Microwave Synthesis of Copper Phyllosilicates as Effective Catalysts for Hydrogenation of C≡C Bonds

Anastasiya Shesterkina; Kseniia Vikanova; Egor Kostyukhin; Anna Strekalova; Elena Shuvalova; Gennady Kapustin; Tapio Salmi

doi:10.3390/molecules27030988

Microwave Synthesis of Copper Phyllosilicates as Effective Catalysts for Hydrogenation of C≡C Bonds

Anastasiya Shesterkina^*, Kseniia Vikanova, Egor Kostyukhin, Anna Strekalova, Elena Shuvalova, Gennady Kapustin, Tapio Salmi

^*Corresponding author for this work

Laboratory of Industrial Chemistry and Reaction Engineering

Research output: Contribution to journal › Article › Scientific › peer-review

7 Citations (Scopus)

16 Downloads (Pure)

Abstract

For the first time, the new microwave-assisted method for the synthesis of copper phyllo-silicates on a commercial SiO2 carrier was developed. The application of microwave synthesis al-lowed to decrease the synthesis time from 9 to 6 h compared to the traditional DPU method of preparing chrysocolla. The synthesized catalysts were studied by N2 adsorption, TEM and XRD methods. Catalysts prepared by microwave method are highly effective in the selective hydrogenation of the С≡С bond in 1,4-butynediol to 1,4-butenediol and 2-phenylethinylaniline with a selectiv-ity of 96.5% and 100% at full conversion for 2 and 0.5 h of the reaction, respectively.

Original language	English
Article number	988
Number of pages	9
Journal	Molecules
Volume	27
Issue number	3
DOIs	https://doi.org/10.3390/molecules27030988
Publication status	Published - 1 Feb 2022
MoE publication type	A1 Journal article-refereed

Keywords

1,4-Butenediol
1,4-Butynediol
Copper phyllosilicate
Microwave synthesis
Selective hydrogenation

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10.3390/molecules27030988Licence: CC BY

molecules-27-00988-v3Final published version, 3.69 MBLicence: CC BY

https://urn.fi/URN:NBN:fi-fe2023030329349

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title = "Microwave Synthesis of Copper Phyllosilicates as Effective Catalysts for Hydrogenation of C≡C Bonds",

abstract = "For the first time, the new microwave-assisted method for the synthesis of copper phyllo-silicates on a commercial SiO2 carrier was developed. The application of microwave synthesis al-lowed to decrease the synthesis time from 9 to 6 h compared to the traditional DPU method of preparing chrysocolla. The synthesized catalysts were studied by N2 adsorption, TEM and XRD methods. Catalysts prepared by microwave method are highly effective in the selective hydrogenation of the С≡С bond in 1,4-butynediol to 1,4-butenediol and 2-phenylethinylaniline with a selectiv-ity of 96.5% and 100% at full conversion for 2 and 0.5 h of the reaction, respectively.",

keywords = "1,4-Butenediol, 1,4-Butynediol, Copper phyllosilicate, Microwave synthesis, Selective hydrogenation",

author = "Anastasiya Shesterkina and Kseniia Vikanova and Egor Kostyukhin and Anna Strekalova and Elena Shuvalova and Gennady Kapustin and Tapio Salmi",

note = "Funding Information: Funding: This research was funded by Ministry of Science and Higher Education (project no. 075-15-2021-591) in part related to investigation of microwave synthesis, by the Russian Foundation for Basic Research, project no. 19-33-60001 in part related to study of thermal synthesis of catalysts of selective hydrogenation. Publisher Copyright: {\textcopyright} 2022 by the authors. Licensee MDPI, Basel, Switzerland.",

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AU - Shesterkina, Anastasiya

AU - Vikanova, Kseniia

AU - Kostyukhin, Egor

AU - Strekalova, Anna

AU - Shuvalova, Elena

AU - Kapustin, Gennady

AU - Salmi, Tapio

N1 - Funding Information: Funding: This research was funded by Ministry of Science and Higher Education (project no. 075-15-2021-591) in part related to investigation of microwave synthesis, by the Russian Foundation for Basic Research, project no. 19-33-60001 in part related to study of thermal synthesis of catalysts of selective hydrogenation. Publisher Copyright: © 2022 by the authors. Licensee MDPI, Basel, Switzerland.

PY - 2022/2/1

Y1 - 2022/2/1

N2 - For the first time, the new microwave-assisted method for the synthesis of copper phyllo-silicates on a commercial SiO2 carrier was developed. The application of microwave synthesis al-lowed to decrease the synthesis time from 9 to 6 h compared to the traditional DPU method of preparing chrysocolla. The synthesized catalysts were studied by N2 adsorption, TEM and XRD methods. Catalysts prepared by microwave method are highly effective in the selective hydrogenation of the С≡С bond in 1,4-butynediol to 1,4-butenediol and 2-phenylethinylaniline with a selectiv-ity of 96.5% and 100% at full conversion for 2 and 0.5 h of the reaction, respectively.

AB - For the first time, the new microwave-assisted method for the synthesis of copper phyllo-silicates on a commercial SiO2 carrier was developed. The application of microwave synthesis al-lowed to decrease the synthesis time from 9 to 6 h compared to the traditional DPU method of preparing chrysocolla. The synthesized catalysts were studied by N2 adsorption, TEM and XRD methods. Catalysts prepared by microwave method are highly effective in the selective hydrogenation of the С≡С bond in 1,4-butynediol to 1,4-butenediol and 2-phenylethinylaniline with a selectiv-ity of 96.5% and 100% at full conversion for 2 and 0.5 h of the reaction, respectively.

KW - 1,4-Butenediol

KW - 1,4-Butynediol

KW - Copper phyllosilicate

KW - Microwave synthesis

KW - Selective hydrogenation

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JO - Molecules

JF - Molecules

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ER -

Microwave Synthesis of Copper Phyllosilicates as Effective Catalysts for Hydrogenation of C≡C Bonds

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