Ammonia chemistry in a flameless jet

M Zieba, Anders Brink, A Schuster, Mikko Hupa, G Scheffknecht

    Research output: Contribution to journalArticleScientificpeer-review

    23 Citations (Scopus)

    Abstract

    In this paper, the nitrogen chemistry in an ammonia (NH(3)) doped flameless jet is investigated using a kinetic reactor network model. The reactor network model is used to explain the main differences in ammonia chemistry for methane (CH(4)) containing fuels and methane-free fuels. The chemical pathways of nitrogen oxides (NO(x)) formation and destruction are identified using rate-of-production analysis. The results show that in the case of natural gas, ammonia reacts relatively late at fuel lean condition leading to high NOx emissions. In the pre-ignition zone, the ammonia chemistry is blocked due to the absence of free radicals which are consumed by methane-methyl radical (CH(3)) conversion. In the case of methane-free gas, the ammonia reacted very rapidly and complete decomposition was reached in the fuel rich region of the jet. In this case the necessary radicals for the ammonia conversion are generated from hydrogen (H(2)) oxidation.
    Original languageUndefined/Unknown
    Pages (from-to)1950–1956
    Number of pages7
    JournalCombustion and Flame
    Volume156
    Issue number10
    DOIs
    Publication statusPublished - 2009
    MoE publication typeA1 Journal article-refereed

    Keywords

    • Ammonia conversion
    • Flameless combustion
    • Fuel-NO(x)

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