Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral

Päivi Mäki-Arvela*, Jyri-Pekka Mikkola, Pasi Virtanen, Hannu Karhu, Tapio Salmi, Dmitry Yu. Murzin

*Corresponding author for this work

Research output: Chapter in Book/Conference proceedingChapterScientificpeer-review

8 Citations (Scopus)

Abstract

The synthesis, characterization and catalytic properties of an ionic liquid supported Pd (0.3 wt.%) catalyst (NB4MPy+BF- 4Pd (acac)/active charcoal) are discussed. The oxidation state of Pd in a fresh, reduced catalyst was corresponding to PdIV, whereas after three-phase citral hydrogenation it was close to PdII. Obtained results, including negligible Pd leaching, demonstrated the feasibility of stable ionic liquid supported Pd catalysts preparation, which can be applied in liquid phase hydrogenation reactions.

Original languageEnglish
Title of host publicationScientific Bases for the Preparation of Heterogeneous Catalysts
EditorsE. M. Gaigneaux, M. Devillers, D. E. De Vos, S. Hermans, P. A. Jacobs, J. A. Martens, P. Ruiz
PublisherElsevier
Pages87-94
Number of pages8
ISBN (Print)044452827X, 978-0-444-52827-8
DOIs
Publication statusPublished - 2006
MoE publication typeA3 Part of a book or another research book

Publication series

NameStudies in Surface Science and Catalysis
Volume162
ISSN (Print)0167-2991

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