Reactions of hydroxymatairesinol over supported palladium catalysts

Heidi Markus; Päivi Mäki-Arvela; Narendra Kumar; Teemu Heikkilä; Vesa-Pekka Lehto; Rainer Sjöholm; Bjarne Holmbom; Tapio Salmi; Dmitry Yu. Murzin

doi:10.1016/j.jcat.2005.12.022

Reactions of hydroxymatairesinol over supported palladium catalysts

Heidi Markus
, Päivi Mäki-Arvela
, Narendra Kumar
, Teemu Heikkilä
, Vesa-Pekka Lehto
, Rainer Sjöholm
, Bjarne Holmbom
, Tapio Salmi
, Dmitry Yu. Murzin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

18 Citations (Scopus)

Abstract

In this work, hydroxymatairesinol (extracted from Norway spruce knots) was hydrogenolyzed to matairesinol over palladium impregnated H-Beta-300, H-Beta-150, H-Beta-25, H-Beta-11, H-Y, H-Mordenite, H-MCM-41, H-ZSM-5, SiO ₂, and Al₂O₃. H-Beta-25 without palladium was also investigated. The hydrogenolysis was performed in 2-propanol at 70 °C under hydrogen and nitrogen atmospheres in a stirred glass reactor. The catalysts were characterized by nitrogen physisorption, direct current plasma atomic emission spectrometry, X-ray powder diffraction, CO pulse chemisorption, transmission electron microscopy, and Fourier transform infrared spectroscopy (pyridine adsorption). Palladium on H-Beta with different acidities was tested; the results showed that the reaction rate was inversely proportional to the acidity. However, Brønsted acid sites are needed for the reaction, because palladium on SiO₂ and Al₂O₃ is not active. In addition to the acidity, a metal is needed; the H-Beta-25 support without palladium displays no activity.

Original language	English
Pages (from-to)	301-308
Number of pages	8
Journal	Journal of Catalysis
Volume	238
Issue number	2
DOIs	https://doi.org/10.1016/j.jcat.2005.12.022
Publication status	Published - 10 Mar 2006
MoE publication type	A1 Journal article-refereed

Funding

This work is part of the activity at the Åbo Akademi Process Chemistry Centre within the Finnish Centre of Excellence Programme (2000–2005) by the Academy of Finland. Financial support from the Raisio Group Research Foundation and European Union through the Sixth Framework Programme is gratefully acknowledged. The authors thank Christer Eckerman for the HMR preparation, Markku Reunanen for the GC-MS analysis, and Drs. Stan Dzwigaj and Eric Marceau for the TEM analysis.

Keywords

Acidity
Hydrogenolysis
Hydroxymatairesinol
Lignans
Matairesinol
Oxomatairesinol
Zeolites

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@article{122e1836323840238956d8f2ef9f1db0,

title = "Reactions of hydroxymatairesinol over supported palladium catalysts",

abstract = "In this work, hydroxymatairesinol (extracted from Norway spruce knots) was hydrogenolyzed to matairesinol over palladium impregnated H-Beta-300, H-Beta-150, H-Beta-25, H-Beta-11, H-Y, H-Mordenite, H-MCM-41, H-ZSM-5, SiO 2, and Al2O3. H-Beta-25 without palladium was also investigated. The hydrogenolysis was performed in 2-propanol at 70 °C under hydrogen and nitrogen atmospheres in a stirred glass reactor. The catalysts were characterized by nitrogen physisorption, direct current plasma atomic emission spectrometry, X-ray powder diffraction, CO pulse chemisorption, transmission electron microscopy, and Fourier transform infrared spectroscopy (pyridine adsorption). Palladium on H-Beta with different acidities was tested; the results showed that the reaction rate was inversely proportional to the acidity. However, Br{\o}nsted acid sites are needed for the reaction, because palladium on SiO2 and Al2O3 is not active. In addition to the acidity, a metal is needed; the H-Beta-25 support without palladium displays no activity.",

keywords = "Acidity, Hydrogenolysis, Hydroxymatairesinol, Lignans, Matairesinol, Oxomatairesinol, Zeolites",

author = "Heidi Markus and P{\"a}ivi M{\"a}ki-Arvela and Narendra Kumar and Teemu Heikkil{\"a} and Vesa-Pekka Lehto and Rainer Sj{\"o}holm and Bjarne Holmbom and Tapio Salmi and Murzin, \{Dmitry Yu.\}",

