Hydrodeoxygenation of vanillin over carbon supported metal catalysts

JL Santos; Moldir Alda-Onggar; V. Fedorov; M. Peurla; Kari Eränen; Päivi Mäki-Arvela; MÁ Centeno; Dmitry Murzin

doi:10.1016/j.apcata.2018.05.010

Hydrodeoxygenation of vanillin over carbon supported metal catalysts

JL Santos
, Moldir Alda-Onggar
, V. Fedorov
, M. Peurla
, Kari Eränen
, Päivi Mäki-Arvela
, MÁ Centeno
, Dmitry Murzin

Research output: Contribution to journal › Article › Scientific › peer-review

91 Citations (Scopus)

Abstract

Different carbon supported metal catalysts were synthesized, and characterized with various physico-chemical methods and tested in vanillin hydrodeoxygenation under 30 bar total pressure in water as a solvent at 100 °C. The catalysts exhibited high specific surface area and the metal dispersion decreased in following order: Pt/C > Pd/C > Au/C > Rh/C > Ru/C. The most active catalyst was Pd/C followed by Ru/C. Vanillin hydrodeoxygenation proceeded via hydrogenation forming vanillyl alcohol further to its hydrogenolysis forming p-creosol. Both hydrogenation and hydrogenolysis were promoted by Pd/C, which exhibited rather high dispersion. The highest selectivity to p-creosol, 95% at complete vanillin conversion, was obtained with Pd/C. Kinetic modelling of vanillyl alcohol selectivity as a function of vanillin conversion was performed.

Original language	Undefined/Unknown
Pages (from-to)	137–149
Journal	Applied Catalysis A: General
Volume	561
DOIs	https://doi.org/10.1016/j.apcata.2018.05.010
Publication status	Published - 2018
MoE publication type	A1 Journal article-refereed

Access to Document

10.1016/j.apcata.2018.05.010

https://www.sciencedirect.com/science/article/pii/S0926860X18302321

Cite this

@article{ec3910fd7c3947f1a9e6bad335e95888,

title = "Hydrodeoxygenation of vanillin over carbon supported metal catalysts",

abstract = "Different carbon supported metal catalysts were synthesized, and characterized with various physico-chemical methods and tested in vanillin hydrodeoxygenation under 30 bar total pressure in water as a solvent at 100 °C. The catalysts exhibited high specific surface area and the metal dispersion decreased in following order: Pt/C > Pd/C > Au/C > Rh/C > Ru/C. The most active catalyst was Pd/C followed by Ru/C. Vanillin hydrodeoxygenation proceeded via hydrogenation forming vanillyl alcohol further to its hydrogenolysis forming p-creosol. Both hydrogenation and hydrogenolysis were promoted by Pd/C, which exhibited rather high dispersion. The highest selectivity to p-creosol, 95\% at complete vanillin conversion, was obtained with Pd/C. Kinetic modelling of vanillyl alcohol selectivity as a function of vanillin conversion was performed.",

author = "JL Santos and Moldir Alda-Onggar and V. Fedorov and M. Peurla and Kari Er{\"a}nen and P{\"a}ivi M{\"a}ki-Arvela and M{\'A} Centeno and Dmitry Murzin",

note = "tk. V. Fedorov is also affiliated with {\AA}AU",

year = "2018",

doi = "10.1016/j.apcata.2018.05.010",

language = "Odefinierat/ok{\"a}nt",

volume = "561",

pages = "137–149",

journal = "Applied Catalysis A: General",

issn = "0926-860X",

publisher = "Elsevier",

}

TY - JOUR

T1 - Hydrodeoxygenation of vanillin over carbon supported metal catalysts

AU - Santos, JL

AU - Alda-Onggar, Moldir

AU - Fedorov, V.

AU - Peurla, M.

AU - Eränen, Kari

AU - Mäki-Arvela, Päivi

AU - Centeno, MÁ

AU - Murzin, Dmitry

N1 - tk. V. Fedorov is also affiliated with ÅAU

PY - 2018

Y1 - 2018

N2 - Different carbon supported metal catalysts were synthesized, and characterized with various physico-chemical methods and tested in vanillin hydrodeoxygenation under 30 bar total pressure in water as a solvent at 100 °C. The catalysts exhibited high specific surface area and the metal dispersion decreased in following order: Pt/C > Pd/C > Au/C > Rh/C > Ru/C. The most active catalyst was Pd/C followed by Ru/C. Vanillin hydrodeoxygenation proceeded via hydrogenation forming vanillyl alcohol further to its hydrogenolysis forming p-creosol. Both hydrogenation and hydrogenolysis were promoted by Pd/C, which exhibited rather high dispersion. The highest selectivity to p-creosol, 95% at complete vanillin conversion, was obtained with Pd/C. Kinetic modelling of vanillyl alcohol selectivity as a function of vanillin conversion was performed.

AB - Different carbon supported metal catalysts were synthesized, and characterized with various physico-chemical methods and tested in vanillin hydrodeoxygenation under 30 bar total pressure in water as a solvent at 100 °C. The catalysts exhibited high specific surface area and the metal dispersion decreased in following order: Pt/C > Pd/C > Au/C > Rh/C > Ru/C. The most active catalyst was Pd/C followed by Ru/C. Vanillin hydrodeoxygenation proceeded via hydrogenation forming vanillyl alcohol further to its hydrogenolysis forming p-creosol. Both hydrogenation and hydrogenolysis were promoted by Pd/C, which exhibited rather high dispersion. The highest selectivity to p-creosol, 95% at complete vanillin conversion, was obtained with Pd/C. Kinetic modelling of vanillyl alcohol selectivity as a function of vanillin conversion was performed.

U2 - 10.1016/j.apcata.2018.05.010

DO - 10.1016/j.apcata.2018.05.010

M3 - Artikel

SN - 0926-860X

VL - 561

SP - 137

EP - 149

JO - Applied Catalysis A: General

JF - Applied Catalysis A: General

ER -