Hydrogenation of 2-methylindole using supported metal catalysts

Heidi Bernas; Narendra Kumar; Atte Aho; Reko Leino; Dmitry Murzin

doi:10.1016/j.catcom.2014.07.001

Hydrogenation of 2-methylindole using supported metal catalysts

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Abstract

The hydrogenation of 2-methylindole to 2-methylindoline in toluene was studied at 60 degrees C and 40 bar hydrogen pressure in a batch mode using a range of carbon, alumina, and zeolite supported metal catalysts were performed in toluene. The results were compared with a more conventional catalytic system containing besides 5% Pt/C also 1.2 eq. of p-toluenesulfonic add in ethanol:water (50:50 v/v). The highest turnover frequency (TOF) was obtained a zeolite supported iridium catalyst.

Original language	Undefined/Unknown
Pages (from-to)	41–44
Journal	Catalysis Communications
Volume	56
DOIs	https://doi.org/10.1016/j.catcom.2014.07.001
Publication status	Published - 2014
MoE publication type	A1 Journal article-refereed

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10.1016/j.catcom.2014.07.001

Cite this

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title = "Hydrogenation of 2-methylindole using supported metal catalysts",

abstract = "The hydrogenation of 2-methylindole to 2-methylindoline in toluene was studied at 60 degrees C and 40 bar hydrogen pressure in a batch mode using a range of carbon, alumina, and zeolite supported metal catalysts were performed in toluene. The results were compared with a more conventional catalytic system containing besides 5\% Pt/C also 1.2 eq. of p-toluenesulfonic add in ethanol:water (50:50 v/v). The highest turnover frequency (TOF) was obtained a zeolite supported iridium catalyst.",

author = "Heidi Bernas and Narendra Kumar and Atte Aho and Reko Leino and Dmitry Murzin",

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pages = "41–44",

journal = "Catalysis Communications",

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AU - Bernas, Heidi

AU - Kumar, Narendra

AU - Aho, Atte

AU - Leino, Reko

AU - Murzin, Dmitry

PY - 2014

Y1 - 2014

N2 - The hydrogenation of 2-methylindole to 2-methylindoline in toluene was studied at 60 degrees C and 40 bar hydrogen pressure in a batch mode using a range of carbon, alumina, and zeolite supported metal catalysts were performed in toluene. The results were compared with a more conventional catalytic system containing besides 5% Pt/C also 1.2 eq. of p-toluenesulfonic add in ethanol:water (50:50 v/v). The highest turnover frequency (TOF) was obtained a zeolite supported iridium catalyst.

AB - The hydrogenation of 2-methylindole to 2-methylindoline in toluene was studied at 60 degrees C and 40 bar hydrogen pressure in a batch mode using a range of carbon, alumina, and zeolite supported metal catalysts were performed in toluene. The results were compared with a more conventional catalytic system containing besides 5% Pt/C also 1.2 eq. of p-toluenesulfonic add in ethanol:water (50:50 v/v). The highest turnover frequency (TOF) was obtained a zeolite supported iridium catalyst.

U2 - 10.1016/j.catcom.2014.07.001

DO - 10.1016/j.catcom.2014.07.001

M3 - Artikel

SN - 1566-7367

VL - 56

SP - 41

EP - 44

JO - Catalysis Communications

JF - Catalysis Communications

ER -