Support effects in nerol hydrogenation over Pt/SiO2, Pt/H-Y and Pt/H-MCM-41 catalysts

Päivi Mäki-Arvela; Narendra Kumar; Ivo Paseka; Tapio Salmi; Dmitry Yu Murzin

doi:10.1007/s10562-004-8677-y

Support effects in nerol hydrogenation over Pt/SiO₂, Pt/H-Y and Pt/H-MCM-41 catalysts

Päivi Mäki-Arvela, Narendra Kumar, Ivo Paseka, Tapio Salmi, Dmitry Yu Murzin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

6 Citations (Scopus)

Abstract

Chemoselective hydrogenation of nerol was investigated over Pt/SiO ₂, Pt/H-Y and Pt/H-MCM-41 catalysts. The initial total reaction rates decreased in following order:Pt/H-Y > Pt/SiO₂ > Pt/H-MCM-41. Nerol hydrogenation was found to be an apparent structure sensitive reaction. The selectivities to citronellol at 30% conversion of nerol were 65%, 55% and 25% over Pt/SiO₂, Pt/H-MCM-41 and Pt/H-Y, respectively.

Original language	English
Pages (from-to)	173-179
Number of pages	7
Journal	Catalysis Letters
Volume	98
Issue number	4
DOIs	https://doi.org/10.1007/s10562-004-8677-y
Publication status	Published - Dec 2004
MoE publication type	A1 Journal article-refereed

Keywords

H-MCM-41
Hydrogenation
Kinetics
Nerol
Pt
Selectivity

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10.1007/s10562-004-8677-y

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@article{fdca413172c642179ced8a893a421879,

title = "Support effects in nerol hydrogenation over Pt/SiO2, Pt/H-Y and Pt/H-MCM-41 catalysts",

abstract = "Chemoselective hydrogenation of nerol was investigated over Pt/SiO 2, Pt/H-Y and Pt/H-MCM-41 catalysts. The initial total reaction rates decreased in following order:Pt/H-Y > Pt/SiO2 > Pt/H-MCM-41. Nerol hydrogenation was found to be an apparent structure sensitive reaction. The selectivities to citronellol at 30% conversion of nerol were 65%, 55% and 25% over Pt/SiO2, Pt/H-MCM-41 and Pt/H-Y, respectively.",

keywords = "H-MCM-41, Hydrogenation, Kinetics, Nerol, Pt, Selectivity",

author = "P{\"a}ivi M{\"a}ki-Arvela and Narendra Kumar and Ivo Paseka and Tapio Salmi and Murzin, {Dmitry Yu}",

note = "Funding Information: This work is part of the activities at the {\AA}bo Akademi Process Chemistry Centre within the Finnish Centre of Excellence Programme (2000–2005) by the Academy of Finland. Authors are grateful to Mr. Markku Reunanen ({\AA}ba Akademi) for the MS analysis and to Mr. Teemu Heikkil{\"a}, University of Turku for XRD measurements. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.",

year = "2004",

month = dec,

doi = "10.1007/s10562-004-8677-y",

language = "English",

volume = "98",

pages = "173--179",

journal = "Catalysis Letters",

issn = "1011-372X",

publisher = "Springer",

number = "4",

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TY - JOUR

T1 - Support effects in nerol hydrogenation over Pt/SiO2, Pt/H-Y and Pt/H-MCM-41 catalysts

AU - Mäki-Arvela, Päivi

AU - Kumar, Narendra

AU - Paseka, Ivo

AU - Salmi, Tapio

AU - Murzin, Dmitry Yu

N1 - Funding Information: This work is part of the activities at the Åbo Akademi Process Chemistry Centre within the Finnish Centre of Excellence Programme (2000–2005) by the Academy of Finland. Authors are grateful to Mr. Markku Reunanen (Åba Akademi) for the MS analysis and to Mr. Teemu Heikkilä, University of Turku for XRD measurements. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.

PY - 2004/12

Y1 - 2004/12

N2 - Chemoselective hydrogenation of nerol was investigated over Pt/SiO 2, Pt/H-Y and Pt/H-MCM-41 catalysts. The initial total reaction rates decreased in following order:Pt/H-Y > Pt/SiO2 > Pt/H-MCM-41. Nerol hydrogenation was found to be an apparent structure sensitive reaction. The selectivities to citronellol at 30% conversion of nerol were 65%, 55% and 25% over Pt/SiO2, Pt/H-MCM-41 and Pt/H-Y, respectively.

AB - Chemoselective hydrogenation of nerol was investigated over Pt/SiO 2, Pt/H-Y and Pt/H-MCM-41 catalysts. The initial total reaction rates decreased in following order:Pt/H-Y > Pt/SiO2 > Pt/H-MCM-41. Nerol hydrogenation was found to be an apparent structure sensitive reaction. The selectivities to citronellol at 30% conversion of nerol were 65%, 55% and 25% over Pt/SiO2, Pt/H-MCM-41 and Pt/H-Y, respectively.

KW - H-MCM-41

KW - Hydrogenation

KW - Kinetics

KW - Nerol

KW - Pt

KW - Selectivity

UR - http://www.scopus.com/inward/record.url?scp=10444286684&partnerID=8YFLogxK

U2 - 10.1007/s10562-004-8677-y

DO - 10.1007/s10562-004-8677-y

M3 - Article

AN - SCOPUS:10444286684

SN - 1011-372X

VL - 98

SP - 173

EP - 179

JO - Catalysis Letters

JF - Catalysis Letters

IS - 4

ER -

Support effects in nerol hydrogenation over Pt/SiO₂, Pt/H-Y and Pt/H-MCM-41 catalysts

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Keywords

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