Kinetic model for skeletal isomerization of n-butene over ZSM-22

R. Byggningsbacka*, N. Kumar, L. E. Lindfors

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

7 Citations (Scopus)

Abstract

A kinetic model for n-butene transformation over ZSM-22 was developed. The effects of temperature, partial pressure, and deactivation on the formation of isobutene and byproducts were included in the model. The model was able to predict n-butene transformation over ZSM-22 reasonably well, although several assumptions were made in order to reduce the number of adjustable parameters. The major assumptions were that isobutene is only produced through monomolecular reactions and byproducts are only produced in reactions between two n-butene molecules or n-butene and isobutene.

Original languageEnglish
Pages (from-to)2896-2901
Number of pages6
JournalIndustrial and Engineering Chemistry Research
Volume38
Issue number8
DOIs
Publication statusPublished - 1999
MoE publication typeA1 Journal article-refereed

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