Application of steel industry slags as novel cost efficient catalysts in catalytic fast pyrolysis of biomass

J. Lehtonen; T. Ohra-Aho; C. Lindfors; E. Kholkina; N. Kumar; Dmitry Murzin; A. Oasmaa

doi:10.5071/26thEUBCE2018-3DO.6.2

Application of steel industry slags as novel cost efficient catalysts in catalytic fast pyrolysis of biomass

J. Lehtonen^*, T. Ohra-Aho, C. Lindfors, E. Kholkina, N. Kumar, Dmitry Murzin, A. Oasmaa

^*Corresponding author for this work

Industrial Chemistry and Reaction Engineering

Research output: Chapter in Book/Conference proceeding › Conference contribution › Scientific

Abstract

Slags from metallurgical industry are cost efficient alternatives for acidic zeolites in catalytic fast pyrolysis. A slag from steel industry was studied for catalytic fast pyrolysis of pine sawdust. The desulfurization slag from a blast furnace steel mill was modified to improve its catalytic properties by using alkaline pretreatments and hydrothermal syntheses. As a result, specific surface area of the material could be increased. Modified desulfurization slags were tested using analytical pyrolysis and bench scale bubbling fluidized bed pyrolyser. Results of analytical pyrolysis indicate that slags are able to modify product distribution. Based on these results, the best modified slag was chosen for bench scale pyrolysis tests. In the bench scale run, the use of modified slag led to oxygenated bio oil compared to fast pyrolysis with sand. However, bio oil yield decreased simultaneously as typically in catalytic fast pyrolysis.

Original language	English
Title of host publication	Proceedings of the 26th European Biomass Conference and Exhibition
Publisher	ETA-Florence Renewable Energies
Pages	1014-1018
Number of pages	5
Volume	2018
Edition	26thEUBCE
ISBN (Print)	978-88-89407-18-9
DOIs	https://doi.org/10.5071/26thEUBCE2018-3DO.6.2
Publication status	Published - 1 May 2018
MoE publication type	B3 Non-refereed article in conference proceedings
Event	26th European Biomass Conference and Exhibition, EUBCE 2018 - Copenhagen, Denmark Duration: 14 May 2018 → 17 May 2018

Publication series

Name	European Biomass Conference and Exhibition Proceedings

Conference

Conference	26th European Biomass Conference and Exhibition, EUBCE 2018
Abbreviated title	EUBCE 2018
Country	Denmark
City	Copenhagen
Period	14/05/18 → 17/05/18

Keywords

Catalyst
Fast pyrolysis
Liquefaction
Thermochemical conversion

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Lehtonen, J., Ohra-Aho, T., Lindfors, C., Kholkina, E., Kumar, N., Murzin, D., & Oasmaa, A. (2018). Application of steel industry slags as novel cost efficient catalysts in catalytic fast pyrolysis of biomass. In Proceedings of the 26th European Biomass Conference and Exhibition (26thEUBCE ed., Vol. 2018, pp. 1014-1018). (European Biomass Conference and Exhibition Proceedings). ETA-Florence Renewable Energies. https://doi.org/10.5071/26thEUBCE2018-3DO.6.2

Lehtonen, J. ; Ohra-Aho, T. ; Lindfors, C. ; Kholkina, E. ; Kumar, N. ; Murzin, Dmitry ; Oasmaa, A. / Application of steel industry slags as novel cost efficient catalysts in catalytic fast pyrolysis of biomass. Proceedings of the 26th European Biomass Conference and Exhibition. Vol. 2018 26thEUBCE. ed. ETA-Florence Renewable Energies, 2018. pp. 1014-1018 (European Biomass Conference and Exhibition Proceedings).

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title = "Application of steel industry slags as novel cost efficient catalysts in catalytic fast pyrolysis of biomass",

abstract = "Slags from metallurgical industry are cost efficient alternatives for acidic zeolites in catalytic fast pyrolysis. A slag from steel industry was studied for catalytic fast pyrolysis of pine sawdust. The desulfurization slag from a blast furnace steel mill was modified to improve its catalytic properties by using alkaline pretreatments and hydrothermal syntheses. As a result, specific surface area of the material could be increased. Modified desulfurization slags were tested using analytical pyrolysis and bench scale bubbling fluidized bed pyrolyser. Results of analytical pyrolysis indicate that slags are able to modify product distribution. Based on these results, the best modified slag was chosen for bench scale pyrolysis tests. In the bench scale run, the use of modified slag led to oxygenated bio oil compared to fast pyrolysis with sand. However, bio oil yield decreased simultaneously as typically in catalytic fast pyrolysis.",

keywords = "Catalyst, Fast pyrolysis, Liquefaction, Thermochemical conversion",

author = "J. Lehtonen and T. Ohra-Aho and C. Lindfors and E. Kholkina and N. Kumar and Dmitry Murzin and A. Oasmaa",

note = "Funding Information: Tekes – the Finnish Funding Agency for Innovation – is acknowledged for funding project “High Value Bio-oils for Transportation and Diesel Power Plants” via the Green Growth program. Publisher Copyright: {\textcopyright} 2018 ETA-Florence Renewable Energies. Copyright: Copyright 2018 Elsevier B.V., All rights reserved.; 26th European Biomass Conference and Exhibition, EUBCE 2018, EUBCE 2018 ; Conference date: 14-05-2018 Through 17-05-2018",

