Direct Synthesis of 1-Butanol from Ethanol in a Plug Flow Reactor: Reactor and Reaction Kinetics Modeling

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Abstract

Bio-ethanol is well known for its use as a gasoline additive. However, it can be blended in low portions to traditional gasoline although it has a corrosive nature. By taking advantage of modern continuous reactor technology and heterogeneous alumina catalysts, ethanol can be upgraded to 1-butanol in fixed beds. Butanol has more feasible properties as fuel component in comparison to ethanol. Mathematical modeling of reaction kinetics revealed a simple kinetic model could be used to describe the complex reaction process on a Cu/alumina catalyst. The reaction kinetics model is based on five parallel reactions in which ethanol reacts to 1-butanol, acetealdehyde, ethyl acetate, diethyl ether and diethoxyethane, respectively.
Original languageUndefined/Unknown
Pages (from-to)1425–1429
JournalTopics in Catalysis
Volume57
Issue number17-20
DOIs
Publication statusPublished - 2014
MoE publication typeA1 Journal article-refereed

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