Hydrogenation of citral over carbon supported iridium catalysts

Heidi Bernas, Irina Simakova, Igor P. Prosvirin, Päivi Mäki-Arvela, Reko Leino, Dmitry Murzin

    Research output: Contribution to journalArticleScientificpeer-review

    12 Citations (Scopus)

    Abstract

    Hydrogenation of citral (3,7-dimethyl-2,6-octadienal) was carried out in a batch reactor at atmospheric hydrogen pressure and 70 °C over Sibunit (mesoporous carbon) supported iridium catalysts with different metal loadings. The major products were isopropyl ethers of geraniol and nerol (2-propanol was used as solvent), but also geraniol, nerol, citronellal di-isopropyl acetal and citronellal were formed. The metal particle size was determined by CO-chemisorption and varied from 2 to 6 nm. The turnover frequency for hydrogenation reactions increased with the metal particle size.
    Original languageUndefined/Unknown
    Pages (from-to)690–697
    Number of pages8
    JournalCatalysis Letters
    Volume142
    Issue number6
    DOIs
    Publication statusPublished - 2012
    MoE publication typeA1 Journal article-refereed

    Keywords

    • Catalysis
    • Citral
    • Iridium

    Cite this