Electrochemically Modified Poly(dicyandiamide) Electrodes for Detecting Hydrazine in Neutral pH

Gopinathan Manavalan; Thiyagarajan Natarajan; Kayode Omotayo Adeniyi; Jyh Myng Zen; Solomon Tesfalidet; Mikael Thyrel; Torbjörn A. Lestander; Subba Reddy Alla; Jyri Pekka Mikkola

doi:10.1021/acs.iecr.3c02669

Electrochemically Modified Poly(dicyandiamide) Electrodes for Detecting Hydrazine in Neutral pH

Gopinathan Manavalan^*
, Thiyagarajan Natarajan
, Kayode Omotayo Adeniyi
, Jyh Myng Zen
, Solomon Tesfalidet
, Mikael Thyrel
, Torbjörn A. Lestander
, Subba Reddy Alla
, Jyri Pekka Mikkola

^*Corresponding author for this work

Laboratory of Industrial Chemistry and Reaction Engineering

Research output: Contribution to journal › Article › Scientific › peer-review

1 Citation (Scopus)

95 Downloads (Pure)

Abstract

A new technique for sensing nanomolar concentrations of hydrazine in water samples is reported. A screen-printed carbon electrode (SPCE) altered using an amine-azo functional group encompassing poly(dicyandiamide) is used in this study. The modified electrode exhibits an enhanced activity toward hydrazine detection at a lower overpotential and broad linear scale between 20 nM and 1 mM, with an accurate sensitivity value of 0.1 nA μm^-1 cm^-2. To the best of our knowledge, poly(dicyandiamide)-modified electrodes exhibit one of the lowest limits of detection for any metal-free electrode that detects 6.7 nM (S/N = 3) of hydrazine. The method established sufficient selectivity and better recoveries. Finally, the poly(dicyandiamide)-modified SPCE* is highly suitable for electrochemical determination of hydrazine in water samples from tap and lake.

Original language	English
Pages (from-to)	18271-18279
Number of pages	9
Journal	Industrial and Engineering Chemistry Research
Volume	62
Issue number	44
DOIs	https://doi.org/10.1021/acs.iecr.3c02669
Publication status	Published - 8 Nov 2023
MoE publication type	A1 Journal article-refereed

Funding

The authors thankfully acknowledge the funding provided by the Bio4Energy programme, Kempe Foundations [JCK-JCK-2140 and JCSMK23-0075], Wallenberg Wood Science Center under auspices of Alice and Knut Wallenberg Foundation, and the Ministry of Science and Technology, Taiwan. The authors conducted experiments at the Technical Chemistry, Department of Chemistry, Chemical-Biological Centre, Umeå University, Sweden, and also at the Johan Gadolin Process Chemistry Centre at Åbo Akademi University in Finland. In this work, the authors particularly wish to honor the late Carl Kempe of Kempe Foundations who for so many years has supported them: rest in peace. They also acknowledge Dr. Shamasree Ghosh and Dr. Tamilselvi Shanmugam for their help with AFM. Additionally, this article represents a considerable portion of Gopinathan Manavalan’s doctoral research conducted at National Chung Hsing University, Taiwan.

Access to Document

10.1021/acs.iecr.3c02669

manavalan-et-al-2023-electrochemically-modified-poly(dicyandiamide)-electrodes-for-detecting-hydrazine-in-neutral-phFinal published version, 4.86 MBLicence: CC BY

https://urn.fi/URN:NBN:fi-fe202401041315

Cite this

@article{ac047cc0c878429497c43db3acb5e9d0,

title = "Electrochemically Modified Poly(dicyandiamide) Electrodes for Detecting Hydrazine in Neutral pH",

