Revealing the role of stabilizers in H2O2 for the peroxyformic acid synthesis and decomposition kinetics

Tommaso Cogliano; Vincenzo Russo; Rosa Turco; Elio Santacesaria; Martino Di Serio; Tapio Salmi; Riccardo Tesser

doi:10.1016/j.ces.2022.117488

Revealing the role of stabilizers in H₂O₂ for the peroxyformic acid synthesis and decomposition kinetics

Tommaso Cogliano, Vincenzo Russo^*, Rosa Turco, Elio Santacesaria, Martino Di Serio, Tapio Salmi, Riccardo Tesser

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

7 Citations (Scopus)

Abstract

The kinetics of formation and decomposition of peroxyformic acid was studied. From experimental evidences taken from literature, we noticed the decomposition reaction depends on the source of the hydrogen peroxide used as a reactant, so we focused on the idea that stabilizing agents present in the hydrogen peroxide solutions affect the reaction rate, inhibiting the peracid decomposition. The nature of the stabilizing agents and the concentration used might in fact change from a supplier to another. A kinetic model was proposed, in which the decomposition model takes into account this effect and, as a first approximation, the stabilizing agent concentration is quantified indirectly through the initial concentration of hydrogen peroxide loaded in the reactive system. The present model aims to lay the foundations for a new approach to the study of the decomposition of peracids in reactive systems.

Original language	English
Article number	117488
Journal	Chemical Engineering Science
Volume	251
Early online date	2 Feb 2022
DOIs	https://doi.org/10.1016/j.ces.2022.117488
Publication status	Published - 6 Apr 2022
MoE publication type	A1 Journal article-refereed

Funding

The authors acknowledge the grant PRIN: Progetti di Ricerca di Interesse Nazionale – Bando 2017 – prot. number: 2017KBTK93 “CARDoon valorisation by InteGrAted biorefiNery (CARDIGAN)” of Italian Ministero dell'Istruzione dell'Università e della Ricerca for the financial support. The authors are grateful to Solvay Italy for providing hydrogen peroxide. This work is part of the activities financed by Academy of Finland, the Academy Professor grant 319002 (T. Salmi). Luca Carnevale is acknowledged for its experimental support in conducting the tests in presence of different hydrogen peroxide solutions. The authors acknowledge the grant PRIN: Progetti di Ricerca di Interesse Nazionale ? Bando 2017 ? prot. number: 2017KBTK93 ?CARDoon valorisation by InteGrAted biorefiNery (CARDIGAN)? of Italian Ministero dell'Istruzione dell'Universit? e della Ricerca for the financial support. The authors are grateful to Solvay Italy for providing hydrogen peroxide. This work is part of the activities financed by Academy of Finland, the Academy Professor grant 319002 (T. Salmi). Luca Carnevale is acknowledged for its experimental support in conducting the tests in presence of different hydrogen peroxide solutions.

Keywords

Catalyzed reaction
Hydrogen peroxide
Kinetic modeling
Kinetics
Performic acid synthesis and decomposition
Stabilizers in HO

Access to Document

10.1016/j.ces.2022.117488Licence: All rights reserved

Cite this

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title = "Revealing the role of stabilizers in H2O2 for the peroxyformic acid synthesis and decomposition kinetics",

abstract = "The kinetics of formation and decomposition of peroxyformic acid was studied. From experimental evidences taken from literature, we noticed the decomposition reaction depends on the source of the hydrogen peroxide used as a reactant, so we focused on the idea that stabilizing agents present in the hydrogen peroxide solutions affect the reaction rate, inhibiting the peracid decomposition. The nature of the stabilizing agents and the concentration used might in fact change from a supplier to another. A kinetic model was proposed, in which the decomposition model takes into account this effect and, as a first approximation, the stabilizing agent concentration is quantified indirectly through the initial concentration of hydrogen peroxide loaded in the reactive system. The present model aims to lay the foundations for a new approach to the study of the decomposition of peracids in reactive systems.",

keywords = "Catalyzed reaction, Hydrogen peroxide, Kinetic modeling, Kinetics, Performic acid synthesis and decomposition, Stabilizers in HO",

author = "Tommaso Cogliano and Vincenzo Russo and Rosa Turco and Elio Santacesaria and \{Di Serio\}, Martino and Tapio Salmi and Riccardo Tesser",

