Conventional synthesis methods of short-chain dialkylcarbonates and novel production technology via direct route from alcohol and waste CO2

E. Leino; P. Mäki-Arvela; V. Eta; D. Yu Murzin; T. Salmi; J.-P. Mikkola

doi:10.1016/j.apcata.2010.05.046

Conventional synthesis methods of short-chain dialkylcarbonates and novel production technology via direct route from alcohol and waste CO₂

Research output: Contribution to journal › Review Article or Literature Review › peer-review

99 Citations (Scopus)

Abstract

The aim of this work is to review different synthesis methods of dialkylcarbonates with special emphasis on diethyl carbonate synthesis methodologies. The novel synthesis route for dimethyl carbonate and diethyl carbonate based on the utilization of alcohol and carbon dioxide as the raw materials, together with heterogeneous catalysts, is presented.

Original language	English
Pages (from-to)	1-13
Number of pages	13
Journal	Applied Catalysis A: General
Volume	383
Issue number	1-2
DOIs	https://doi.org/10.1016/j.apcata.2010.05.046
Publication status	Published - 31 Jul 2010
MoE publication type	A2 Review article in a scientific journal

Funding

This work is part of the activities at the Åbo Akademi Process Chemistry Centre (ÅA-PCC) within the Finnish Centre of Excellence Programme (2000–2011) appointed by the Academy of Finland. The authors are grateful to the Academy of Finland for the financial support under the grant 129170 . This work is also associated with the activities of Umeå University Technical Chemistry whereupon financial support from Umeå University, Kempe foundations and Knut & Alice Wallenberg foundation are acknowledged.

Keywords

Carbon dioxide
Diethyl carbonate
Dimethyl carbonate
Palladium-copper chloride
Zirconia

Access to Document

10.1016/j.apcata.2010.05.046Licence: Publisher rights policy

Cite this

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title = "Conventional synthesis methods of short-chain dialkylcarbonates and novel production technology via direct route from alcohol and waste CO2",

abstract = "The aim of this work is to review different synthesis methods of dialkylcarbonates with special emphasis on diethyl carbonate synthesis methodologies. The novel synthesis route for dimethyl carbonate and diethyl carbonate based on the utilization of alcohol and carbon dioxide as the raw materials, together with heterogeneous catalysts, is presented.",

keywords = "Carbon dioxide, Diethyl carbonate, Dimethyl carbonate, Palladium-copper chloride, Zirconia",

author = "E. Leino and P. M{\"a}ki-Arvela and V. Eta and Murzin, \{D. Yu\} and T. Salmi and J.-P. Mikkola",

note = "Funding Information: This work is part of the activities at the {\AA}bo Akademi Process Chemistry Centre ({\AA}A-PCC) within the Finnish Centre of Excellence Programme (2000{\textendash}2011) appointed by the Academy of Finland. The authors are grateful to the Academy of Finland for the financial support under the grant 129170 . This work is also associated with the activities of Ume{\aa} University Technical Chemistry whereupon financial support from Ume{\aa} University, Kempe foundations and Knut \& Alice Wallenberg foundation are acknowledged. Copyright: Copyright 2018 Elsevier B.V., All rights reserved.",

year = "2010",

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doi = "10.1016/j.apcata.2010.05.046",

language = "English",

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T1 - Conventional synthesis methods of short-chain dialkylcarbonates and novel production technology via direct route from alcohol and waste CO2

AU - Leino, E.

AU - Mäki-Arvela, P.

AU - Eta, V.

AU - Murzin, D. Yu

AU - Salmi, T.

AU - Mikkola, J.-P.

N1 - Funding Information: This work is part of the activities at the Åbo Akademi Process Chemistry Centre (ÅA-PCC) within the Finnish Centre of Excellence Programme (2000–2011) appointed by the Academy of Finland. The authors are grateful to the Academy of Finland for the financial support under the grant 129170 . This work is also associated with the activities of Umeå University Technical Chemistry whereupon financial support from Umeå University, Kempe foundations and Knut & Alice Wallenberg foundation are acknowledged. Copyright: Copyright 2018 Elsevier B.V., All rights reserved.

PY - 2010/7/31

Y1 - 2010/7/31

N2 - The aim of this work is to review different synthesis methods of dialkylcarbonates with special emphasis on diethyl carbonate synthesis methodologies. The novel synthesis route for dimethyl carbonate and diethyl carbonate based on the utilization of alcohol and carbon dioxide as the raw materials, together with heterogeneous catalysts, is presented.

AB - The aim of this work is to review different synthesis methods of dialkylcarbonates with special emphasis on diethyl carbonate synthesis methodologies. The novel synthesis route for dimethyl carbonate and diethyl carbonate based on the utilization of alcohol and carbon dioxide as the raw materials, together with heterogeneous catalysts, is presented.

KW - Carbon dioxide

KW - Diethyl carbonate

KW - Dimethyl carbonate

KW - Palladium-copper chloride

KW - Zirconia

UR - https://www.scopus.com/pages/publications/77954771272

U2 - 10.1016/j.apcata.2010.05.046

DO - 10.1016/j.apcata.2010.05.046

M3 - Review Article or Literature Review

AN - SCOPUS:77954771272

SN - 0926-860X

VL - 383

SP - 1

EP - 13

JO - Applied Catalysis A: General

JF - Applied Catalysis A: General

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