abstract = "A new technique for sensing nanomolar concentrations of hydrazine in water samples is reported. A screen-printed carbon electrode (SPCE) altered using an amine-azo functional group encompassing poly(dicyandiamide) is used in this study. The modified electrode exhibits an enhanced activity toward hydrazine detection at a lower overpotential and broad linear scale between 20 nM and 1 mM, with an accurate sensitivity value of 0.1 nA μm-1 cm-2. To the best of our knowledge, poly(dicyandiamide)-modified electrodes exhibit one of the lowest limits of detection for any metal-free electrode that detects 6.7 nM (S/N = 3) of hydrazine. The method established sufficient selectivity and better recoveries. Finally, the poly(dicyandiamide)-modified SPCE* is highly suitable for electrochemical determination of hydrazine in water samples from tap and lake.",

author = "Gopinathan Manavalan and Thiyagarajan Natarajan and Adeniyi, \{Kayode Omotayo\} and Zen, \{Jyh Myng\} and Solomon Tesfalidet and Mikael Thyrel and Lestander, \{Torbj{\"o}rn A.\} and Alla, \{Subba Reddy\} and Mikkola, \{Jyri Pekka\}",

note = "Publisher Copyright: {\textcopyright} 2023 The Authors. Published by American Chemical Society.",

year = "2023",

month = nov,

day = "8",

doi = "10.1021/acs.iecr.3c02669",

language = "English",

volume = "62",

pages = "18271--18279",

journal = "Industrial and Engineering Chemistry Research",

issn = "0888-5885",

publisher = "American chemical society",

number = "44",

}

TY - JOUR

T1 - Electrochemically Modified Poly(dicyandiamide) Electrodes for Detecting Hydrazine in Neutral pH

AU - Manavalan, Gopinathan

AU - Natarajan, Thiyagarajan

AU - Adeniyi, Kayode Omotayo

AU - Zen, Jyh Myng

AU - Tesfalidet, Solomon

AU - Thyrel, Mikael

AU - Lestander, Torbjörn A.

AU - Alla, Subba Reddy

AU - Mikkola, Jyri Pekka

PY - 2023/11/8

Y1 - 2023/11/8

N2 - A new technique for sensing nanomolar concentrations of hydrazine in water samples is reported. A screen-printed carbon electrode (SPCE) altered using an amine-azo functional group encompassing poly(dicyandiamide) is used in this study. The modified electrode exhibits an enhanced activity toward hydrazine detection at a lower overpotential and broad linear scale between 20 nM and 1 mM, with an accurate sensitivity value of 0.1 nA μm-1 cm-2. To the best of our knowledge, poly(dicyandiamide)-modified electrodes exhibit one of the lowest limits of detection for any metal-free electrode that detects 6.7 nM (S/N = 3) of hydrazine. The method established sufficient selectivity and better recoveries. Finally, the poly(dicyandiamide)-modified SPCE* is highly suitable for electrochemical determination of hydrazine in water samples from tap and lake.

AB - A new technique for sensing nanomolar concentrations of hydrazine in water samples is reported. A screen-printed carbon electrode (SPCE) altered using an amine-azo functional group encompassing poly(dicyandiamide) is used in this study. The modified electrode exhibits an enhanced activity toward hydrazine detection at a lower overpotential and broad linear scale between 20 nM and 1 mM, with an accurate sensitivity value of 0.1 nA μm-1 cm-2. To the best of our knowledge, poly(dicyandiamide)-modified electrodes exhibit one of the lowest limits of detection for any metal-free electrode that detects 6.7 nM (S/N = 3) of hydrazine. The method established sufficient selectivity and better recoveries. Finally, the poly(dicyandiamide)-modified SPCE* is highly suitable for electrochemical determination of hydrazine in water samples from tap and lake.

UR - https://www.scopus.com/pages/publications/85177814574

U2 - 10.1021/acs.iecr.3c02669

DO - 10.1021/acs.iecr.3c02669

M3 - Article

AN - SCOPUS:85177814574

SN - 0888-5885

VL - 62

SP - 18271

EP - 18279

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 44

ER -

Electrochemically Modified Poly(dicyandiamide) Electrodes for Detecting Hydrazine in Neutral pH

Abstract

Funding

Access to Document

Other files and links

Fingerprint

Cite this