TY - CHAP
T1 - Supported ionic liquid catalyst (SILCA) in the hydrogenation of citral
AU - Mäki-Arvela, Päivi
AU - Mikkola, Jyri Pekka
AU - Virtanen, Pasi
AU - Karhu, Hannu
AU - Salmi, Tapio
AU - Murzin, Dmitry Yu
N1 - Copyright:
Copyright 2018 Elsevier B.V., All rights reserved.
PY - 2006
Y1 - 2006
N2 - The synthesis, characterization and catalytic properties of an ionic liquid supported Pd (0.3 wt.%) catalyst (NB4MPy+BF- 4Pd (acac)/active charcoal) are discussed. The oxidation state of Pd in a fresh, reduced catalyst was corresponding to PdIV, whereas after three-phase citral hydrogenation it was close to PdII. Obtained results, including negligible Pd leaching, demonstrated the feasibility of stable ionic liquid supported Pd catalysts preparation, which can be applied in liquid phase hydrogenation reactions.
AB - The synthesis, characterization and catalytic properties of an ionic liquid supported Pd (0.3 wt.%) catalyst (NB4MPy+BF- 4Pd (acac)/active charcoal) are discussed. The oxidation state of Pd in a fresh, reduced catalyst was corresponding to PdIV, whereas after three-phase citral hydrogenation it was close to PdII. Obtained results, including negligible Pd leaching, demonstrated the feasibility of stable ionic liquid supported Pd catalysts preparation, which can be applied in liquid phase hydrogenation reactions.
UR - http://www.scopus.com/inward/record.url?scp=35048886172&partnerID=8YFLogxK
U2 - 10.1016/S0167-2991(06)80894-3
DO - 10.1016/S0167-2991(06)80894-3
M3 - Chapter
AN - SCOPUS:35048886172
SN - 044452827X
SN - 9780444528278
T3 - Studies in Surface Science and Catalysis
SP - 87
EP - 94
BT - Scientific Bases for the Preparation of Heterogeneous Catalysts
PB - Elsevier
ER -