Kinetics, modeling, and process design of hydrogen production by aqueous phase reforming of xylitol

Dmitry Murzin; Sonia Garcia; Vincezo Russo; Teuvo Kilpiö; Lidia Godina; Anton Tokarev; Alexey V. Kirilin; Irina L. Simakova; Stephen Poulston; Dmitry A. Sladkovskiy; Johan Wärnå

doi:10.1021/acs.iecr.7b01636

Kinetics, modeling, and process design of hydrogen production by aqueous phase reforming of xylitol

Dmitry Murzin, Sonia Garcia, Vincezo Russo, Teuvo Kilpiö, Lidia Godina, Anton Tokarev, Alexey V. Kirilin, Irina L. Simakova, Stephen Poulston, Dmitry A. Sladkovskiy, Johan Wärnå

Research output: Contribution to journal › Article › Scientific › peer-review

24 Citations (Scopus)

Abstract

The present study was focused on kinetic investigation of xylitol aqueous phase reforming with 2.5%Pt/C catalyst in a fixed bed reactor. For kinetic modeling, a complex reaction network was taken into account considering the formation of not only hydrogen and CO₂ but also a range of alkanes in various side reactions. Parameter investigation revealed an adequate description of the experimental data. The influence of mass transfer was elucidated by exploring the parameter space of diffusion and mass transfer coefficients as well as Peclet numbers. Aspen HYSYS software was used to design a hydrogen production plant with 500 kg/h capacity operating with xylitol as a feedstock. Heat consumption of the designed process can be fully covered by heat generated by combusting alkanes formed during APR reaction.

Original language	Undefined/Unknown
Pages (from-to)	13240–13253
Journal	Industrial & Engineering Chemistry Research
Volume	56
Issue number	45
DOIs	https://doi.org/10.1021/acs.iecr.7b01636
Publication status	Published - 2017
MoE publication type	A1 Journal article-refereed

Keywords

Chemical Engineering

Access to Document

10.1021/acs.iecr.7b01636

http://pubs.acs.org/doi/abs/10.1021/acs.iecr.7b01636

Cite this

Murzin, D., Garcia, S., Russo, V., Kilpiö, T., Godina, L., Tokarev, A., Kirilin, A. V., Simakova, I. L., Poulston, S., Sladkovskiy, D. A., & Wärnå, J. (2017). Kinetics, modeling, and process design of hydrogen production by aqueous phase reforming of xylitol. Industrial & Engineering Chemistry Research, 56(45), 13240–13253. https://doi.org/10.1021/acs.iecr.7b01636

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title = "Kinetics, modeling, and process design of hydrogen production by aqueous phase reforming of xylitol",

abstract = "The present study was focused on kinetic investigation of xylitol aqueous phase reforming with 2.5%Pt/C catalyst in a fixed bed reactor. For kinetic modeling, a complex reaction network was taken into account considering the formation of not only hydrogen and CO2 but also a range of alkanes in various side reactions. Parameter investigation revealed an adequate description of the experimental data. The influence of mass transfer was elucidated by exploring the parameter space of diffusion and mass transfer coefficients as well as Peclet numbers. Aspen HYSYS software was used to design a hydrogen production plant with 500 kg/h capacity operating with xylitol as a feedstock. Heat consumption of the designed process can be fully covered by heat generated by combusting alkanes formed during APR reaction.",

keywords = "Chemical Engineering, Chemical Engineering, Chemical Engineering",

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T1 - Kinetics, modeling, and process design of hydrogen production by aqueous phase reforming of xylitol

AU - Murzin, Dmitry

AU - Garcia, Sonia

AU - Russo, Vincezo

AU - Kilpiö, Teuvo

AU - Godina, Lidia

AU - Tokarev, Anton

AU - Kirilin, Alexey V.

AU - Simakova, Irina L.

AU - Poulston, Stephen

AU - Sladkovskiy, Dmitry A.

AU - Wärnå, Johan

N1 - tk. This article is part of the Tapio Salmi Festschrift special issue.

PY - 2017

Y1 - 2017

N2 - The present study was focused on kinetic investigation of xylitol aqueous phase reforming with 2.5%Pt/C catalyst in a fixed bed reactor. For kinetic modeling, a complex reaction network was taken into account considering the formation of not only hydrogen and CO2 but also a range of alkanes in various side reactions. Parameter investigation revealed an adequate description of the experimental data. The influence of mass transfer was elucidated by exploring the parameter space of diffusion and mass transfer coefficients as well as Peclet numbers. Aspen HYSYS software was used to design a hydrogen production plant with 500 kg/h capacity operating with xylitol as a feedstock. Heat consumption of the designed process can be fully covered by heat generated by combusting alkanes formed during APR reaction.

AB - The present study was focused on kinetic investigation of xylitol aqueous phase reforming with 2.5%Pt/C catalyst in a fixed bed reactor. For kinetic modeling, a complex reaction network was taken into account considering the formation of not only hydrogen and CO2 but also a range of alkanes in various side reactions. Parameter investigation revealed an adequate description of the experimental data. The influence of mass transfer was elucidated by exploring the parameter space of diffusion and mass transfer coefficients as well as Peclet numbers. Aspen HYSYS software was used to design a hydrogen production plant with 500 kg/h capacity operating with xylitol as a feedstock. Heat consumption of the designed process can be fully covered by heat generated by combusting alkanes formed during APR reaction.

KW - Chemical Engineering

U2 - 10.1021/acs.iecr.7b01636

DO - 10.1021/acs.iecr.7b01636

M3 - Artikel

SN - 0888-5885

VL - 56

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EP - 13253

JO - Industrial & Engineering Chemistry Research

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