Indenyl esters as potential electronically modified cyclopentadienyl ligands for transition metal complexes

Reko Leino, Luttikhedde HJG, L Langstedt, A Penninkangas

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    Abstract

    The preparation of two new indenyl esters 2-(2,4,6-trimethylbenzoyloxy)indene (1) and 2-(adamantanoyloxy)indene (2) is reported. Both compounds can be deprotonated with alkyllithiums such as n-BuLi and the resulting anions trapped by addition of TMSCl or iodomethane, rendering them as potential electronically modified cyclopentadienyl ligand analogues for complexation with transition metals. (C) 2002 Elsevier Science Ltd. All rights reserved.
    Original languageUndefined/Unknown
    Pages (from-to)4149–4151
    Number of pages3
    JournalTetrahedron Letters
    Volume43
    Issue number23
    Publication statusPublished - 2002
    MoE publication typeA1 Journal article-refereed

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