Furfural Oxidation with Hydrogen Peroxide Over ZSM-5 Based Micro-Mesoporous Aluminosilicates

Nataliya D. Shcherban; Roman Yu Barakov; Sergii A. Sergiienko; Kari Eränen; Johan Wärnå; Dmitry Yu Murzin

doi:10.1007/s10562-021-03899-9

Furfural Oxidation with Hydrogen Peroxide Over ZSM-5 Based Micro-Mesoporous Aluminosilicates

Nataliya D. Shcherban, Roman Yu Barakov, Sergii A. Sergiienko, Kari Eränen, Johan Wärnå, Dmitry Yu Murzin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

6 Citations (Scopus)

Abstract

Micro-mesoporous aluminosilicates based on ZSM-5 zeolite, obtained by a dual template method, as well as in the presence of a dual-functional template (i.e. a Gemini-type surfactant), were tested in the oxidation of furfural with hydrogen peroxide. Even substantial changes in acidity and porosity of the catalysts result in minor variations of selectivity towards the desired products. Application of the synthesized zeolite-based materials in the oxidation of furfural with hydrogen peroxide leads to formation of 2(5H)-furanone (yield up to 28.5%) and succinic acid (up to 19.5%) as the main C4 reaction products. The kinetic model developed previously to treat the results for oxidation of furfural over sulfated zirconia was able to describe the data also for micro-mesoporous aluminosilicates. Graphical Abstract: [Figure not available: see fulltext.]

Original language	English
Journal	Catalysis Letters
DOIs	https://doi.org/10.1007/s10562-021-03899-9
Publication status	Published - 2021
MoE publication type	A1 Journal article-refereed

Keywords

Acid sites
Furfural oxidation
Micro-mesoporous aluminosilicate
Zeolite

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10.1007/s10562-021-03899-9

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@article{00215421495442b5b540abb3717d7200,

title = "Furfural Oxidation with Hydrogen Peroxide Over ZSM-5 Based Micro-Mesoporous Aluminosilicates",

abstract = "Micro-mesoporous aluminosilicates based on ZSM-5 zeolite, obtained by a dual template method, as well as in the presence of a dual-functional template (i.e. a Gemini-type surfactant), were tested in the oxidation of furfural with hydrogen peroxide. Even substantial changes in acidity and porosity of the catalysts result in minor variations of selectivity towards the desired products. Application of the synthesized zeolite-based materials in the oxidation of furfural with hydrogen peroxide leads to formation of 2(5H)-furanone (yield up to 28.5%) and succinic acid (up to 19.5%) as the main C4 reaction products. The kinetic model developed previously to treat the results for oxidation of furfural over sulfated zirconia was able to describe the data also for micro-mesoporous aluminosilicates. Graphical Abstract: [Figure not available: see fulltext.]",

keywords = "Acid sites, Furfural oxidation, Micro-mesoporous aluminosilicate, Zeolite",

author = "Shcherban, {Nataliya D.} and Barakov, {Roman Yu} and Sergiienko, {Sergii A.} and Kari Er{\"a}nen and Johan W{\"a}rn{\aa} and Murzin, {Dmitry Yu}",

note = "Funding Information: The authors gratefully acknowledge the financial support of the National Research Foundation of Ukraine to the project “New effective zeolite catalysts for environmentally friendly processes of the conversion of renewable raw materials into valuable organic compounds” (project number 2020.02/0335). N.S. also acknowledges the support of the Verkhovna Rada of Ukraine to a personal scholarship for young scientists—doctors of sciences for 2021. Publisher Copyright: {\textcopyright} 2021, The Author(s).",

year = "2021",

doi = "10.1007/s10562-021-03899-9",

language = "English",

journal = "Catalysis Letters",

issn = "1011-372X",

publisher = "Springer",

}

TY - JOUR

T1 - Furfural Oxidation with Hydrogen Peroxide Over ZSM-5 Based Micro-Mesoporous Aluminosilicates

AU - Shcherban, Nataliya D.

AU - Barakov, Roman Yu

AU - Sergiienko, Sergii A.

AU - Eränen, Kari

AU - Wärnå, Johan

AU - Murzin, Dmitry Yu

N1 - Funding Information: The authors gratefully acknowledge the financial support of the National Research Foundation of Ukraine to the project “New effective zeolite catalysts for environmentally friendly processes of the conversion of renewable raw materials into valuable organic compounds” (project number 2020.02/0335). N.S. also acknowledges the support of the Verkhovna Rada of Ukraine to a personal scholarship for young scientists—doctors of sciences for 2021. Publisher Copyright: © 2021, The Author(s).

PY - 2021

Y1 - 2021

N2 - Micro-mesoporous aluminosilicates based on ZSM-5 zeolite, obtained by a dual template method, as well as in the presence of a dual-functional template (i.e. a Gemini-type surfactant), were tested in the oxidation of furfural with hydrogen peroxide. Even substantial changes in acidity and porosity of the catalysts result in minor variations of selectivity towards the desired products. Application of the synthesized zeolite-based materials in the oxidation of furfural with hydrogen peroxide leads to formation of 2(5H)-furanone (yield up to 28.5%) and succinic acid (up to 19.5%) as the main C4 reaction products. The kinetic model developed previously to treat the results for oxidation of furfural over sulfated zirconia was able to describe the data also for micro-mesoporous aluminosilicates. Graphical Abstract: [Figure not available: see fulltext.]

AB - Micro-mesoporous aluminosilicates based on ZSM-5 zeolite, obtained by a dual template method, as well as in the presence of a dual-functional template (i.e. a Gemini-type surfactant), were tested in the oxidation of furfural with hydrogen peroxide. Even substantial changes in acidity and porosity of the catalysts result in minor variations of selectivity towards the desired products. Application of the synthesized zeolite-based materials in the oxidation of furfural with hydrogen peroxide leads to formation of 2(5H)-furanone (yield up to 28.5%) and succinic acid (up to 19.5%) as the main C4 reaction products. The kinetic model developed previously to treat the results for oxidation of furfural over sulfated zirconia was able to describe the data also for micro-mesoporous aluminosilicates. Graphical Abstract: [Figure not available: see fulltext.]

KW - Acid sites

KW - Furfural oxidation

KW - Micro-mesoporous aluminosilicate

KW - Zeolite

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U2 - 10.1007/s10562-021-03899-9

DO - 10.1007/s10562-021-03899-9

M3 - Article

AN - SCOPUS:85121868480

SN - 1011-372X

JO - Catalysis Letters

JF - Catalysis Letters

ER -

Furfural Oxidation with Hydrogen Peroxide Over ZSM-5 Based Micro-Mesoporous Aluminosilicates

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Keywords

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