Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral

Päivi Mäki-Arvela; Jyri Pekka Mikkola; Pasi Virtanen; Hannu Karhu; Tapio Salmi; Dmitry Yu Murzin

doi:10.1016/S0167-2991(06)80894-3

Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral

Päivi Mäki-Arvela^*, Jyri Pekka Mikkola, Pasi Virtanen, Hannu Karhu, Tapio Salmi, Dmitry Yu Murzin

^*Corresponding author for this work

Industrial Chemistry and Reaction Engineering

Research output: Chapter in Book/Conference proceeding › Chapter › Scientific › peer-review

8 Citations (Scopus)

Abstract

The synthesis, characterization and catalytic properties of an ionic liquid supported Pd (0.3 wt.%) catalyst (NB4MPy⁺BF^- ₄Pd (acac)/active charcoal) are discussed. The oxidation state of Pd in a fresh, reduced catalyst was corresponding to Pd^IV, whereas after three-phase citral hydrogenation it was close to Pd^II. Obtained results, including negligible Pd leaching, demonstrated the feasibility of stable ionic liquid supported Pd catalysts preparation, which can be applied in liquid phase hydrogenation reactions.

Original language	English
Title of host publication	Scientific Bases for the Preparation of Heterogeneous Catalysts
Publisher	Elsevier
Pages	87-94
Number of pages	8
ISBN (Print)	044452827X, 9780444528278
DOIs	https://doi.org/10.1016/S0167-2991(06)80894-3
Publication status	Published - 2006
MoE publication type	A3 Part of a book or another research book

Publication series

Name	Studies in Surface Science and Catalysis
Volume	162
ISSN (Print)	0167-2991

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10.1016/S0167-2991(06)80894-3

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abstract = "The synthesis, characterization and catalytic properties of an ionic liquid supported Pd (0.3 wt.%) catalyst (NB4MPy+BF- 4Pd (acac)/active charcoal) are discussed. The oxidation state of Pd in a fresh, reduced catalyst was corresponding to PdIV, whereas after three-phase citral hydrogenation it was close to PdII. Obtained results, including negligible Pd leaching, demonstrated the feasibility of stable ionic liquid supported Pd catalysts preparation, which can be applied in liquid phase hydrogenation reactions.",

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Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral. / Mäki-Arvela, Päivi ; Mikkola, Jyri Pekka ; Virtanen, Pasi; Karhu, Hannu; Salmi, Tapio ; Murzin, Dmitry Yu.

Scientific Bases for the Preparation of Heterogeneous Catalysts. Elsevier, 2006. p. 87-94 (Studies in Surface Science and Catalysis; Vol. 162).

Research output: Chapter in Book/Conference proceeding › Chapter › Scientific › peer-review

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AU - Salmi, Tapio

AU - Murzin, Dmitry Yu

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