note = "Funding Information: This work is part of the activity at the {\AA}bo Akademi Process Chemistry Centre within the Finnish Centre of Excellence Programme (2000–2005) by the Academy of Finland. Financial support from the Raisio Group Research Foundation and European Union through the Sixth Framework Programme is gratefully acknowledged. The authors thank Christer Eckerman for the HMR preparation, Markku Reunanen for the GC-MS analysis, and Drs. Stan Dzwigaj and Eric Marceau for the TEM analysis. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.",

year = "2006",

month = mar,

day = "10",

doi = "10.1016/j.jcat.2005.12.022",

language = "English",

volume = "238",

pages = "301--308",

journal = "Journal of Catalysis",

issn = "0021-9517",

publisher = "Elsevier",

number = "2",

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TY - JOUR

T1 - Reactions of hydroxymatairesinol over supported palladium catalysts

AU - Markus, Heidi

AU - Mäki-Arvela, Päivi

AU - Kumar, Narendra

AU - Heikkilä, Teemu

AU - Lehto, Vesa-Pekka

AU - Sjöholm, Rainer

AU - Holmbom, Bjarne

AU - Salmi, Tapio

AU - Murzin, Dmitry Yu.

N1 - Funding Information: This work is part of the activity at the Åbo Akademi Process Chemistry Centre within the Finnish Centre of Excellence Programme (2000–2005) by the Academy of Finland. Financial support from the Raisio Group Research Foundation and European Union through the Sixth Framework Programme is gratefully acknowledged. The authors thank Christer Eckerman for the HMR preparation, Markku Reunanen for the GC-MS analysis, and Drs. Stan Dzwigaj and Eric Marceau for the TEM analysis. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.

PY - 2006/3/10

Y1 - 2006/3/10

N2 - In this work, hydroxymatairesinol (extracted from Norway spruce knots) was hydrogenolyzed to matairesinol over palladium impregnated H-Beta-300, H-Beta-150, H-Beta-25, H-Beta-11, H-Y, H-Mordenite, H-MCM-41, H-ZSM-5, SiO 2, and Al2O3. H-Beta-25 without palladium was also investigated. The hydrogenolysis was performed in 2-propanol at 70 °C under hydrogen and nitrogen atmospheres in a stirred glass reactor. The catalysts were characterized by nitrogen physisorption, direct current plasma atomic emission spectrometry, X-ray powder diffraction, CO pulse chemisorption, transmission electron microscopy, and Fourier transform infrared spectroscopy (pyridine adsorption). Palladium on H-Beta with different acidities was tested; the results showed that the reaction rate was inversely proportional to the acidity. However, Brønsted acid sites are needed for the reaction, because palladium on SiO2 and Al2O3 is not active. In addition to the acidity, a metal is needed; the H-Beta-25 support without palladium displays no activity.

AB - In this work, hydroxymatairesinol (extracted from Norway spruce knots) was hydrogenolyzed to matairesinol over palladium impregnated H-Beta-300, H-Beta-150, H-Beta-25, H-Beta-11, H-Y, H-Mordenite, H-MCM-41, H-ZSM-5, SiO 2, and Al2O3. H-Beta-25 without palladium was also investigated. The hydrogenolysis was performed in 2-propanol at 70 °C under hydrogen and nitrogen atmospheres in a stirred glass reactor. The catalysts were characterized by nitrogen physisorption, direct current plasma atomic emission spectrometry, X-ray powder diffraction, CO pulse chemisorption, transmission electron microscopy, and Fourier transform infrared spectroscopy (pyridine adsorption). Palladium on H-Beta with different acidities was tested; the results showed that the reaction rate was inversely proportional to the acidity. However, Brønsted acid sites are needed for the reaction, because palladium on SiO2 and Al2O3 is not active. In addition to the acidity, a metal is needed; the H-Beta-25 support without palladium displays no activity.

KW - Acidity

KW - Hydrogenolysis

KW - Hydroxymatairesinol

KW - Lignans

KW - Matairesinol

KW - Oxomatairesinol

KW - Zeolites

UR - https://www.scopus.com/pages/publications/32344453785

U2 - 10.1016/j.jcat.2005.12.022

DO - 10.1016/j.jcat.2005.12.022

M3 - Article

AN - SCOPUS:32344453785

SN - 0021-9517

VL - 238

SP - 301

EP - 308

JO - Journal of Catalysis

JF - Journal of Catalysis

IS - 2

ER -

Reactions of hydroxymatairesinol over supported palladium catalysts

Abstract

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Keywords

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