Catalytic conversion of hexanol to 2-butyl-octanol through the Guerbet reaction

Frans Storgårds, Päivi Mäki-Arvela, Narendra Kumar, Janne Peltonen, Jarno Salonen, Markus Perula, Kari Eränen, Vincenzo Russo, Dmitry Murzin, Henrik Grénman

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Activity of heterogeneous catalysts for synthesis of Guerbet alcohols from hexanol was evaluated. Commercial synthetic hydrotalcite (HT) was used in the aldol condensation reaction, which is a part of the Guerbet reaction network. HTs were calcined at different temperatures in order to modify their basicity and additionally, NaOH was applied in some experiments as a homogeneous base. The homogeneous base proved to be more efficient in aldol condensation experiments, while HT also performed in an acceptable way. Bi-functional metal containing HTs were synthesized by wet impregnation and co-precipitation methods employing different active metals. The materials were characterized with a number of methods, including CO2-TPD, pyridine-FTIR, nitrogen physisorption, transmission electron microscopy, SEM–EDX and XRD. Copper containing catalysts produced hexyl-hexanoate with a very high selectivity, while Ni-containing counterparts exhibited the highest selectivity towards the Guerbet alcohol. The co-precipitated catalysts were more active in the current study than the ones produced by wet-impregnation. Nevertheless, synthesis of Guerbet alcohols from hexanol with a one-pot method proved to be challenging, with the best yield of the Guerbet product in 24 h being 5%. This is proposed to be largely due to thermodynamic limitations, which was confirmed by calculations of thermodynamics.

Original languageUndefined/Unknown
Pages (from-to)1888–1900
JournalTopics in Catalysis
Issue number18-19
Publication statusPublished - 2018
MoE publication typeA1 Journal article-refereed


  • Chemical Engineering

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