4MPy+BF- 4Pd (acac)/active charcoal) are discussed. The oxidation state of Pd in a fresh, reduced catalyst was corresponding to PdIV, whereas after three-phase citral hydrogenation it was close to PdII. Obtained results, including negligible Pd leaching, demonstrated the feasibility of stable ionic liquid supported Pd catalysts preparation, which can be applied in liquid phase hydrogenation reactions.

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U2 - 10.1016/S0167-2991(06)80894-3

DO - 10.1016/S0167-2991(06)80894-3

M3 - Chapter

AN - SCOPUS:35048886172

SN - 044452827X

SN - 978-0-444-52827-8

T3 - Studies in Surface Science and Catalysis

SP - 87

EP - 94

BT - Scientific Bases for the Preparation of Heterogeneous Catalysts

A2 - Gaigneaux, E. M.

A2 - Devillers, M.

A2 - De Vos, D. E.

A2 - Hermans, S.

A2 - Jacobs, P. A.

A2 - Martens, J. A.

A2 - Ruiz, P.

PB - Elsevier

ER -

Mäki-Arvela P , Mikkola J-P , Virtanen P, Karhu H, Salmi T , Murzin DY. Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral. In Gaigneaux EM, Devillers M, De Vos DE, Hermans S, Jacobs PA, Martens JA, Ruiz P, editors, Scientific Bases for the Preparation of Heterogeneous Catalysts. Elsevier. 2006. p. 87-94. (Studies in Surface Science and Catalysis). doi: 10.1016/S0167-2991(06)80894-3

Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral

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