Isolation of pure pinosylvins from industrial knotwood residue with non-chlorinated solvents

Ida Poljanšek; Primož Oven; Viljem Vek; Jan-Erik Raitanen; Jarl Hemming; Stefan Willför

doi:10.1515/hf-2018-0152

Isolation of pure pinosylvins from industrial knotwood residue with non-chlorinated solvents

Ida Poljanšek, Primož Oven, Viljem Vek, Jan-Erik Raitanen, Jarl Hemming, Stefan Willför

Technologies for a Sustainable Future

Research output: Contribution to journal › Article › Scientific › peer-review

7 Citations (Scopus)

Abstract

The aim of the study was to find appropriate non-chlorinated solvent systems for the extraction and separation of pure pinosylvin (PS) and pinosylvin monomethylether (PSMME) from Scots pine/Norway spruce wood residues. The extraction was performed in a pressurized solvent extractor and the purification and isolation of pure substances was done by flash chromatography. More precisely, pure PS was isolated via sequential flash chromatography in two repetitions in the gradient mode of the mobile phase, with cylcohexane (CX) and ethylacetate (EtOAc), beginning with 100% CX and ending up with 100% EtOAc. The extractives were qualitatively and quantitatively analyzed in terms of PS and PSMME contents by gas chromatography-flame ionization detector (GC-FID), gas chromatography-mass spectrometry (GC-MS), high-performance liquid chromatography (HPLC) and proton nuclear magnetic resonance (1H-NMR) spectroscopy.

Original language	Undefined/Unknown
Pages (from-to)	475–484
Journal	Holzforschung
Volume	73
Issue number	5
DOIs	https://doi.org/10.1515/hf-2018-0152
Publication status	Published - 2019
MoE publication type	A1 Journal article-refereed

Keywords

non-chlorinated solvents
pinosylvin
Extraction
knotwood

Access to Document

10.1515/hf-2018-0152

https://www.degruyter.com/view/j/hfsg.2019.73.issue-5/hf-2018-0152/hf-2018-0152.xml

Cite this

@article{27501061280e48709c6408df18d81740,

title = "Isolation of pure pinosylvins from industrial knotwood residue with non-chlorinated solvents",

abstract = "The aim of the study was to find appropriate non-chlorinated solvent systems for the extraction and separation of pure pinosylvin (PS) and pinosylvin monomethylether (PSMME) from Scots pine/Norway spruce wood residues. The extraction was performed in a pressurized solvent extractor and the purification and isolation of pure substances was done by flash chromatography. More precisely, pure PS was isolated via sequential flash chromatography in two repetitions in the gradient mode of the mobile phase, with cylcohexane (CX) and ethylacetate (EtOAc), beginning with 100% CX and ending up with 100% EtOAc. The extractives were qualitatively and quantitatively analyzed in terms of PS and PSMME contents by gas chromatography-flame ionization detector (GC-FID), gas chromatography-mass spectrometry (GC-MS), high-performance liquid chromatography (HPLC) and proton nuclear magnetic resonance (1H-NMR) spectroscopy.",

keywords = "non-chlorinated solvents, pinosylvin, Extraction, knotwood, non-chlorinated solvents, pinosylvin, Extraction, knotwood, non-chlorinated solvents, pinosylvin, Extraction, knotwood",

author = "Ida Poljan{\v s}ek and Primo{\v z} Oven and Viljem Vek and Jan-Erik Raitanen and Jarl Hemming and Stefan Willf{\"o}r",

note = "3PK",

year = "2019",

doi = "10.1515/hf-2018-0152",

language = "Odefinierat/ok{\"a}nt",

volume = "73",

pages = "475–484",

journal = "Holzforschung",

issn = "0018-3830",

publisher = "De Gruyter",

number = "5",

}

TY - JOUR

T1 - Isolation of pure pinosylvins from industrial knotwood residue with non-chlorinated solvents

AU - Poljanšek, Ida

AU - Oven, Primož

AU - Vek, Viljem

AU - Raitanen, Jan-Erik

AU - Hemming, Jarl

AU - Willför, Stefan

N1 - 3PK

PY - 2019

Y1 - 2019

N2 - The aim of the study was to find appropriate non-chlorinated solvent systems for the extraction and separation of pure pinosylvin (PS) and pinosylvin monomethylether (PSMME) from Scots pine/Norway spruce wood residues. The extraction was performed in a pressurized solvent extractor and the purification and isolation of pure substances was done by flash chromatography. More precisely, pure PS was isolated via sequential flash chromatography in two repetitions in the gradient mode of the mobile phase, with cylcohexane (CX) and ethylacetate (EtOAc), beginning with 100% CX and ending up with 100% EtOAc. The extractives were qualitatively and quantitatively analyzed in terms of PS and PSMME contents by gas chromatography-flame ionization detector (GC-FID), gas chromatography-mass spectrometry (GC-MS), high-performance liquid chromatography (HPLC) and proton nuclear magnetic resonance (1H-NMR) spectroscopy.

AB - The aim of the study was to find appropriate non-chlorinated solvent systems for the extraction and separation of pure pinosylvin (PS) and pinosylvin monomethylether (PSMME) from Scots pine/Norway spruce wood residues. The extraction was performed in a pressurized solvent extractor and the purification and isolation of pure substances was done by flash chromatography. More precisely, pure PS was isolated via sequential flash chromatography in two repetitions in the gradient mode of the mobile phase, with cylcohexane (CX) and ethylacetate (EtOAc), beginning with 100% CX and ending up with 100% EtOAc. The extractives were qualitatively and quantitatively analyzed in terms of PS and PSMME contents by gas chromatography-flame ionization detector (GC-FID), gas chromatography-mass spectrometry (GC-MS), high-performance liquid chromatography (HPLC) and proton nuclear magnetic resonance (1H-NMR) spectroscopy.

KW - non-chlorinated solvents

KW - pinosylvin

KW - Extraction

KW - knotwood

KW - non-chlorinated solvents

KW - pinosylvin

KW - Extraction

KW - knotwood

KW - non-chlorinated solvents

KW - pinosylvin

KW - Extraction

KW - knotwood

U2 - 10.1515/hf-2018-0152

DO - 10.1515/hf-2018-0152

M3 - Artikel

SN - 0018-3830

VL - 73

SP - 475

EP - 484

JO - Holzforschung

JF - Holzforschung

IS - 5

ER -