note = "Funding Information: The authors acknowledge the grant PRIN: Progetti di Ricerca di Interesse Nazionale – Bando 2017 – prot. number: 2017KBTK93 “CARDoon valorisation by InteGrAted biorefiNery (CARDIGAN)” of Italian Ministero dell'Istruzione dell'Universit{\`a} e della Ricerca for the financial support. The authors are grateful to Solvay Italy for providing hydrogen peroxide. This work is part of the activities financed by Academy of Finland, the Academy Professor grant 319002 (T. Salmi). Luca Carnevale is acknowledged for its experimental support in conducting the tests in presence of different hydrogen peroxide solutions. Funding Information: The authors acknowledge the grant PRIN: Progetti di Ricerca di Interesse Nazionale ? Bando 2017 ? prot. number: 2017KBTK93 ?CARDoon valorisation by InteGrAted biorefiNery (CARDIGAN)? of Italian Ministero dell'Istruzione dell'Universit? e della Ricerca for the financial support. The authors are grateful to Solvay Italy for providing hydrogen peroxide. This work is part of the activities financed by Academy of Finland, the Academy Professor grant 319002 (T. Salmi). Luca Carnevale is acknowledged for its experimental support in conducting the tests in presence of different hydrogen peroxide solutions. Publisher Copyright: {\textcopyright} 2022 Elsevier Ltd",

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T1 - Revealing the role of stabilizers in H2O2 for the peroxyformic acid synthesis and decomposition kinetics

AU - Cogliano, Tommaso

AU - Russo, Vincenzo

AU - Turco, Rosa

AU - Santacesaria, Elio

AU - Di Serio, Martino

AU - Salmi, Tapio

AU - Tesser, Riccardo

N1 - Funding Information: The authors acknowledge the grant PRIN: Progetti di Ricerca di Interesse Nazionale – Bando 2017 – prot. number: 2017KBTK93 “CARDoon valorisation by InteGrAted biorefiNery (CARDIGAN)” of Italian Ministero dell'Istruzione dell'Università e della Ricerca for the financial support. The authors are grateful to Solvay Italy for providing hydrogen peroxide. This work is part of the activities financed by Academy of Finland, the Academy Professor grant 319002 (T. Salmi). Luca Carnevale is acknowledged for its experimental support in conducting the tests in presence of different hydrogen peroxide solutions. Funding Information: The authors acknowledge the grant PRIN: Progetti di Ricerca di Interesse Nazionale ? Bando 2017 ? prot. number: 2017KBTK93 ?CARDoon valorisation by InteGrAted biorefiNery (CARDIGAN)? of Italian Ministero dell'Istruzione dell'Universit? e della Ricerca for the financial support. The authors are grateful to Solvay Italy for providing hydrogen peroxide. This work is part of the activities financed by Academy of Finland, the Academy Professor grant 319002 (T. Salmi). Luca Carnevale is acknowledged for its experimental support in conducting the tests in presence of different hydrogen peroxide solutions. Publisher Copyright: © 2022 Elsevier Ltd

PY - 2022/4/6

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N2 - The kinetics of formation and decomposition of peroxyformic acid was studied. From experimental evidences taken from literature, we noticed the decomposition reaction depends on the source of the hydrogen peroxide used as a reactant, so we focused on the idea that stabilizing agents present in the hydrogen peroxide solutions affect the reaction rate, inhibiting the peracid decomposition. The nature of the stabilizing agents and the concentration used might in fact change from a supplier to another. A kinetic model was proposed, in which the decomposition model takes into account this effect and, as a first approximation, the stabilizing agent concentration is quantified indirectly through the initial concentration of hydrogen peroxide loaded in the reactive system. The present model aims to lay the foundations for a new approach to the study of the decomposition of peracids in reactive systems.

AB - The kinetics of formation and decomposition of peroxyformic acid was studied. From experimental evidences taken from literature, we noticed the decomposition reaction depends on the source of the hydrogen peroxide used as a reactant, so we focused on the idea that stabilizing agents present in the hydrogen peroxide solutions affect the reaction rate, inhibiting the peracid decomposition. The nature of the stabilizing agents and the concentration used might in fact change from a supplier to another. A kinetic model was proposed, in which the decomposition model takes into account this effect and, as a first approximation, the stabilizing agent concentration is quantified indirectly through the initial concentration of hydrogen peroxide loaded in the reactive system. The present model aims to lay the foundations for a new approach to the study of the decomposition of peracids in reactive systems.

KW - Catalyzed reaction

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KW - Kinetic modeling

KW - Kinetics

KW - Performic acid synthesis and decomposition

KW - Stabilizers in HO

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