Selective dimerization of cyclohexene over a Re2O7-B2O3/Al2O3 catalyst under mild conditions

Alexander A.  Greish; Alexandra P.  Barkova; Elena D.  Finashina; Tapio Salmi; Leonid M.  Kustov

doi:10.1016/j.mcat.2021.111398

Selective dimerization of cyclohexene over a Re₂O₇-B₂O₃/Al₂O₃ catalyst under mild conditions

Alexander A. Greish, Alexandra P. Barkova, Elena D. Finashina, Tapio Salmi, Leonid M. Kustov

Industrial Chemistry and Reaction Engineering

Research output: Contribution to journal › Article › Scientific › peer-review

Abstract

A Re2O7-B2O3/Al2O3 catalyst was demonstrated to reveal significant activity in cyclohexene dimerization into 1-cyclohexenylcyclohexane with a total yield of 95 % and a selectivity close to 100 % in the batch mode at 75−80°C and atmospheric pressure.

Original language	English
Article number	111398
Number of pages	5
Journal	Molecular Catalysis
Volume	502
DOIs	https://doi.org/10.1016/j.mcat.2021.111398
Publication status	Published - Feb 2021
MoE publication type	A1 Journal article-refereed

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10.1016/j.mcat.2021.111398

https://www.sciencedirect.com/science/article/pii/S2468823121000158

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@article{63334f56e7c646a893d039ea95fe43f6,

title = "Selective dimerization of cyclohexene over a Re2O7-B2O3/Al2O3 catalyst under mild conditions",

abstract = "A Re2O7-B2O3/Al2O3 catalyst was demonstrated to reveal significant activity in cyclohexene dimerization into 1-cyclohexenylcyclohexane with a total yield of 95 % and a selectivity close to 100 % in the batch mode at 75−80°C and atmospheric pressure.",

author = "Greish, {Alexander A.} and Barkova, {Alexandra P.} and Finashina, {Elena D.} and Tapio Salmi and Kustov, {Leonid M.}",

year = "2021",

month = feb,

doi = "10.1016/j.mcat.2021.111398",

language = "English",

volume = "502",

journal = "Molecular Catalysis",

issn = "2468-8231",

publisher = "Elsevier",

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T1 - Selective dimerization of cyclohexene over a Re2O7-B2O3/Al2O3 catalyst under mild conditions

AU - Greish, Alexander A.

AU - Barkova, Alexandra P.

AU - Finashina, Elena D.

AU - Salmi, Tapio

AU - Kustov, Leonid M.

PY - 2021/2

Y1 - 2021/2

N2 - A Re2O7-B2O3/Al2O3 catalyst was demonstrated to reveal significant activity in cyclohexene dimerization into 1-cyclohexenylcyclohexane with a total yield of 95 % and a selectivity close to 100 % in the batch mode at 75−80°C and atmospheric pressure.

AB - A Re2O7-B2O3/Al2O3 catalyst was demonstrated to reveal significant activity in cyclohexene dimerization into 1-cyclohexenylcyclohexane with a total yield of 95 % and a selectivity close to 100 % in the batch mode at 75−80°C and atmospheric pressure.

U2 - 10.1016/j.mcat.2021.111398

DO - 10.1016/j.mcat.2021.111398

M3 - Article

SN - 2468-8231

VL - 502

JO - Molecular Catalysis

JF - Molecular Catalysis

M1 - 111398

ER -

Selective dimerization of cyclohexene over a Re2O7-B2O3/Al2O3 catalyst under mild conditions

Abstract

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Selective dimerization of cyclohexene over a Re₂O₇-B₂O₃/Al₂O₃ catalyst under mild conditions