Biomass to value added chemicals: isomerisation of β-pinene oxide over supported ionic liquid catalysts (SILCAs) containing Lewis acids

Eero Salminen; Luis Rujana; Päivi Mäki-Arvela; Pasi Virtanen; Tapio Salmi; Jyri-Pekka Mikkola

doi:10.1016/j.cattod.2014.05.024

Biomass to value added chemicals: isomerisation of β-pinene oxide over supported ionic liquid catalysts (SILCAs) containing Lewis acids

Eero Salminen, Luis Rujana, Päivi Mäki-Arvela, Pasi Virtanen, Tapio Salmi, Jyri-Pekka Mikkola

Research output: Contribution to journal › Article › Scientific › peer-review

21 Citations (Scopus)

Abstract

The isomerisation of β-pinene oxide was studied over supported ionic liquid catalysts (SILCAs) consisting of Lewis acids in immobilized ionic liquid. SILCAs were demonstrated as efficient catalysts for the transformation of β-pinene oxide to myrtanal with the product distribution and activity being dependent on the nature of the ionic liquid and Lewis acid strength of catalytic species. With the catalyst ZnCl₂/[N(3-OH-Pr)Py][NTf₂]/ACC, the highest myrtanal molar yield obtained was 68%.

Original language	Undefined/Unknown
Pages (from-to)	318–321
Journal	Catalysis Today
Volume	257, Part 2
DOIs	https://doi.org/10.1016/j.cattod.2014.05.024
Publication status	Published - 2015
MoE publication type	A1 Journal article-refereed

Access to Document

10.1016/j.cattod.2014.05.024

http://www.sciencedirect.com/science/article/pii/S0920586114003940

Cite this

@article{4e94d5ced54e48f88d5df89e9f749df9,

title = "Biomass to value added chemicals: isomerisation of β-pinene oxide over supported ionic liquid catalysts (SILCAs) containing Lewis acids",

abstract = "The isomerisation of β-pinene oxide was studied over supported ionic liquid catalysts (SILCAs) consisting of Lewis acids in immobilized ionic liquid. SILCAs were demonstrated as efficient catalysts for the transformation of β-pinene oxide to myrtanal with the product distribution and activity being dependent on the nature of the ionic liquid and Lewis acid strength of catalytic species. With the catalyst ZnCl2/[N(3-OH-Pr)Py][NTf2]/ACC, the highest myrtanal molar yield obtained was 68%.",

author = "Eero Salminen and Luis Rujana and P{\"a}ivi M{\"a}ki-Arvela and Pasi Virtanen and Tapio Salmi and Jyri-Pekka Mikkola",

note = "tk. Published online 2014 WOS: Biomass to value added chemicals: Isomerisation of beta-pinene oxide over supported ionic liquid catalysts (SILCAs) containing Lewis acids",

year = "2015",

doi = "10.1016/j.cattod.2014.05.024",

language = "Odefinierat/ok{\"a}nt",

volume = "257, Part 2",

pages = "318–321",

journal = "Catalysis Today",

issn = "0920-5861",

publisher = "Elsevier",

}

TY - JOUR

T1 - Biomass to value added chemicals: isomerisation of β-pinene oxide over supported ionic liquid catalysts (SILCAs) containing Lewis acids

AU - Salminen, Eero

AU - Rujana, Luis

AU - Mäki-Arvela, Päivi

AU - Virtanen, Pasi

AU - Salmi, Tapio

AU - Mikkola, Jyri-Pekka

N1 - tk. Published online 2014 WOS: Biomass to value added chemicals: Isomerisation of beta-pinene oxide over supported ionic liquid catalysts (SILCAs) containing Lewis acids

PY - 2015

Y1 - 2015

N2 - The isomerisation of β-pinene oxide was studied over supported ionic liquid catalysts (SILCAs) consisting of Lewis acids in immobilized ionic liquid. SILCAs were demonstrated as efficient catalysts for the transformation of β-pinene oxide to myrtanal with the product distribution and activity being dependent on the nature of the ionic liquid and Lewis acid strength of catalytic species. With the catalyst ZnCl2/[N(3-OH-Pr)Py][NTf2]/ACC, the highest myrtanal molar yield obtained was 68%.

AB - The isomerisation of β-pinene oxide was studied over supported ionic liquid catalysts (SILCAs) consisting of Lewis acids in immobilized ionic liquid. SILCAs were demonstrated as efficient catalysts for the transformation of β-pinene oxide to myrtanal with the product distribution and activity being dependent on the nature of the ionic liquid and Lewis acid strength of catalytic species. With the catalyst ZnCl2/[N(3-OH-Pr)Py][NTf2]/ACC, the highest myrtanal molar yield obtained was 68%.

U2 - 10.1016/j.cattod.2014.05.024

DO - 10.1016/j.cattod.2014.05.024

M3 - Artikel

SN - 0920-5861

VL - 257, Part 2

SP - 318

EP - 321

JO - Catalysis Today

JF - Catalysis Today

ER -