Effect of iron-subgroup metal salts on polymer cord pyrolysis

Yu V. Lugovoy; K. V. Chalov; O. P. Tkachenko; E. M. Sulman; Johan Wärnå; Dmitry Murzin

doi:10.1039/C5RA09656A

Effect of iron-subgroup metal salts on polymer cord pyrolysis

Yu V. Lugovoy
, K. V. Chalov
, O. P. Tkachenko
, E. M. Sulman
, Johan Wärnå
, Dmitry Murzin

Laboratory of Industrial Chemistry and Reaction Engineering

Research output: Contribution to journal › Article › Scientific › peer-review

5 Citations (Scopus)

Abstract

For the first time, the effects of iron-subgroup metal chlorides on polymer cord conversion to liquid and gaseous pyrolysis products have been studied. The optimum parameters for pyrolysis were identified (T = 450 °C, CoCl₂ 2 wt%). The presence of aprotic acidic centers of the iron-subgroup metal chlorides on the polymer cord was confirmed by FTIR. The catalytic effect of iron-subgroup metal chlorides is predominantly attributed to the acidic properties of the catalysts used.

Original language	Undefined/Unknown
Pages (from-to)	56460–56469
Journal	RSC Advances
Volume	5
Issue number	70
DOIs	https://doi.org/10.1039/C5RA09656A
Publication status	Published - 2015
MoE publication type	A1 Journal article-refereed

Access to Document

10.1039/C5RA09656A

http://pubs.rsc.org/en/content/articlelanding/2015/ra/c5ra09656a#!divAbstract

Cite this

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title = "Effect of iron-subgroup metal salts on polymer cord pyrolysis",

abstract = "For the first time, the effects of iron-subgroup metal chlorides on polymer cord conversion to liquid and gaseous pyrolysis products have been studied. The optimum parameters for pyrolysis were identified (T = 450 °C, CoCl2 2 wt\%). The presence of aprotic acidic centers of the iron-subgroup metal chlorides on the polymer cord was confirmed by FTIR. The catalytic effect of iron-subgroup metal chlorides is predominantly attributed to the acidic properties of the catalysts used.",

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T1 - Effect of iron-subgroup metal salts on polymer cord pyrolysis

AU - V. Lugovoy, Yu

AU - V. Chalov, K.

AU - P. Tkachenko, O.

AU - M. Sulman, E.

AU - Wärnå, Johan

AU - Murzin, Dmitry

N1 - tk.

PY - 2015

Y1 - 2015

N2 - For the first time, the effects of iron-subgroup metal chlorides on polymer cord conversion to liquid and gaseous pyrolysis products have been studied. The optimum parameters for pyrolysis were identified (T = 450 °C, CoCl2 2 wt%). The presence of aprotic acidic centers of the iron-subgroup metal chlorides on the polymer cord was confirmed by FTIR. The catalytic effect of iron-subgroup metal chlorides is predominantly attributed to the acidic properties of the catalysts used.

AB - For the first time, the effects of iron-subgroup metal chlorides on polymer cord conversion to liquid and gaseous pyrolysis products have been studied. The optimum parameters for pyrolysis were identified (T = 450 °C, CoCl2 2 wt%). The presence of aprotic acidic centers of the iron-subgroup metal chlorides on the polymer cord was confirmed by FTIR. The catalytic effect of iron-subgroup metal chlorides is predominantly attributed to the acidic properties of the catalysts used.

U2 - 10.1039/C5RA09656A

DO - 10.1039/C5RA09656A

M3 - Artikel

VL - 5

SP - 56460

EP - 56469

JO - RSC Advances

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IS - 70

ER -