One-pot propargylation and Claisen-type rearrangement for natural lignans matairesinol and α-conidendrin

Dmitrii Riabukhin; Lucas Lagerquist; Jani Rahkila; Patrik Christoffer Eklund

doi:10.1007/s10593-020-02755-9

One-pot propargylation and Claisen-type rearrangement for natural lignans matairesinol and α-conidendrin

Dmitrii Riabukhin^*, Lucas Lagerquist, Jani Rahkila, Patrik Christoffer Eklund

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

1 Citation (Scopus)

Abstract

Improved methods for one-pot propargylation and Claisen rearrangement have been devised for natural lignans – matairesinol and α-conidendrin. The rearrangement was regiospecific, yielding only 2-methylbenzofuran derivatives.

Original language	English
Pages (from-to)	949-952
Number of pages	4
Journal	Chemistry of Heterocyclic Compounds
Volume	56
Issue number	7
DOIs	https://doi.org/10.1007/s10593-020-02755-9
Publication status	Published - 22 Aug 2020
MoE publication type	A1 Journal article-refereed

Keywords

benzofurans
lignans
propargyl ethers
superacids
Claisen rearrangement
natural compounds
propargylation

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title = "One-pot propargylation and Claisen-type rearrangement for natural lignans matairesinol and α-conidendrin",

abstract = "Improved methods for one-pot propargylation and Claisen rearrangement have been devised for natural lignans – matairesinol and α-conidendrin. The rearrangement was regiospecific, yielding only 2-methylbenzofuran derivatives.",

keywords = "benzofurans, lignans, propargyl ethers, superacids, Claisen rearrangement, natural compounds, propargylation",

author = "Dmitrii Riabukhin and Lucas Lagerquist and Jani Rahkila and Eklund, {Patrik Christoffer}",

note = "Published in Khimiya Geterotsiklicheskikh Soedinenii, 2020, 56(7), 949–952",

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doi = "10.1007/s10593-020-02755-9",

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T1 - One-pot propargylation and Claisen-type rearrangement for natural lignans matairesinol and α-conidendrin

AU - Riabukhin, Dmitrii

AU - Lagerquist, Lucas

AU - Rahkila, Jani

AU - Eklund, Patrik Christoffer

N1 - Published in Khimiya Geterotsiklicheskikh Soedinenii, 2020, 56(7), 949–952

PY - 2020/8/22

Y1 - 2020/8/22

N2 - Improved methods for one-pot propargylation and Claisen rearrangement have been devised for natural lignans – matairesinol and α-conidendrin. The rearrangement was regiospecific, yielding only 2-methylbenzofuran derivatives.

AB - Improved methods for one-pot propargylation and Claisen rearrangement have been devised for natural lignans – matairesinol and α-conidendrin. The rearrangement was regiospecific, yielding only 2-methylbenzofuran derivatives.

KW - benzofurans

KW - lignans

KW - propargyl ethers

KW - superacids

KW - Claisen rearrangement

KW - natural compounds

KW - propargylation

U2 - 10.1007/s10593-020-02755-9

DO - 10.1007/s10593-020-02755-9

M3 - Article

SN - 0009-3122

VL - 56

SP - 949

EP - 952

JO - Chemistry of Heterocyclic Compounds

JF - Chemistry of Heterocyclic Compounds

IS - 7

ER -

One-pot propargylation and Claisen-type rearrangement for natural lignans matairesinol and α-conidendrin

Abstract

Keywords

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