Erbium-doped borosilicate glasses containing various amounts of P2O5 and Al2O3: influence of the silica content on the structure and thermal, physical, optical and luminescence properties

Kevin Bourhis; Jonathan Massera; Laeticia Petit; Joona Koponen; Alexandre Fargues; Thierry Cardinal; Mikko Hupa; Leena Hupa; Marc Dussauze; Vincent Rodriguez; Monica Ferraris

doi:10.1016/j.materresbull.2015.04.017

Erbium-doped borosilicate glasses containing various amounts of P2O5 and Al2O3: influence of the silica content on the structure and thermal, physical, optical and luminescence properties

Kevin Bourhis, Jonathan Massera, Laeticia Petit, Joona Koponen, Alexandre Fargues, Thierry Cardinal, Mikko Hupa, Leena Hupa, Marc Dussauze, Vincent Rodriguez, Monica Ferraris

Laboratory of Molecular Science and Engineering

Research output: Contribution to journal › Article › Scientific › peer-review

9 Citations (Scopus)

Abstract

The influence of the silica content on several properties of Er-doped borosilicate glasses in the presence of various amounts of P₂O₅ and Al₂O₃ has been investigated. The introduction of P₂O₅ and/or Al₂O₃ are responsible for structural modifications in the glass network through a charge-compensation mechanism related to the formation of negatively-charged PO₄ and AlO₄ groups or through the formation of AlPO₄-like structural units. In this paper, we show that an increase in the SiO₂ content leads to a silicate-rich environment around the Er³⁺ site, resulting in an increased dependence of the Er³⁺ ions optical and luminescence properties on the P₂O₅ and/or Al₂O₃ concentration. The highest emission intensity at 1.5 μm was achieved for the glass with an equal proportion of P and Al in the glass system with 60 mol% of SiO₂.

Original language	Undefined/Unknown
Pages (from-to)	47–54
Journal	Materials Research Bulletin
Volume	70
DOIs	https://doi.org/10.1016/j.materresbull.2015.04.017
Publication status	Published - 2015
MoE publication type	A1 Journal article-refereed

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10.1016/j.materresbull.2015.04.017

http://www.sciencedirect.com/science/article/pii/S0025540815002652

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Bourhis, K., Massera, J., Petit, L., Koponen, J., Fargues, A., Cardinal, T., Hupa, M., Hupa, L., Dussauze, M., Rodriguez, V., & Ferraris, M. (2015). Erbium-doped borosilicate glasses containing various amounts of P2O5 and Al2O3: influence of the silica content on the structure and thermal, physical, optical and luminescence properties. Materials Research Bulletin, 70, 47–54. https://doi.org/10.1016/j.materresbull.2015.04.017

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title = "Erbium-doped borosilicate glasses containing various amounts of P2O5 and Al2O3: influence of the silica content on the structure and thermal, physical, optical and luminescence properties",

abstract = "The influence of the silica content on several properties of Er-doped borosilicate glasses in the presence of various amounts of P2O5 and Al2O3 has been investigated. The introduction of P2O5 and/or Al2O3 are responsible for structural modifications in the glass network through a charge-compensation mechanism related to the formation of negatively-charged PO4 and AlO4 groups or through the formation of AlPO4-like structural units. In this paper, we show that an increase in the SiO2 content leads to a silicate-rich environment around the Er3+ site, resulting in an increased dependence of the Er3+ ions optical and luminescence properties on the P2O5 and/or Al2O3 concentration. The highest emission intensity at 1.5 μm was achieved for the glass with an equal proportion of P and Al in the glass system with 60 mol% of SiO2.",

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Bourhis, K, Massera, J, Petit, L, Koponen, J, Fargues, A, Cardinal, T, Hupa, M , Hupa, L, Dussauze, M, Rodriguez, V & Ferraris, M 2015, 'Erbium-doped borosilicate glasses containing various amounts of P2O5 and Al2O3: influence of the silica content on the structure and thermal, physical, optical and luminescence properties', Materials Research Bulletin, vol. 70, pp. 47–54. https://doi.org/10.1016/j.materresbull.2015.04.017

Erbium-doped borosilicate glasses containing various amounts of P2O5 and Al2O3: influence of the silica content on the structure and thermal, physical, optical and luminescence properties. / Bourhis, Kevin; Massera, Jonathan; Petit, Laeticia et al.
In: Materials Research Bulletin, Vol. 70, 2015, p. 47–54.

Research output: Contribution to journal › Article › Scientific › peer-review

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T1 - Erbium-doped borosilicate glasses containing various amounts of P2O5 and Al2O3: influence of the silica content on the structure and thermal, physical, optical and luminescence properties

AU - Bourhis, Kevin

AU - Massera, Jonathan

AU - Petit, Laeticia

AU - Koponen, Joona

AU - Fargues, Alexandre

AU - Cardinal, Thierry

AU - Hupa, Mikko

AU - Hupa, Leena

AU - Dussauze, Marc

AU - Rodriguez, Vincent

AU - Ferraris, Monica

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AB - The influence of the silica content on several properties of Er-doped borosilicate glasses in the presence of various amounts of P2O5 and Al2O3 has been investigated. The introduction of P2O5 and/or Al2O3 are responsible for structural modifications in the glass network through a charge-compensation mechanism related to the formation of negatively-charged PO4 and AlO4 groups or through the formation of AlPO4-like structural units. In this paper, we show that an increase in the SiO2 content leads to a silicate-rich environment around the Er3+ site, resulting in an increased dependence of the Er3+ ions optical and luminescence properties on the P2O5 and/or Al2O3 concentration. The highest emission intensity at 1.5 μm was achieved for the glass with an equal proportion of P and Al in the glass system with 60 mol% of SiO2.

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DO - 10.1016/j.materresbull.2015.04.017

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