Stability of hydrogen peroxide during perhydrolysis of carboxylic acids on acidic heterogeneous catalysts

Sébastien Leveneur; Narendra Kumar; Tapio Salmi; Dmitry Yu Murzin

doi:10.1007/s11164-010-0149-y

Stability of hydrogen peroxide during perhydrolysis of carboxylic acids on acidic heterogeneous catalysts

Sébastien Leveneur^*, Narendra Kumar, Tapio Salmi, Dmitry Yu Murzin

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

6 Citations (Scopus)

Abstract

This paper describes a study of the stability of hydrogen peroxide in the presence of different aluminosilicate materials, in connection with an investigation of carboxylic acid perhydrolysis. During the reaction, aluminosilicate materials such as H-β zeolites, mesoporous material H-MCM-41 and alumina initiate the decomposition of hydrogen peroxide. The reason of the spontaneous decomposition of H₂O₂ is related to the partial dealumination of these zeolites. However, in the case of experiments carried out with H-ZSM-5 zeolite catalysts, a slight catalytic effect on the perhydrolysis and no spontaneous decomposition of hydrogen peroxide were noticed. The use of cation exchange resins as catalysts is more kinetically beneficial than H-ZSM-5 zeolite catalysts.

Original language	English
Pages (from-to)	389-401
Number of pages	13
Journal	Research on Chemical Intermediates
Volume	36
Issue number	4
DOIs	https://doi.org/10.1007/s11164-010-0149-y
Publication status	Published - Jun 2010
MoE publication type	A1 Journal article-refereed

Funding

Acknowledgements The financial support from the Åbo Akademi Forskningsinstitut and the Finnish Graduate School in Chemical Engineering (GSCE) are gratefully acknowledged. This work is part of the activities at the Åbo Akademi Process Chemistry Centre (PCC) within the Finnish Centre of Excellence Programme (2006–2011) by the Academy of Finland.

Keywords

Aluminosilicate materials
Decomposition
Hydrogen peroxide
Perhydrolysis

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title = "Stability of hydrogen peroxide during perhydrolysis of carboxylic acids on acidic heterogeneous catalysts",

abstract = "This paper describes a study of the stability of hydrogen peroxide in the presence of different aluminosilicate materials, in connection with an investigation of carboxylic acid perhydrolysis. During the reaction, aluminosilicate materials such as H-β zeolites, mesoporous material H-MCM-41 and alumina initiate the decomposition of hydrogen peroxide. The reason of the spontaneous decomposition of H2O2 is related to the partial dealumination of these zeolites. However, in the case of experiments carried out with H-ZSM-5 zeolite catalysts, a slight catalytic effect on the perhydrolysis and no spontaneous decomposition of hydrogen peroxide were noticed. The use of cation exchange resins as catalysts is more kinetically beneficial than H-ZSM-5 zeolite catalysts.",

keywords = "Aluminosilicate materials, Decomposition, Hydrogen peroxide, Perhydrolysis",

author = "S{\'e}bastien Leveneur and Narendra Kumar and Tapio Salmi and Murzin, \{Dmitry Yu\}",

note = "Funding Information: Acknowledgements The financial support from the {\AA}bo Akademi Forskningsinstitut and the Finnish Graduate School in Chemical Engineering (GSCE) are gratefully acknowledged. This work is part of the activities at the {\AA}bo Akademi Process Chemistry Centre (PCC) within the Finnish Centre of Excellence Programme (2006–2011) by the Academy of Finland. Copyright: Copyright 2010 Elsevier B.V., All rights reserved.",

year = "2010",

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doi = "10.1007/s11164-010-0149-y",

language = "English",

volume = "36",

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AU - Leveneur, Sébastien

AU - Kumar, Narendra

AU - Salmi, Tapio

AU - Murzin, Dmitry Yu

N1 - Funding Information: Acknowledgements The financial support from the Åbo Akademi Forskningsinstitut and the Finnish Graduate School in Chemical Engineering (GSCE) are gratefully acknowledged. This work is part of the activities at the Åbo Akademi Process Chemistry Centre (PCC) within the Finnish Centre of Excellence Programme (2006–2011) by the Academy of Finland. Copyright: Copyright 2010 Elsevier B.V., All rights reserved.

PY - 2010/6

Y1 - 2010/6

N2 - This paper describes a study of the stability of hydrogen peroxide in the presence of different aluminosilicate materials, in connection with an investigation of carboxylic acid perhydrolysis. During the reaction, aluminosilicate materials such as H-β zeolites, mesoporous material H-MCM-41 and alumina initiate the decomposition of hydrogen peroxide. The reason of the spontaneous decomposition of H2O2 is related to the partial dealumination of these zeolites. However, in the case of experiments carried out with H-ZSM-5 zeolite catalysts, a slight catalytic effect on the perhydrolysis and no spontaneous decomposition of hydrogen peroxide were noticed. The use of cation exchange resins as catalysts is more kinetically beneficial than H-ZSM-5 zeolite catalysts.

AB - This paper describes a study of the stability of hydrogen peroxide in the presence of different aluminosilicate materials, in connection with an investigation of carboxylic acid perhydrolysis. During the reaction, aluminosilicate materials such as H-β zeolites, mesoporous material H-MCM-41 and alumina initiate the decomposition of hydrogen peroxide. The reason of the spontaneous decomposition of H2O2 is related to the partial dealumination of these zeolites. However, in the case of experiments carried out with H-ZSM-5 zeolite catalysts, a slight catalytic effect on the perhydrolysis and no spontaneous decomposition of hydrogen peroxide were noticed. The use of cation exchange resins as catalysts is more kinetically beneficial than H-ZSM-5 zeolite catalysts.

KW - Aluminosilicate materials

KW - Decomposition

KW - Hydrogen peroxide

KW - Perhydrolysis

UR - https://www.scopus.com/pages/publications/77955853820

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DO - 10.1007/s11164-010-0149-y

M3 - Article

AN - SCOPUS:77955853820

SN - 0922-6168

VL - 36

SP - 389

EP - 401

JO - Research on Chemical Intermediates

JF - Research on Chemical Intermediates

IS - 4

ER -

Stability of hydrogen peroxide during perhydrolysis of carboxylic acids on acidic heterogeneous catalysts

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Keywords

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