Preparation of chiral indenes containing β-pinenyl derived ligand substituents

S Silver; E Johansson; R Sjoholm; Reko Leino

doi:10.1016/j.tetlet.2003.10.186

Preparation of chiral indenes containing β-pinenyl derived ligand substituents

S Silver
, E Johansson
, R Sjoholm
, Reko Leino

Research output: Contribution to journal › Article › Scientific › peer-review

2 Citations (Scopus)

Abstract

A simple procedure for the preparation of new 1-, 2- and 1,3-chirally substituted indenes is described in which indenyllithium or 2-indenylmagnesium bromide is reacted with a beta-pinenyl derived chlorosilane. Synthesis of the ethylene bridged bis(indene) analogues of two of the new compounds is also described. (C) 2003 Elsevier Ltd. All rights reserved.

Original language	Undefined/Unknown
Pages (from-to)	249–252
Number of pages	4
Journal	Tetrahedron Letters
Volume	45
Issue number	2
DOIs	https://doi.org/10.1016/j.tetlet.2003.10.186
Publication status	Published - 2004
MoE publication type	A1 Journal article-refereed

Keywords

chirality
indene
indenyl
metallocenes

Access to Document

10.1016/j.tetlet.2003.10.186

Cite this

@article{30f93efe48604509bb803f54ba186da2,

title = "Preparation of chiral indenes containing β-pinenyl derived ligand substituents",

abstract = "A simple procedure for the preparation of new 1-, 2- and 1,3-chirally substituted indenes is described in which indenyllithium or 2-indenylmagnesium bromide is reacted with a beta-pinenyl derived chlorosilane. Synthesis of the ethylene bridged bis(indene) analogues of two of the new compounds is also described. (C) 2003 Elsevier Ltd. All rights reserved.",

keywords = "chirality, indene, indenyl, metallocenes, chirality, indene, indenyl, metallocenes, chirality, indene, indenyl, metallocenes",

author = "S Silver and E Johansson and R Sjoholm and Reko Leino",

year = "2004",

doi = "10.1016/j.tetlet.2003.10.186",

language = "Odefinierat/ok{\"a}nt",

volume = "45",

pages = "249–252",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier",

number = "2",

}

TY - JOUR

T1 - Preparation of chiral indenes containing β-pinenyl derived ligand substituents

AU - Silver, S

AU - Johansson, E

AU - Sjoholm, R

AU - Leino, Reko

PY - 2004

Y1 - 2004

N2 - A simple procedure for the preparation of new 1-, 2- and 1,3-chirally substituted indenes is described in which indenyllithium or 2-indenylmagnesium bromide is reacted with a beta-pinenyl derived chlorosilane. Synthesis of the ethylene bridged bis(indene) analogues of two of the new compounds is also described. (C) 2003 Elsevier Ltd. All rights reserved.

AB - A simple procedure for the preparation of new 1-, 2- and 1,3-chirally substituted indenes is described in which indenyllithium or 2-indenylmagnesium bromide is reacted with a beta-pinenyl derived chlorosilane. Synthesis of the ethylene bridged bis(indene) analogues of two of the new compounds is also described. (C) 2003 Elsevier Ltd. All rights reserved.

KW - chirality

KW - indene

KW - indenyl

KW - metallocenes

KW - chirality

KW - indene

KW - indenyl

KW - metallocenes

KW - chirality

KW - indene

KW - indenyl

KW - metallocenes

U2 - 10.1016/j.tetlet.2003.10.186

DO - 10.1016/j.tetlet.2003.10.186

M3 - Artikel

SN - 0040-4039

VL - 45

SP - 249

EP - 252

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 2

ER -