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doi = "10.5071/26thEUBCE2018-3DO.6.2",

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publisher = "ETA-Florence Renewable Energies",

pages = "1014--1018",

booktitle = "Proceedings of the 26th European Biomass Conference and Exhibition",

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Lehtonen, J, Ohra-Aho, T, Lindfors, C, Kholkina, E , Kumar, N , Murzin, D & Oasmaa, A 2018, Application of steel industry slags as novel cost efficient catalysts in catalytic fast pyrolysis of biomass. in Proceedings of the 26th European Biomass Conference and Exhibition. 26thEUBCE edn, vol. 2018, European Biomass Conference and Exhibition Proceedings, ETA-Florence Renewable Energies, pp. 1014-1018, 26th European Biomass Conference and Exhibition, EUBCE 2018, Copenhagen, Denmark, 14/05/18. https://doi.org/10.5071/26thEUBCE2018-3DO.6.2

Application of steel industry slags as novel cost efficient catalysts in catalytic fast pyrolysis of biomass. / Lehtonen, J.; Ohra-Aho, T.; Lindfors, C.; Kholkina, E.; Kumar, N.; Murzin, Dmitry; Oasmaa, A.

Proceedings of the 26th European Biomass Conference and Exhibition. Vol. 2018 26thEUBCE. ed. ETA-Florence Renewable Energies, 2018. p. 1014-1018 (European Biomass Conference and Exhibition Proceedings).

Research output: Chapter in Book/Conference proceeding › Conference contribution › Scientific

TY - GEN

T1 - Application of steel industry slags as novel cost efficient catalysts in catalytic fast pyrolysis of biomass

AU - Lehtonen, J.

AU - Ohra-Aho, T.

AU - Lindfors, C.

AU - Kholkina, E.

AU - Kumar, N.

AU - Murzin, Dmitry

AU - Oasmaa, A.

N1 - Funding Information: Tekes – the Finnish Funding Agency for Innovation – is acknowledged for funding project “High Value Bio-oils for Transportation and Diesel Power Plants” via the Green Growth program. Publisher Copyright: © 2018 ETA-Florence Renewable Energies. Copyright: Copyright 2018 Elsevier B.V., All rights reserved.

PY - 2018/5/1

Y1 - 2018/5/1

N2 - Slags from metallurgical industry are cost efficient alternatives for acidic zeolites in catalytic fast pyrolysis. A slag from steel industry was studied for catalytic fast pyrolysis of pine sawdust. The desulfurization slag from a blast furnace steel mill was modified to improve its catalytic properties by using alkaline pretreatments and hydrothermal syntheses. As a result, specific surface area of the material could be increased. Modified desulfurization slags were tested using analytical pyrolysis and bench scale bubbling fluidized bed pyrolyser. Results of analytical pyrolysis indicate that slags are able to modify product distribution. Based on these results, the best modified slag was chosen for bench scale pyrolysis tests. In the bench scale run, the use of modified slag led to oxygenated bio oil compared to fast pyrolysis with sand. However, bio oil yield decreased simultaneously as typically in catalytic fast pyrolysis.

AB - Slags from metallurgical industry are cost efficient alternatives for acidic zeolites in catalytic fast pyrolysis. A slag from steel industry was studied for catalytic fast pyrolysis of pine sawdust. The desulfurization slag from a blast furnace steel mill was modified to improve its catalytic properties by using alkaline pretreatments and hydrothermal syntheses. As a result, specific surface area of the material could be increased. Modified desulfurization slags were tested using analytical pyrolysis and bench scale bubbling fluidized bed pyrolyser. Results of analytical pyrolysis indicate that slags are able to modify product distribution. Based on these results, the best modified slag was chosen for bench scale pyrolysis tests. In the bench scale run, the use of modified slag led to oxygenated bio oil compared to fast pyrolysis with sand. However, bio oil yield decreased simultaneously as typically in catalytic fast pyrolysis.

KW - Catalyst

KW - Fast pyrolysis

KW - Liquefaction

KW - Thermochemical conversion

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M3 - Conference contribution

AN - SCOPUS:85051030571

SN - 978-88-89407-18-9

VL - 2018

T3 - European Biomass Conference and Exhibition Proceedings

SP - 1014

EP - 1018

BT - Proceedings of the 26th European Biomass Conference and Exhibition

PB - ETA-Florence Renewable Energies

T2 - 26th European Biomass Conference and Exhibition, EUBCE 2018

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ER -

Lehtonen J, Ohra-Aho T, Lindfors C, Kholkina E , Kumar N , Murzin D et al. Application of steel industry slags as novel cost efficient catalysts in catalytic fast pyrolysis of biomass. In Proceedings of the 26th European Biomass Conference and Exhibition. 26thEUBCE ed. Vol. 2018. ETA-Florence Renewable Energies. 2018. p. 1014-1018. (European Biomass Conference and Exhibition Proceedings). https://doi.org/10.5071/26thEUBCE2018-3DO.6.2

Application of steel industry slags as novel cost efficient catalysts in catalytic fast pyrolysis of biomass

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Keywords

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