Catalyst deactivation in diborane decomposition

Mats Söderlund; Päivi Mäki-Arvela; Kari Eränen; Tapio Salmi; Risto Rahkola; Dmitry Yu Murzin

doi:10.1007/s10562-005-8690-9

Catalyst deactivation in diborane decomposition

Mats Söderlund, Päivi Mäki-Arvela, Kari Eränen, Tapio Salmi, Risto Rahkola, Dmitry Yu Murzin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

32 Citations (Scopus)

Abstract

Both thermal and catalytic decomposition of diborane resulting in borane as the main product were investigated under the pressure and temperature ranges of 2-15 bar and 100-300 °C, respectively over Al₂O₃ and Pt/Al₂O₃ in a fixed bed reactor. Catalytic decomposition rate was essentially higher than the thermal decomposition, however the catalyst deactivation was substantial.

Original language	English
Pages (from-to)	191-202
Number of pages	12
Journal	Catalysis Letters
Volume	105
Issue number	3-4
DOIs	https://doi.org/10.1007/s10562-005-8690-9
Publication status	Published - Dec 2005
MoE publication type	A1 Journal article-refereed

Keywords

Boron hydrides
Catalytic decomposition
Deactivation
Diborane

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abstract = "Both thermal and catalytic decomposition of diborane resulting in borane as the main product were investigated under the pressure and temperature ranges of 2-15 bar and 100-300 °C, respectively over Al2O3 and Pt/Al2O3 in a fixed bed reactor. Catalytic decomposition rate was essentially higher than the thermal decomposition, however the catalyst deactivation was substantial.",

keywords = "Boron hydrides, Catalytic decomposition, Deactivation, Diborane",

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AU - Söderlund, Mats

AU - Mäki-Arvela, Päivi

AU - Eränen, Kari

AU - Salmi, Tapio

AU - Rahkola, Risto

AU - Murzin, Dmitry Yu

PY - 2005/12

Y1 - 2005/12

N2 - Both thermal and catalytic decomposition of diborane resulting in borane as the main product were investigated under the pressure and temperature ranges of 2-15 bar and 100-300 °C, respectively over Al2O3 and Pt/Al2O3 in a fixed bed reactor. Catalytic decomposition rate was essentially higher than the thermal decomposition, however the catalyst deactivation was substantial.

AB - Both thermal and catalytic decomposition of diborane resulting in borane as the main product were investigated under the pressure and temperature ranges of 2-15 bar and 100-300 °C, respectively over Al2O3 and Pt/Al2O3 in a fixed bed reactor. Catalytic decomposition rate was essentially higher than the thermal decomposition, however the catalyst deactivation was substantial.

KW - Boron hydrides

KW - Catalytic decomposition

KW - Deactivation

KW - Diborane

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M3 - Article

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JO - Catalysis Letters

JF - Catalysis Letters

IS - 3-4

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Catalyst deactivation in diborane decomposition

Abstract

Keywords

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