Abstract
Thioamide derivatives of p-tert-butylcalix[4]arene were used as ionophores in the development of solid-contact ion-selective electrodes based on conducting polymer poly(3,4-ethylenedioxythiophene)/polystyrene sulfonate (PEDOT/PSS) which was synthesized by electrodeposition on the glassy carbon electrodes. The typical ion-selective membranes with optionally two different plasticizers [bis(2-ethylhexyl)sebacate (DOS) and 2-nitrophenyl octyl ether (NPOE)] were investigated. The potentiometric selectivity coefficients were determined by separate solution method (SSM) for Pb2+ over Cu2+, Cd2+, Ca2+, Na+, and K+. High selectivity toward Pb2+ was obtained. By applying two conditioning protocols, a low detection limit log(a(DL)) approximate to -9 was achieved. The fabricated ion-selective electrodes were used to determine Pb2+ concentration in environmental samples. The obtained results were compared to analysis done by inductively coupled plasma mass spectrometry (ICPMS).
Original language | Undefined/Unknown |
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Pages (from-to) | 1555–1561 |
Number of pages | 7 |
Journal | Analytical Chemistry |
Volume | 85 |
Issue number | 3 |
DOIs | |
Publication status | Published - 2013 |
MoE publication type | A1 Journal article-refereed |