Hexadecane hydrocracking for production of jet fuels from renewable diesel over proton and metal modified H-Beta zeolites

Taimoor Kaka khel; Päivi Mäki-Arvela; Muhammad Azkaar; Zuzana Vajglová; Atte Aho; Jarl Hemming; Markus Peurla; Kari Eränen; Narendra Kumar; Dmitry Murzin

doi:10.1016/j.mcat.2019.110515

Hexadecane hydrocracking for production of jet fuels from renewable diesel over proton and metal modified H-Beta zeolites

Taimoor Kaka khel, Päivi Mäki-Arvela, Muhammad Azkaar, Zuzana Vajglová, Atte Aho, Jarl Hemming, Markus Peurla, Kari Eränen, Narendra Kumar, Dmitry Murzin

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Abstract

Hydrocracking of hexadecane to produce jet fuel components was investigated over proton and metal modified Beta zeolites with different acidity. They were characterized by a range of physico-chemical methods. The initial catalyst screening was performed at 210 °C under 40 bar hydrogen showing that the most promising catalysts were 2.5 wt% Pt-H-Beta-25 and 2.5 wt% Ru-H-Beta-300, which were also tested at 240 °C under 45 bar hydrogen. The results revealed that the yield of jet fuel components was maximally 27% over 2.5 wt% Pt-H-Beta-25. This catalyst gave, however, only 55% mass balance closure to the liquid phase products, while a mildly acidic 2.5 wt% Ru-H-Beta-300 afforded 24% yield of the jet fuel components and 89% liquid mass balance closure.

Original language	Undefined/Unknown
Pages (from-to)	–
Journal	Molecular Catalysis
Volume	476
DOIs	https://doi.org/10.1016/j.mcat.2019.110515
Publication status	Published - 2019
MoE publication type	A1 Journal article-refereed

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10.1016/j.mcat.2019.110515

Kinetics in hexadecane hydrocracking for production of jet fuels from renewable diesel over parent and metal modified H-Beta zeolites1.pdfAccepted author manuscript, 1.97 MBLicence: CC BY-NC-ND

Cite this

@article{7c1697bcb1384023acb2d7922228007f,

title = "Hexadecane hydrocracking for production of jet fuels from renewable diesel over proton and metal modified H-Beta zeolites",

abstract = "Hydrocracking of hexadecane to produce jet fuel components was investigated over proton and metal modified Beta zeolites with different acidity. They were characterized by a range of physico-chemical methods. The initial catalyst screening was performed at 210 °C under 40 bar hydrogen showing that the most promising catalysts were 2.5 wt% Pt-H-Beta-25 and 2.5 wt% Ru-H-Beta-300, which were also tested at 240 °C under 45 bar hydrogen. The results revealed that the yield of jet fuel components was maximally 27% over 2.5 wt% Pt-H-Beta-25. This catalyst gave, however, only 55% mass balance closure to the liquid phase products, while a mildly acidic 2.5 wt% Ru-H-Beta-300 afforded 24% yield of the jet fuel components and 89% liquid mass balance closure.",

author = "{Kaka khel}, Taimoor and P{\"a}ivi M{\"a}ki-Arvela and Muhammad Azkaar and Zuzana Vajglov{\'a} and Atte Aho and Jarl Hemming and Markus Peurla and Kari Er{\"a}nen and Narendra Kumar and Dmitry Murzin",

note = "tk. 3pk Taimoor Kaka khel and Muhammad Azkaar are also affiliated vith {\AA}AU. Authors can share their accepted manuscript via non-commercial hosting platforms such as their institutional repository After the embargo period 24 months Available online 19 August 2019 CC-BY-NC-ND ------------------------------------------------------------ Har kontaktat [email protected] den 10.2.2020/LN ------------------------------------------------------------",

year = "2019",

doi = "10.1016/j.mcat.2019.110515",

language = "Odefinierat/ok{\"a}nt",

volume = "476",

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journal = "Molecular Catalysis",

issn = "2468-8231",

publisher = "Elsevier",

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TY - JOUR

T1 - Hexadecane hydrocracking for production of jet fuels from renewable diesel over proton and metal modified H-Beta zeolites

AU - Kaka khel, Taimoor

AU - Mäki-Arvela, Päivi

AU - Azkaar, Muhammad

AU - Vajglová, Zuzana

AU - Aho, Atte

AU - Hemming, Jarl

AU - Peurla, Markus

AU - Eränen, Kari

AU - Kumar, Narendra

AU - Murzin, Dmitry

N1 - tk. 3pk Taimoor Kaka khel and Muhammad Azkaar are also affiliated vith ÅAU. Authors can share their accepted manuscript via non-commercial hosting platforms such as their institutional repository After the embargo period 24 months Available online 19 August 2019 CC-BY-NC-ND ------------------------------------------------------------ Har kontaktat [email protected] den 10.2.2020/LN ------------------------------------------------------------

PY - 2019

Y1 - 2019

N2 - Hydrocracking of hexadecane to produce jet fuel components was investigated over proton and metal modified Beta zeolites with different acidity. They were characterized by a range of physico-chemical methods. The initial catalyst screening was performed at 210 °C under 40 bar hydrogen showing that the most promising catalysts were 2.5 wt% Pt-H-Beta-25 and 2.5 wt% Ru-H-Beta-300, which were also tested at 240 °C under 45 bar hydrogen. The results revealed that the yield of jet fuel components was maximally 27% over 2.5 wt% Pt-H-Beta-25. This catalyst gave, however, only 55% mass balance closure to the liquid phase products, while a mildly acidic 2.5 wt% Ru-H-Beta-300 afforded 24% yield of the jet fuel components and 89% liquid mass balance closure.

AB - Hydrocracking of hexadecane to produce jet fuel components was investigated over proton and metal modified Beta zeolites with different acidity. They were characterized by a range of physico-chemical methods. The initial catalyst screening was performed at 210 °C under 40 bar hydrogen showing that the most promising catalysts were 2.5 wt% Pt-H-Beta-25 and 2.5 wt% Ru-H-Beta-300, which were also tested at 240 °C under 45 bar hydrogen. The results revealed that the yield of jet fuel components was maximally 27% over 2.5 wt% Pt-H-Beta-25. This catalyst gave, however, only 55% mass balance closure to the liquid phase products, while a mildly acidic 2.5 wt% Ru-H-Beta-300 afforded 24% yield of the jet fuel components and 89% liquid mass balance closure.

U2 - 10.1016/j.mcat.2019.110515

DO - 10.1016/j.mcat.2019.110515

M3 - Artikel

SN - 2468-8231

VL - 476

SP - –

JO - Molecular Catalysis

JF - Molecular Catalysis

ER -