Hydrodesulfurization Catalysts from Aluminium-Containing Waste

M. P. Yunusov; Sh Gulomov; K. A. Nasullayev; D. P.K. Turdiyeva; N. F. Isayeva; I. S.K. Abdurakhmanova; B. D. Mustafayev; D. Yu Murzin

doi:10.1007/s10562-024-04685-z

Hydrodesulfurization Catalysts from Aluminium-Containing Waste

M. P. Yunusov, Sh Gulomov, K. A. Nasullayev, D. P.K. Turdiyeva, N. F. Isayeva, I. S.K. Abdurakhmanova, B. D. Mustafayev, D. Yu Murzin^*

^*Corresponding author for this work

Laboratory of Industrial Chemistry and Reaction Engineering

Research output: Contribution to journal › Article › Scientific › peer-review

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Abstract

A possibility of using aluminum hydroxide, a product of processing of the adsorbent that lost its sorption activity in purification of a polyethylene solution cyclohexane, was demonstrated in the synthesis of aluminum kaolin borate supports for hydrodesulfurization catalysis in oil refining. The influence of typical impurities V, Ti and Na in the composition of the spent adsorbent on the physicochemical and catalytic properties of supports and catalysts was determined. Alumina-kaolin-borate catalyst carriers with the Ti content of approx. 0.2% have been prepared by atomic layer deposition (ALD) of TiCl₄ onto the granules. A positive effect of molecular layering with TiO₂ has been revealed by temperature programmed reduction and oxidation in combination with hydrodesulphurization activity testing. Graphical Abstract: (Figure presented.).

Original language	English
Pages (from-to)	4409-4421
Number of pages	13
Journal	Catalysis Letters
Volume	154
Issue number	8
DOIs	https://doi.org/10.1007/s10562-024-04685-z
Publication status	Published - Aug 2024
MoE publication type	A1 Journal article-refereed

Keywords

Alumina waste
Catalysts
Hydrodesulfurization, atomic layer deposition

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10.1007/s10562-024-04685-z

s10562-024-04685-zFinal published version, 2.07 MBLicence: CC BY

https://urn.fi/URN:NBN:fi-fe202502018631

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title = "Hydrodesulfurization Catalysts from Aluminium-Containing Waste",

abstract = "A possibility of using aluminum hydroxide, a product of processing of the adsorbent that lost its sorption activity in purification of a polyethylene solution cyclohexane, was demonstrated in the synthesis of aluminum kaolin borate supports for hydrodesulfurization catalysis in oil refining. The influence of typical impurities V, Ti and Na in the composition of the spent adsorbent on the physicochemical and catalytic properties of supports and catalysts was determined. Alumina-kaolin-borate catalyst carriers with the Ti content of approx. 0.2% have been prepared by atomic layer deposition (ALD) of TiCl4 onto the granules. A positive effect of molecular layering with TiO2 has been revealed by temperature programmed reduction and oxidation in combination with hydrodesulphurization activity testing. Graphical Abstract: (Figure presented.).",

keywords = "Alumina waste, Catalysts, Hydrodesulfurization, atomic layer deposition",

author = "Yunusov, {M. P.} and Sh Gulomov and Nasullayev, {K. A.} and Turdiyeva, {D. P.K.} and Isayeva, {N. F.} and Abdurakhmanova, {I. S.K.} and Mustafayev, {B. D.} and Murzin, {D. Yu}",

note = "Publisher Copyright: {\textcopyright} The Author(s) 2024.",

year = "2024",

month = aug,

doi = "10.1007/s10562-024-04685-z",

language = "English",

volume = "154",

pages = "4409--4421",

journal = "Catalysis Letters",

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TY - JOUR

T1 - Hydrodesulfurization Catalysts from Aluminium-Containing Waste

AU - Yunusov, M. P.

AU - Gulomov, Sh

AU - Nasullayev, K. A.

AU - Turdiyeva, D. P.K.

AU - Isayeva, N. F.

AU - Abdurakhmanova, I. S.K.

AU - Mustafayev, B. D.

AU - Murzin, D. Yu

PY - 2024/8

Y1 - 2024/8

N2 - A possibility of using aluminum hydroxide, a product of processing of the adsorbent that lost its sorption activity in purification of a polyethylene solution cyclohexane, was demonstrated in the synthesis of aluminum kaolin borate supports for hydrodesulfurization catalysis in oil refining. The influence of typical impurities V, Ti and Na in the composition of the spent adsorbent on the physicochemical and catalytic properties of supports and catalysts was determined. Alumina-kaolin-borate catalyst carriers with the Ti content of approx. 0.2% have been prepared by atomic layer deposition (ALD) of TiCl4 onto the granules. A positive effect of molecular layering with TiO2 has been revealed by temperature programmed reduction and oxidation in combination with hydrodesulphurization activity testing. Graphical Abstract: (Figure presented.).

AB - A possibility of using aluminum hydroxide, a product of processing of the adsorbent that lost its sorption activity in purification of a polyethylene solution cyclohexane, was demonstrated in the synthesis of aluminum kaolin borate supports for hydrodesulfurization catalysis in oil refining. The influence of typical impurities V, Ti and Na in the composition of the spent adsorbent on the physicochemical and catalytic properties of supports and catalysts was determined. Alumina-kaolin-borate catalyst carriers with the Ti content of approx. 0.2% have been prepared by atomic layer deposition (ALD) of TiCl4 onto the granules. A positive effect of molecular layering with TiO2 has been revealed by temperature programmed reduction and oxidation in combination with hydrodesulphurization activity testing. Graphical Abstract: (Figure presented.).

KW - Alumina waste

KW - Catalysts

KW - Hydrodesulfurization, atomic layer deposition

UR - http://www.scopus.com/inward/record.url?scp=85191743073&partnerID=8YFLogxK

U2 - 10.1007/s10562-024-04685-z

DO - 10.1007/s10562-024-04685-z

M3 - Article

AN - SCOPUS:85191743073

SN - 1011-372X

VL - 154

SP - 4409

EP - 4421

JO - Catalysis Letters

JF - Catalysis Letters

IS - 8

ER -

Hydrodesulfurization Catalysts from Aluminium-Containing Waste

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