L-Lysine templated CaCO₃ precipitated to flax develops flowery crystal structures that improve the mechanical properties of natural fibre reinforced composites

Parvez Alam, Pi Fagerlund, Piotr Hägerstrand, Jim Töyrylä, Shahrouz Amini, Maryam Tadayon, Ali Miserez, Vinay Kumar, Mahdi Pahlevan, Martti Toivakka

Research output: Contribution to journalArticleScientificpeer-review

8 Citations (Scopus)

Abstract

We describe how the mechanical properties of natural fibre composites can be improved by precipitating coral-like coatings to the surfaces of reinforcing fibres. We consider three amino-acid templates (L-lysine, glycine and beta-alanine) on calcium carbonate growth to natural fibres. L-Lysine forms reticulate flower-like crystals, beta-alanine forms globular crystals and glycine forms blocky crystals. These coralised fibres are used to reinforce styrene butadiene rubber and when compared against untreated-fibre reinforced composites; we find that at sufficiently high concentrations L-lysine templated mineral coatings improve composite strength by more than 100%. Contrarily, beta-alanine and glycine templated mineral coatings do not improve the composite strength by more than ca. 60% and ca. 40% respectively. Molecular dynamics simulations elucidate the attachment mechanisms for each amino acid and the highest potential is in the L-lysine templated crystals. Finite element analyses reveal the success of L-lysine templated coatings is due to a heightened fibre tractive resistance.
Original languageUndefined/Unknown
Pages (from-to)84–88
Number of pages5
JournalComposites Part A: Applied Science and Manufacturing
Volume75
DOIs
Publication statusPublished - 2015
MoE publication typeA1 Journal article-refereed

Keywords

  • Fibre/matrix bond
  • Fibres
  • Polymer-matrix composites (PMCs)

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