TY - JOUR
T1 - One flow through hydrolysis and hydrogenation of semi-industrial xylan from birch (betula pendula) in a continuous reactor—Kinetics and modelling
AU - Lu, Xiaojia
AU - Junghans, Paula
AU - Weckesser, Stephanie
AU - Wärnå, Johan
AU - Hilpmann, Gerd
AU - Lange, Rüdiger
AU - Trajano, Heather
AU - Eränen, Kari
AU - Estel, Lionel
AU - Leveneur, Sebastien
AU - Grénman, Henrik
N1 - Funding Information:
The current study has been performed in the framework of the AMED project financed with the support from the European Union within the European Regional Development Fund (ERDF) and from the Regional Council of Normandie. The China Scholarship Council: Cooperation Program with the UTs (Universit?s de technologie) and INSAs (Institut National des Sciences Appliqu?es) (France) is gratefully acknowledged for financial support as is ?bo Akademi University and its strategic profiling area Technologies for a Sustainable Future. Additionally, the authors are grateful for CH-Bioforce for supplying the hemicellulose.
Funding Information:
The current study has been performed in the framework of the AMED project financed with the support from the European Union within the European Regional Development Fund (ERDF) and from the Regional Council of Normandie. The China Scholarship Council: Cooperation Program with the UTs (Universités de technologie) and INSAs (Institut National des Sciences Appliquées) (France) is gratefully acknowledged for financial support as is Åbo Akademi University and its strategic profiling area Technologies for a Sustainable Future. Additionally, the authors are grateful for CH-Bioforce for supplying the hemicellulose.
Publisher Copyright:
© 2021
PY - 2021/12
Y1 - 2021/12
N2 - Xylan obtained from birch (betula pendula) by a novel semi-industrial scale aqueous based method was used for studying the hydrolysis and consecutive hydrolysis-hydrogenation processes in continuous reactors. Dowex 50WX2-100 was chosen as the hydrolysis catalyst based on the results of catalyst screening performed previously in batch reactor. It was also observed to perform well in continuous reactor converting xylan to xylose in high yield under the studied reaction conditions. The influence of several reaction parameters were investigated for optimization. Similar experimental conditions used in the hydrolysis were then applied for studying one flow through hydrolysis and hydrogenation of the semi-industrial xylan. A consecutive catalyst bed consisting of ruthenium on carbon was introduced into the continuous reactor downstream from the hydrolysis bed to hydrogenate monosaccharides to xylitol. Hydrogen was co-fed into the reactor with the xylan solution. Reaction parameters, including temperature, residence time and hydrogen pressure, were varied to maximize the xylitol yield. The developed continuous process was demonstrated to be highly selective and efficient for the valorization of the semi-industrial xylan by yielding over 90% xylitol under optimal experimental conditions. It was noticed, that co-feeding hydrogenation decreased the degradation of monosaccharides during hydrolysis, thus improving the selectivity towards the target product and enabling remarkable process intensification. Moreover, mathematical modelling was performed for the hydrolysis and one flow through hydrolysis and hydrogenation processes. The models take into account the consecutive reaction pathways and the influence of the experimental conditions. Good fits of the model to the experimental data were obtained. The conversion of this novel, well characterized wood-based xylan to produce xylose or xylitol in continuous reactors has not been studied previously. The current work contributes significantly to understanding the processing of real feedstock in one flow through employing consecutive reactions and provides necessary data for process intensification.
AB - Xylan obtained from birch (betula pendula) by a novel semi-industrial scale aqueous based method was used for studying the hydrolysis and consecutive hydrolysis-hydrogenation processes in continuous reactors. Dowex 50WX2-100 was chosen as the hydrolysis catalyst based on the results of catalyst screening performed previously in batch reactor. It was also observed to perform well in continuous reactor converting xylan to xylose in high yield under the studied reaction conditions. The influence of several reaction parameters were investigated for optimization. Similar experimental conditions used in the hydrolysis were then applied for studying one flow through hydrolysis and hydrogenation of the semi-industrial xylan. A consecutive catalyst bed consisting of ruthenium on carbon was introduced into the continuous reactor downstream from the hydrolysis bed to hydrogenate monosaccharides to xylitol. Hydrogen was co-fed into the reactor with the xylan solution. Reaction parameters, including temperature, residence time and hydrogen pressure, were varied to maximize the xylitol yield. The developed continuous process was demonstrated to be highly selective and efficient for the valorization of the semi-industrial xylan by yielding over 90% xylitol under optimal experimental conditions. It was noticed, that co-feeding hydrogenation decreased the degradation of monosaccharides during hydrolysis, thus improving the selectivity towards the target product and enabling remarkable process intensification. Moreover, mathematical modelling was performed for the hydrolysis and one flow through hydrolysis and hydrogenation processes. The models take into account the consecutive reaction pathways and the influence of the experimental conditions. Good fits of the model to the experimental data were obtained. The conversion of this novel, well characterized wood-based xylan to produce xylose or xylitol in continuous reactors has not been studied previously. The current work contributes significantly to understanding the processing of real feedstock in one flow through employing consecutive reactions and provides necessary data for process intensification.
KW - Combined hydrolysis and hydrogenation
KW - Continuous reactor
KW - Increased selectivity
KW - Kinetics
KW - Process intensification
KW - Xylan
UR - http://www.scopus.com/inward/record.url?scp=85114383460&partnerID=8YFLogxK
U2 - 10.1016/j.cep.2021.108614
DO - 10.1016/j.cep.2021.108614
M3 - Article
AN - SCOPUS:85114383460
SN - 0255-2701
VL - 169
JO - Chemical Engineering and Processing - Process Intensification
JF - Chemical Engineering and Processing - Process Intensification
M1 - 108614
ER -