Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate

Serap Sahin; Päivi Mäki-Arvela; Jean Philippe Tessonnier; Alberto Villa; Lidong Shao; Dang Sheng Su; Robert Schlögl; Tapio Salmi; Dmitry Yu Murzin

doi:10.1016/S0167-2991(10)75043-6

Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate

Serap Sahin^*, Päivi Mäki-Arvela, Jean Philippe Tessonnier, Alberto Villa, Lidong Shao, Dang Sheng Su, Robert Schlögl, Tapio Salmi, Dmitry Yu Murzin

^*Corresponding author for this work

Industrial Chemistry and Reaction Engineering

Research output: Chapter in Book/Conference proceeding › Conference contribution › Scientific › peer-review

1 Citation (Scopus)

Abstract

Catalytic activities of palladium catalysts supported on activated carbon and carbon nanotubes were investigated in the one-pot synthesis of R-1-phenylethyl acetate in combination with an immobilized lipase in toluene. Palladium catalysts on carbon nanotubes with nitrogen-containing surface groups were prepared by incipient wetness impregnation. The basic N-CNT support was synthesized by post-treating oxidized CNTs in gaseous NH₃ at high temperature, prior to Pd addition. The basic character of the support was adjusted by controlling the temperature of the post-treatment step. The results showed that the desired product yield was enhanced over palladium catalysts with the lowest basicity.

Original language	English
Title of host publication	Scientific Bases for the Preparation of Heterogeneous Catalysts - Proceedings of the 10th International Symposium
Publisher	Elsevier
Pages	283-287
Number of pages	5
ISBN (Print)	9780444536013
DOIs	https://doi.org/10.1016/S0167-2991(10)75043-6
Publication status	Published - 2010
MoE publication type	A4 Article in a conference publication

Publication series

Name	Studies in Surface Science and Catalysis
Volume	175
ISSN (Print)	0167-2991

Keywords

Acetophenone
Carbon nanotubes
Immobilized lipase
One-pot cascades

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10.1016/S0167-2991(10)75043-6

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Sahin, S., Mäki-Arvela, P., Tessonnier, J. P., Villa, A., Shao, L., Su, D. S., Schlögl, R., Salmi, T., & Murzin, D. Y. (2010). Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate. In Scientific Bases for the Preparation of Heterogeneous Catalysts - Proceedings of the 10th International Symposium (pp. 283-287). (Studies in Surface Science and Catalysis; Vol. 175). Elsevier. https://doi.org/10.1016/S0167-2991(10)75043-6

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title = "Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate",

abstract = "Catalytic activities of palladium catalysts supported on activated carbon and carbon nanotubes were investigated in the one-pot synthesis of R-1-phenylethyl acetate in combination with an immobilized lipase in toluene. Palladium catalysts on carbon nanotubes with nitrogen-containing surface groups were prepared by incipient wetness impregnation. The basic N-CNT support was synthesized by post-treating oxidized CNTs in gaseous NH3 at high temperature, prior to Pd addition. The basic character of the support was adjusted by controlling the temperature of the post-treatment step. The results showed that the desired product yield was enhanced over palladium catalysts with the lowest basicity.",

keywords = "Acetophenone, Carbon nanotubes, Immobilized lipase, One-pot cascades",

author = "Serap Sahin and P{\"a}ivi M{\"a}ki-Arvela and Tessonnier, {Jean Philippe} and Alberto Villa and Lidong Shao and Su, {Dang Sheng} and Robert Schl{\"o}gl and Tapio Salmi and Murzin, {Dmitry Yu}",

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doi = "10.1016/S0167-2991(10)75043-6",

language = "English",

isbn = "9780444536013",

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Sahin, S, Mäki-Arvela, P, Tessonnier, JP, Villa, A, Shao, L, Su, DS, Schlögl, R, Salmi, T & Murzin, DY 2010, Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate. in Scientific Bases for the Preparation of Heterogeneous Catalysts - Proceedings of the 10th International Symposium. Studies in Surface Science and Catalysis, vol. 175, Elsevier, pp. 283-287. https://doi.org/10.1016/S0167-2991(10)75043-6

Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate. / Sahin, Serap; Mäki-Arvela, Päivi; Tessonnier, Jean Philippe et al.
Scientific Bases for the Preparation of Heterogeneous Catalysts - Proceedings of the 10th International Symposium. Elsevier, 2010. p. 283-287 (Studies in Surface Science and Catalysis; Vol. 175).

Research output: Chapter in Book/Conference proceeding › Conference contribution › Scientific › peer-review

TY - GEN

T1 - Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate

AU - Sahin, Serap

AU - Mäki-Arvela, Päivi

AU - Tessonnier, Jean Philippe

AU - Villa, Alberto

AU - Shao, Lidong

AU - Su, Dang Sheng

AU - Schlögl, Robert

AU - Salmi, Tapio

AU - Murzin, Dmitry Yu

PY - 2010

Y1 - 2010

N2 - Catalytic activities of palladium catalysts supported on activated carbon and carbon nanotubes were investigated in the one-pot synthesis of R-1-phenylethyl acetate in combination with an immobilized lipase in toluene. Palladium catalysts on carbon nanotubes with nitrogen-containing surface groups were prepared by incipient wetness impregnation. The basic N-CNT support was synthesized by post-treating oxidized CNTs in gaseous NH3 at high temperature, prior to Pd addition. The basic character of the support was adjusted by controlling the temperature of the post-treatment step. The results showed that the desired product yield was enhanced over palladium catalysts with the lowest basicity.

AB - Catalytic activities of palladium catalysts supported on activated carbon and carbon nanotubes were investigated in the one-pot synthesis of R-1-phenylethyl acetate in combination with an immobilized lipase in toluene. Palladium catalysts on carbon nanotubes with nitrogen-containing surface groups were prepared by incipient wetness impregnation. The basic N-CNT support was synthesized by post-treating oxidized CNTs in gaseous NH3 at high temperature, prior to Pd addition. The basic character of the support was adjusted by controlling the temperature of the post-treatment step. The results showed that the desired product yield was enhanced over palladium catalysts with the lowest basicity.

KW - Acetophenone

KW - Carbon nanotubes

KW - Immobilized lipase

KW - One-pot cascades

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U2 - 10.1016/S0167-2991(10)75043-6

DO - 10.1016/S0167-2991(10)75043-6

M3 - Conference contribution

AN - SCOPUS:79551616367

SN - 9780444536013

T3 - Studies in Surface Science and Catalysis

SP - 283

EP - 287

BT - Scientific Bases for the Preparation of Heterogeneous Catalysts - Proceedings of the 10th International Symposium

PB - Elsevier

ER -

Sahin S, Mäki-Arvela P, Tessonnier JP, Villa A, Shao L, Su DS et al. Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate. In Scientific Bases for the Preparation of Heterogeneous Catalysts - Proceedings of the 10th International Symposium. Elsevier. 2010. p. 283-287. (Studies in Surface Science and Catalysis). doi: 10.1016/S0167-2991(10)75043-6

Effect of the carbon nanotube basicity in Pd/N-CNT catalysts on the synthesis of R-1-phenyl ethyl acetate

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