Effects of pressurized hot water extraction on the nanoscale structure of birch sawdust

Paavo A. Penttilä, Petri Kilpeläinen, Lasse Tolonen, Jussi Petteri Suuronen, Herbert Sixta, Stefan Willför, Ritva Serimaa

Research output: Contribution to journalArticleScientificpeer-review

28 Citations (Scopus)

Abstract

Pressurized hot water extraction with a flow-through system was used to extract hemicelluloses and lignin from birch sawdust. The structure of the extraction residue was studied on various levels. Molecular mass distributions were determined with gel permeation chromatography and the crystal structure of cellulose was characterized using wide-angle X-ray scattering (WAXS). Information on the short-range order of cellulose microfibrils and on the nanoscale pore structure was obtained with small-angle X-ray scattering (SAXS), and the micrometre scale cellular morphology was imaged with X-ray microtomography. The pressurized hot water treatment was observed to increase the lateral width of cellulose crystallites, determined with WAXS, whereas a possible small decrease in the crystallinity of cellulose compared to native wood was detected. The molecular mass of cellulose remained at a relatively high level. According to the SAXS results, a tighter lateral association of cellulose microfibrils was observed in the extracted samples, which possibly led to opening of pores between bundles of microfibrils, as indicated by an increased specific surface area. A reduction in the thickness of the fibre cell walls was evidenced by X-ray microtomography.

Original languageEnglish
Pages (from-to)2335-2347
Number of pages13
JournalCellulose
Volume20
Issue number5
DOIs
Publication statusPublished - Oct 2013
MoE publication typeA1 Journal article-refereed

Keywords

  • Birch
  • Cellulose crystallinity
  • Hydrothermal treatment
  • Pressurized hot water extraction
  • X-ray scattering

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