Specific electrocatalytic oxidation of cellulose at carbon electrodes modified by gold nanoparticles

Yasuhito Sugano; Narendra Kumar; Markus Peurla; Jorma Roine; Atte Aho; Johan Bobacka; Jyri-Pekka Mikkola

doi:10.1002/cctc.201600190

Specific electrocatalytic oxidation of cellulose at carbon electrodes modified by gold nanoparticles

Yasuhito Sugano, Narendra Kumar, Markus Peurla, Jorma Roine, Atte Aho, Johan Bobacka, Jyri-Pekka Mikkola

Research output: Contribution to journal › Article › Scientific › peer-review

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Abstract

The influence of the size and oxidation state of Au nanoparticles (AuNPs) as electrocatalysts for the electro-oxidation of cellulose was studied. Carbon paper electrodes modified with AuNPs were used as the electrocatalysts for the electro-oxidation of cellulose dissolved in 1.3 m NaOH. The size and oxidation state of the AuNPs were determined by using SEM, TEM, and X-ray photoelectron spectroscopy. Both the size and the oxidation state of the AuNPs were found to influence the electrocatalytic properties of the electrode, as studied by using cyclic voltammetry, square wave voltammetry, and electrochemical impedance spectroscopy. The carbon paper electrodes decorated with AuNPs (less than 25 nm) that consist of metallic Au gave rise to a significantly higher electrocatalytic activity than a bare polycrystalline Au electrode.

Original language	Undefined/Unknown
Pages (from-to)	2401–2405
Journal	ChemCatChem
Volume	8
Issue number	14
DOIs	https://doi.org/10.1002/cctc.201600190
Publication status	Published - 2016
MoE publication type	A1 Journal article-refereed

Keywords

engineering education

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10.1002/cctc.201600190

http://onlinelibrary.wiley.com/doi/10.1002/cctc.201600190/abstract

Cite this

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title = "Specific electrocatalytic oxidation of cellulose at carbon electrodes modified by gold nanoparticles",

abstract = "The influence of the size and oxidation state of Au nanoparticles (AuNPs) as electrocatalysts for the electro-oxidation of cellulose was studied. Carbon paper electrodes modified with AuNPs were used as the electrocatalysts for the electro-oxidation of cellulose dissolved in 1.3 m NaOH. The size and oxidation state of the AuNPs were determined by using SEM, TEM, and X-ray photoelectron spectroscopy. Both the size and the oxidation state of the AuNPs were found to influence the electrocatalytic properties of the electrode, as studied by using cyclic voltammetry, square wave voltammetry, and electrochemical impedance spectroscopy. The carbon paper electrodes decorated with AuNPs (less than 25 nm) that consist of metallic Au gave rise to a significantly higher electrocatalytic activity than a bare polycrystalline Au electrode.",

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AU - Sugano, Yasuhito

AU - Kumar, Narendra

AU - Peurla, Markus

AU - Roine, Jorma

AU - Aho, Atte

AU - Bobacka, Johan

AU - Mikkola, Jyri-Pekka

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N2 - The influence of the size and oxidation state of Au nanoparticles (AuNPs) as electrocatalysts for the electro-oxidation of cellulose was studied. Carbon paper electrodes modified with AuNPs were used as the electrocatalysts for the electro-oxidation of cellulose dissolved in 1.3 m NaOH. The size and oxidation state of the AuNPs were determined by using SEM, TEM, and X-ray photoelectron spectroscopy. Both the size and the oxidation state of the AuNPs were found to influence the electrocatalytic properties of the electrode, as studied by using cyclic voltammetry, square wave voltammetry, and electrochemical impedance spectroscopy. The carbon paper electrodes decorated with AuNPs (less than 25 nm) that consist of metallic Au gave rise to a significantly higher electrocatalytic activity than a bare polycrystalline Au electrode.

AB - The influence of the size and oxidation state of Au nanoparticles (AuNPs) as electrocatalysts for the electro-oxidation of cellulose was studied. Carbon paper electrodes modified with AuNPs were used as the electrocatalysts for the electro-oxidation of cellulose dissolved in 1.3 m NaOH. The size and oxidation state of the AuNPs were determined by using SEM, TEM, and X-ray photoelectron spectroscopy. Both the size and the oxidation state of the AuNPs were found to influence the electrocatalytic properties of the electrode, as studied by using cyclic voltammetry, square wave voltammetry, and electrochemical impedance spectroscopy. The carbon paper electrodes decorated with AuNPs (less than 25 nm) that consist of metallic Au gave rise to a significantly higher electrocatalytic activity than a bare polycrystalline Au electrode.

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