Support effects in nerol hydrogenation over Pt/SiO2, Pt/H-Y and Pt/H-MCM-41 catalysts

Päivi Mäki-Arvela, Narendra Kumar, Ivo Paseka, Tapio Salmi, Dmitry Yu Murzin*

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

6 Citations (Scopus)

Abstract

Chemoselective hydrogenation of nerol was investigated over Pt/SiO 2, Pt/H-Y and Pt/H-MCM-41 catalysts. The initial total reaction rates decreased in following order:Pt/H-Y > Pt/SiO2 > Pt/H-MCM-41. Nerol hydrogenation was found to be an apparent structure sensitive reaction. The selectivities to citronellol at 30% conversion of nerol were 65%, 55% and 25% over Pt/SiO2, Pt/H-MCM-41 and Pt/H-Y, respectively.

Original languageEnglish
Pages (from-to)173-179
Number of pages7
JournalCatalysis Letters
Volume98
Issue number4
DOIs
Publication statusPublished - Dec 2004
MoE publication typeA1 Journal article-refereed

Keywords

  • H-MCM-41
  • Hydrogenation
  • Kinetics
  • Nerol
  • Pt
  • Selectivity

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