Kinetic model for skeletal isomerization of n-butene over ZSM-22

R. Byggningsbacka; N. Kumar; L. E. Lindfors

doi:10.1021/ie990123w

Kinetic model for skeletal isomerization of n-butene over ZSM-22

R. Byggningsbacka^*, N. Kumar, L. E. Lindfors

^*Corresponding author for this work

Industrial Chemistry and Reaction Engineering

Research output: Contribution to journal › Article › Scientific › peer-review

8 Citations (Scopus)

Abstract

A kinetic model for n-butene transformation over ZSM-22 was developed. The effects of temperature, partial pressure, and deactivation on the formation of isobutene and byproducts were included in the model. The model was able to predict n-butene transformation over ZSM-22 reasonably well, although several assumptions were made in order to reduce the number of adjustable parameters. The major assumptions were that isobutene is only produced through monomolecular reactions and byproducts are only produced in reactions between two n-butene molecules or n-butene and isobutene.

Original language	English
Pages (from-to)	2896-2901
Number of pages	6
Journal	Industrial and Engineering Chemistry Research
Volume	38
Issue number	8
DOIs	https://doi.org/10.1021/ie990123w
Publication status	Published - 1999
MoE publication type	A1 Journal article-refereed

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abstract = "A kinetic model for n-butene transformation over ZSM-22 was developed. The effects of temperature, partial pressure, and deactivation on the formation of isobutene and byproducts were included in the model. The model was able to predict n-butene transformation over ZSM-22 reasonably well, although several assumptions were made in order to reduce the number of adjustable parameters. The major assumptions were that isobutene is only produced through monomolecular reactions and byproducts are only produced in reactions between two n-butene molecules or n-butene and isobutene.",

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AU - Lindfors, L. E.

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AB - A kinetic model for n-butene transformation over ZSM-22 was developed. The effects of temperature, partial pressure, and deactivation on the formation of isobutene and byproducts were included in the model. The model was able to predict n-butene transformation over ZSM-22 reasonably well, although several assumptions were made in order to reduce the number of adjustable parameters. The major assumptions were that isobutene is only produced through monomolecular reactions and byproducts are only produced in reactions between two n-butene molecules or n-butene and isobutene.

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JF - Industrial and Engineering Chemistry Research

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ER -

Kinetic model for skeletal isomerization of n-butene over ZSM-22

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