Short overview on the application of metal-modified molecular sieves in selective hydrogenation of cinnamaldehyde

Jan Hájek; Narendra Kumar; Tapio Salmi; Dmitry Yu Murzin

doi:10.1016/j.cattod.2004.11.003

Short overview on the application of metal-modified molecular sieves in selective hydrogenation of cinnamaldehyde

Jan Hájek^*, Narendra Kumar, Tapio Salmi, Dmitry Yu Murzin

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

10 Citations (Scopus)

Abstract

This article shortly overviews our recent work on the application of metal supported molecular sieve catalysts in liquid-phase hydrogenation of cinnamaldehyde. The topic covers catalyst deactivation, influence of the support, active metals as well as the influence of reaction conditions on catalytic performance. Acquired results demonstrate superior performance of microporous supports (zeolites) compared to mesoporous MCM-41, which was relatively unselective and less active. At optimised conditions, selectivity towards cinnamylalcohol of about 60-70% and reasonable activity were achieved.

Original language	English
Pages (from-to)	349-353
Number of pages	5
Journal	Catalysis Today
Volume	100
Issue number	3-4
DOIs	https://doi.org/10.1016/j.cattod.2004.11.003
Publication status	Published - 28 Feb 2005
MoE publication type	A1 Journal article-refereed

Keywords

Cinnamaldehyde hydrogenation
Cinnamylalcohol
Zeolite catalysts

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10.1016/j.cattod.2004.11.003

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title = "Short overview on the application of metal-modified molecular sieves in selective hydrogenation of cinnamaldehyde",

abstract = "This article shortly overviews our recent work on the application of metal supported molecular sieve catalysts in liquid-phase hydrogenation of cinnamaldehyde. The topic covers catalyst deactivation, influence of the support, active metals as well as the influence of reaction conditions on catalytic performance. Acquired results demonstrate superior performance of microporous supports (zeolites) compared to mesoporous MCM-41, which was relatively unselective and less active. At optimised conditions, selectivity towards cinnamylalcohol of about 60-70% and reasonable activity were achieved.",

keywords = "Cinnamaldehyde hydrogenation, Cinnamylalcohol, Zeolite catalysts",

author = "Jan H{\'a}jek and Narendra Kumar and Tapio Salmi and Murzin, {Dmitry Yu}",

note = "Funding Information: This work is a part of the Process Chemistry Centre activities within the Finnish Academy Centre of Excellence Program (2000–2005). The support given by the Finnish Graduate School of Chemical Engineering is gratefully acknowledged. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.",

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AU - Murzin, Dmitry Yu

N1 - Funding Information: This work is a part of the Process Chemistry Centre activities within the Finnish Academy Centre of Excellence Program (2000–2005). The support given by the Finnish Graduate School of Chemical Engineering is gratefully acknowledged. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.

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AB - This article shortly overviews our recent work on the application of metal supported molecular sieve catalysts in liquid-phase hydrogenation of cinnamaldehyde. The topic covers catalyst deactivation, influence of the support, active metals as well as the influence of reaction conditions on catalytic performance. Acquired results demonstrate superior performance of microporous supports (zeolites) compared to mesoporous MCM-41, which was relatively unselective and less active. At optimised conditions, selectivity towards cinnamylalcohol of about 60-70% and reasonable activity were achieved.

KW - Cinnamaldehyde hydrogenation

KW - Cinnamylalcohol

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ER -

Short overview on the application of metal-modified molecular sieves in selective hydrogenation of cinnamaldehyde

Abstract

Keywords

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