Hydrogenolysis of lignin over Ru-based catalysts: The role of the ruthenium in a lignin fragmentation process

Marian Verziu; Alina Tirsoaga; Bogdan Cojocaru; Cristina Bucur; Bogdan Tudora; Aurore Richel; Mario Aguedo; Ajaikumar Samikannu; Jyri-Pekka Mikkola

doi:10.1016/j.mcat.2018.03.004

Hydrogenolysis of lignin over Ru-based catalysts: The role of the ruthenium in a lignin fragmentation process

Marian Verziu, Alina Tirsoaga, Bogdan Cojocaru, Cristina Bucur, Bogdan Tudora, Aurore Richel, Mario Aguedo, Ajaikumar Samikannu, Jyri-Pekka Mikkola

Research output: Contribution to journal › Article › Scientific › peer-review

37 Citations (Scopus)

Abstract

The catalytic performances of two different classes of catalysts containing nickel or/and ruthenium as the active sites were studied in the depolymerisation of lignin isolated from Miscanthus × giganteus. The catalysts were prepared either by coprecipitation (ie, (RuNiMgAlO)x, (RuNiAlO)x, (NiAlO)x, (NiMgAlO)x) or by wet impregnation (ie, Ru/Al2O3) and characterized by nitrogen physisorption (BET), XRD, XPS, NH3-TPD, Raman and H2-TPR techniques. The experimental results indicate that the presence of ruthenium led to dimers as dominant products.

Original language	Undefined/Unknown
Pages (from-to)	65–76
Journal	Molecular Catalysis
Volume	450
DOIs	https://doi.org/10.1016/j.mcat.2018.03.004
Publication status	Published - 2018
MoE publication type	A1 Journal article-refereed

Keywords

Chemical Engineering

Access to Document

10.1016/j.mcat.2018.03.004

https://www.sciencedirect.com/science/article/pii/S2468823118300944

Cite this

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title = "Hydrogenolysis of lignin over Ru-based catalysts: The role of the ruthenium in a lignin fragmentation process",

abstract = "The catalytic performances of two different classes of catalysts containing nickel or/and ruthenium as the active sites were studied in the depolymerisation of lignin isolated from Miscanthus × giganteus. The catalysts were prepared either by coprecipitation (ie, (RuNiMgAlO)x, (RuNiAlO)x, (NiAlO)x, (NiMgAlO)x) or by wet impregnation (ie, Ru/Al2O3) and characterized by nitrogen physisorption (BET), XRD, XPS, NH3-TPD, Raman and H2-TPR techniques. The experimental results indicate that the presence of ruthenium led to dimers as dominant products.",

keywords = "Chemical Engineering, Chemical Engineering, Chemical Engineering",

author = "Marian Verziu and Alina Tirsoaga and Bogdan Cojocaru and Cristina Bucur and Bogdan Tudora and Aurore Richel and Mario Aguedo and Ajaikumar Samikannu and Jyri-Pekka Mikkola",

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TY - JOUR

T1 - Hydrogenolysis of lignin over Ru-based catalysts: The role of the ruthenium in a lignin fragmentation process

AU - Verziu, Marian

AU - Tirsoaga, Alina

AU - Cojocaru, Bogdan

AU - Bucur, Cristina

AU - Tudora, Bogdan

AU - Richel, Aurore

AU - Aguedo, Mario

AU - Samikannu, Ajaikumar

AU - Mikkola, Jyri-Pekka

N1 - tk. Mikkolas förnamn felstavat i publikationen.

PY - 2018

Y1 - 2018

N2 - The catalytic performances of two different classes of catalysts containing nickel or/and ruthenium as the active sites were studied in the depolymerisation of lignin isolated from Miscanthus × giganteus. The catalysts were prepared either by coprecipitation (ie, (RuNiMgAlO)x, (RuNiAlO)x, (NiAlO)x, (NiMgAlO)x) or by wet impregnation (ie, Ru/Al2O3) and characterized by nitrogen physisorption (BET), XRD, XPS, NH3-TPD, Raman and H2-TPR techniques. The experimental results indicate that the presence of ruthenium led to dimers as dominant products.

AB - The catalytic performances of two different classes of catalysts containing nickel or/and ruthenium as the active sites were studied in the depolymerisation of lignin isolated from Miscanthus × giganteus. The catalysts were prepared either by coprecipitation (ie, (RuNiMgAlO)x, (RuNiAlO)x, (NiAlO)x, (NiMgAlO)x) or by wet impregnation (ie, Ru/Al2O3) and characterized by nitrogen physisorption (BET), XRD, XPS, NH3-TPD, Raman and H2-TPR techniques. The experimental results indicate that the presence of ruthenium led to dimers as dominant products.

KW - Chemical Engineering

U2 - 10.1016/j.mcat.2018.03.004

DO - 10.1016/j.mcat.2018.03.004

M3 - Artikel

SN - 2468-8231

VL - 450

SP - 65

EP - 76

JO - Molecular Catalysis

JF - Molecular Catalysis

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