Electrochemical Behaviour of Poly(benzopyrene) Films Doped with Eriochrome Black T as a Pb2+-Sensitive Sensors

Grzegorz Lisak; Michal Wagner; Carita Kvarnström; Johan Bobacka; Ari Ivaska; Andrzej Lewenstam

doi:10.1002/elan.201000459

Electrochemical Behaviour of Poly(benzopyrene) Films Doped with Eriochrome Black T as a Pb2+-Sensitive Sensors

Grzegorz Lisak, Michal Wagner, Carita Kvarnström, Johan Bobacka, Ari Ivaska, Andrzej Lewenstam

Laboratory of Molecular Science and Engineering

Research output: Contribution to journal › Article › Scientific › peer-review

23 Citations (Scopus)

Abstract

Poly(benzopyrene) films were electrosynthesized on glassy carbon disk electrodes from benzo(a) pyrene by cyclic voltammetry in the presence of eriochrome black T, which forms strong complexes with lead ions. In consequence, by conditioning the films in high concentration of lead (0.1 mol dm(-3) Pb(NO3)(2)) potentiometric sensitivity to lead ions down to 10(-5) mol dm(-3) Pb2+ was induced, and a novel type of lead-sensitive electrode was obtained. The electrode is characterized by high stability of the potential readouts, good reproducibility of the calibration curves as well as a minor hysteresis effects. The performance of our lead-sensitive electrode was favourable compared to PEDOT and PPy-based electrodes doped with eriochrome black T. We conclude that poly(benzopyrene) doped with eriochrome black T is a new electroactive material that may be applied in sensor technology.

Original language	Undefined/Unknown
Pages (from-to)	2794–2800
Number of pages	7
Journal	Electroanalysis
Volume	22
Issue number	23
DOIs	https://doi.org/10.1002/elan.201000459
Publication status	Published - 2010
MoE publication type	A1 Journal article-refereed

Keywords

Poly(benzopyrene) films
Eriochrome black T
PEDOT

Access to Document

10.1002/elan.201000459

Cite this

@article{68186417f121474d9c4639fa4181eb11,

title = "Electrochemical Behaviour of Poly(benzopyrene) Films Doped with Eriochrome Black T as a Pb2+-Sensitive Sensors",

abstract = "Poly(benzopyrene) films were electrosynthesized on glassy carbon disk electrodes from benzo(a) pyrene by cyclic voltammetry in the presence of eriochrome black T, which forms strong complexes with lead ions. In consequence, by conditioning the films in high concentration of lead (0.1 mol dm(-3) Pb(NO3)(2)) potentiometric sensitivity to lead ions down to 10(-5) mol dm(-3) Pb2+ was induced, and a novel type of lead-sensitive electrode was obtained. The electrode is characterized by high stability of the potential readouts, good reproducibility of the calibration curves as well as a minor hysteresis effects. The performance of our lead-sensitive electrode was favourable compared to PEDOT and PPy-based electrodes doped with eriochrome black T. We conclude that poly(benzopyrene) doped with eriochrome black T is a new electroactive material that may be applied in sensor technology.",

keywords = "Poly(benzopyrene) films, Eriochrome black T, PEDOT, Poly(benzopyrene) films, Eriochrome black T, PEDOT, Poly(benzopyrene) films, Eriochrome black T, PEDOT",

author = "Grzegorz Lisak and Michal Wagner and Carita Kvarnstr{\"o}m and Johan Bobacka and Ari Ivaska and Andrzej Lewenstam",

year = "2010",

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T1 - Electrochemical Behaviour of Poly(benzopyrene) Films Doped with Eriochrome Black T as a Pb2+-Sensitive Sensors

AU - Lisak, Grzegorz

AU - Wagner, Michal

AU - Kvarnström, Carita

AU - Bobacka, Johan

AU - Ivaska, Ari

AU - Lewenstam, Andrzej

PY - 2010

Y1 - 2010

N2 - Poly(benzopyrene) films were electrosynthesized on glassy carbon disk electrodes from benzo(a) pyrene by cyclic voltammetry in the presence of eriochrome black T, which forms strong complexes with lead ions. In consequence, by conditioning the films in high concentration of lead (0.1 mol dm(-3) Pb(NO3)(2)) potentiometric sensitivity to lead ions down to 10(-5) mol dm(-3) Pb2+ was induced, and a novel type of lead-sensitive electrode was obtained. The electrode is characterized by high stability of the potential readouts, good reproducibility of the calibration curves as well as a minor hysteresis effects. The performance of our lead-sensitive electrode was favourable compared to PEDOT and PPy-based electrodes doped with eriochrome black T. We conclude that poly(benzopyrene) doped with eriochrome black T is a new electroactive material that may be applied in sensor technology.

AB - Poly(benzopyrene) films were electrosynthesized on glassy carbon disk electrodes from benzo(a) pyrene by cyclic voltammetry in the presence of eriochrome black T, which forms strong complexes with lead ions. In consequence, by conditioning the films in high concentration of lead (0.1 mol dm(-3) Pb(NO3)(2)) potentiometric sensitivity to lead ions down to 10(-5) mol dm(-3) Pb2+ was induced, and a novel type of lead-sensitive electrode was obtained. The electrode is characterized by high stability of the potential readouts, good reproducibility of the calibration curves as well as a minor hysteresis effects. The performance of our lead-sensitive electrode was favourable compared to PEDOT and PPy-based electrodes doped with eriochrome black T. We conclude that poly(benzopyrene) doped with eriochrome black T is a new electroactive material that may be applied in sensor technology.

KW - Poly(benzopyrene) films

KW - Eriochrome black T

KW - PEDOT

KW - Poly(benzopyrene) films

KW - Eriochrome black T

KW - PEDOT

KW - Poly(benzopyrene) films

KW - Eriochrome black T

KW - PEDOT

U2 - 10.1002/elan.201000459

DO - 10.1002/elan.201000459

M3 - Artikel

SN - 1040-0397

VL - 22

SP - 2794

EP - 2800

JO - Electroanalysis

JF - Electroanalysis

IS - 23

ER -