Kinetic modeling of gas phase synthesis of ethyl chloride from ethanol and HCl in fixed bed reactor

Natalia Bukhanko; Johan Wärnå; Ajaikumar Samikannu; Jyri-Pekka Mikkola

doi:10.1016/j.ces.2015.12.005

Kinetic modeling of gas phase synthesis of ethyl chloride from ethanol and HCl in fixed bed reactor

Natalia Bukhanko, Johan Wärnå, Ajaikumar Samikannu, Jyri-Pekka Mikkola

Research output: Contribution to journal › Article › Scientific › peer-review

3 Citations (Scopus)

Abstract

Kinetic modeling of gas-phase synthesis of ethyl chloride from ethanol and hydrochloric acid over high porous Al₂O₃ and 2 wt% ZnCl₂/Al₂O₃ catalysts was studied in a continuous plug flow reactor in the temperature range of 200–325 °C. Two rival kinetic models were proposed that both describe the kinetics well. The kinetic parameters of the reaction were determined and activation energy values for ethyl chloride formation from ethyl alcohol and diethyl ether reactions were calculated.

Original language	Undefined/Unknown
Pages (from-to)	310–317
Journal	Chemical Engineering Science
Volume	142
DOIs	https://doi.org/10.1016/j.ces.2015.12.005
Publication status	Published - 2016
MoE publication type	A1 Journal article-refereed

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10.1016/j.ces.2015.12.005

http://www.sciencedirect.com/science/article/pii/S0009250915007824

Cite this

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title = "Kinetic modeling of gas phase synthesis of ethyl chloride from ethanol and HCl in fixed bed reactor",

abstract = "Kinetic modeling of gas-phase synthesis of ethyl chloride from ethanol and hydrochloric acid over high porous Al2O3 and 2 wt% ZnCl2/Al2O3 catalysts was studied in a continuous plug flow reactor in the temperature range of 200–325 °C. Two rival kinetic models were proposed that both describe the kinetics well. The kinetic parameters of the reaction were determined and activation energy values for ethyl chloride formation from ethyl alcohol and diethyl ether reactions were calculated.",

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AU - Bukhanko, Natalia

AU - Wärnå, Johan

AU - Samikannu, Ajaikumar

AU - Mikkola, Jyri-Pekka

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N2 - Kinetic modeling of gas-phase synthesis of ethyl chloride from ethanol and hydrochloric acid over high porous Al2O3 and 2 wt% ZnCl2/Al2O3 catalysts was studied in a continuous plug flow reactor in the temperature range of 200–325 °C. Two rival kinetic models were proposed that both describe the kinetics well. The kinetic parameters of the reaction were determined and activation energy values for ethyl chloride formation from ethyl alcohol and diethyl ether reactions were calculated.

AB - Kinetic modeling of gas-phase synthesis of ethyl chloride from ethanol and hydrochloric acid over high porous Al2O3 and 2 wt% ZnCl2/Al2O3 catalysts was studied in a continuous plug flow reactor in the temperature range of 200–325 °C. Two rival kinetic models were proposed that both describe the kinetics well. The kinetic parameters of the reaction were determined and activation energy values for ethyl chloride formation from ethyl alcohol and diethyl ether reactions were calculated.

U2 - 10.1016/j.ces.2015.12.005

DO - 10.1016/j.ces.2015.12.005

M3 - Artikel

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SP - 310

EP - 317

JO - Chemical Engineering Science

JF - Chemical Engineering Science

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