A Simulation Case Study for Bio-based Hydrogen Production from Hardwood Hemicellulose

Ville Tuppurainen; Jani Kangas; Juha Ahola; Juha Tanskanen; Atte Aho; Henrik Grénman; Dmitry Yu Murzin; Tapio Salmi

doi:10.1016/B978-0-12-823377-1.50290-1

A Simulation Case Study for Bio-based Hydrogen Production from Hardwood Hemicellulose

Ville Tuppurainen, Jani Kangas, Juha Ahola, Juha Tanskanen, Atte Aho, Henrik Grénman, Dmitry Yu Murzin, Tapio Salmi

Research output: Chapter in Book/Conference proceeding › Conference contribution › Scientific › peer-review

Abstract

A novel bio-based hydrogen production process concept is simulated using Aspen Plus software. In the concept, hemicellulose is first extracted from birch wood using aqueous formic acid (FA). The dilute FA is then decomposed and used synergistically as a source of H₂. The hemicellulose monosaccharides in the dilute aqueous hydrolysate are hydrogenated to their corresponding sugar alcohols, which are further processed to H₂, various alkanes and carbon dioxide using aqueous phase reforming (APR). In addition to H₂ and electricity, cellulose and lignin rich solid wood fraction is produced. However, the case study revealed high heating requirements of dilute aqueous hydrolysate stream to APR reaction temperatures. High degree of APR effluent recycling to the extraction stage is considered, resulting in a relatively high concentration of the required fresh FA stream in the process concept.

Original language	English
Title of host publication	Computer Aided Chemical Engineering
Publisher	Elsevier B.V.
Pages	1735-1740
Number of pages	6
ISBN (Electronic)	978-0-12-823378-8
ISBN (Print)	978-0-12-823377-1
DOIs	https://doi.org/10.1016/B978-0-12-823377-1.50290-1
Publication status	Published - Jan 2020
MoE publication type	A4 Article in a conference publication
Event	30th European Symposium on Computer Aided Process Engineering - Milan, Italy Duration: 24 May 2020 → 27 May 2020 Conference number: 30

Publication series

Name	Computer Aided Chemical Engineering
Volume	48
ISSN (Print)	1570-7946

Conference

Conference	30th European Symposium on Computer Aided Process Engineering
Abbreviated title	ESCAPE)
Country	Italy
City	Milan
Period	24/05/20 → 27/05/20

Keywords

Aqueous Phase Reforming
Bio-based Hydrogen
Hemicellulose Extraction

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title = "A Simulation Case Study for Bio-based Hydrogen Production from Hardwood Hemicellulose",

abstract = "A novel bio-based hydrogen production process concept is simulated using Aspen Plus software. In the concept, hemicellulose is first extracted from birch wood using aqueous formic acid (FA). The dilute FA is then decomposed and used synergistically as a source of H2. The hemicellulose monosaccharides in the dilute aqueous hydrolysate are hydrogenated to their corresponding sugar alcohols, which are further processed to H2, various alkanes and carbon dioxide using aqueous phase reforming (APR). In addition to H2 and electricity, cellulose and lignin rich solid wood fraction is produced. However, the case study revealed high heating requirements of dilute aqueous hydrolysate stream to APR reaction temperatures. High degree of APR effluent recycling to the extraction stage is considered, resulting in a relatively high concentration of the required fresh FA stream in the process concept.",

keywords = "Aqueous Phase Reforming, Bio-based Hydrogen, Hemicellulose Extraction",

author = "Ville Tuppurainen and Jani Kangas and Juha Ahola and Juha Tanskanen and Atte Aho and Henrik Gr{\'e}nman and Murzin, {Dmitry Yu} and Tapio Salmi",

note = "Funding Information: The authors are grateful for the financial support from Business Finland (Biohydrogen from wood hemicellulose hydrolysate, HemiH2, 2017-2019). Publisher Copyright: {\textcopyright} 2020 Elsevier B.V. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.; 30th European Symposium on Computer Aided Process Engineering, ESCAPE) ; Conference date: 24-05-2020 Through 27-05-2020",

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Tuppurainen, V, Kangas, J, Ahola, J, Tanskanen, J, Aho, A , Grénman, H , Murzin, DY & Salmi, T 2020, A Simulation Case Study for Bio-based Hydrogen Production from Hardwood Hemicellulose. in Computer Aided Chemical Engineering. Computer Aided Chemical Engineering, vol. 48, Elsevier B.V., pp. 1735-1740, 30th European Symposium on Computer Aided Process Engineering, Milan, Italy, 24/05/20. https://doi.org/10.1016/B978-0-12-823377-1.50290-1

A Simulation Case Study for Bio-based Hydrogen Production from Hardwood Hemicellulose. / Tuppurainen, Ville; Kangas, Jani; Ahola, Juha; Tanskanen, Juha; Aho, Atte ; Grénman, Henrik ; Murzin, Dmitry Yu ; Salmi, Tapio.

Computer Aided Chemical Engineering. Elsevier B.V., 2020. p. 1735-1740 (Computer Aided Chemical Engineering; Vol. 48).

Research output: Chapter in Book/Conference proceeding › Conference contribution › Scientific › peer-review

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T1 - A Simulation Case Study for Bio-based Hydrogen Production from Hardwood Hemicellulose

AU - Tuppurainen, Ville

AU - Kangas, Jani

AU - Ahola, Juha

AU - Tanskanen, Juha

AU - Aho, Atte

AU - Grénman, Henrik

AU - Murzin, Dmitry Yu

AU - Salmi, Tapio

N1 - Conference code: 30

PY - 2020/1

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N2 - A novel bio-based hydrogen production process concept is simulated using Aspen Plus software. In the concept, hemicellulose is first extracted from birch wood using aqueous formic acid (FA). The dilute FA is then decomposed and used synergistically as a source of H2. The hemicellulose monosaccharides in the dilute aqueous hydrolysate are hydrogenated to their corresponding sugar alcohols, which are further processed to H2, various alkanes and carbon dioxide using aqueous phase reforming (APR). In addition to H2 and electricity, cellulose and lignin rich solid wood fraction is produced. However, the case study revealed high heating requirements of dilute aqueous hydrolysate stream to APR reaction temperatures. High degree of APR effluent recycling to the extraction stage is considered, resulting in a relatively high concentration of the required fresh FA stream in the process concept.

AB - A novel bio-based hydrogen production process concept is simulated using Aspen Plus software. In the concept, hemicellulose is first extracted from birch wood using aqueous formic acid (FA). The dilute FA is then decomposed and used synergistically as a source of H2. The hemicellulose monosaccharides in the dilute aqueous hydrolysate are hydrogenated to their corresponding sugar alcohols, which are further processed to H2, various alkanes and carbon dioxide using aqueous phase reforming (APR). In addition to H2 and electricity, cellulose and lignin rich solid wood fraction is produced. However, the case study revealed high heating requirements of dilute aqueous hydrolysate stream to APR reaction temperatures. High degree of APR effluent recycling to the extraction stage is considered, resulting in a relatively high concentration of the required fresh FA stream in the process concept.

KW - Aqueous Phase Reforming

KW - Bio-based Hydrogen

KW - Hemicellulose Extraction

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PB - Elsevier B.V.

T2 - 30th European Symposium on Computer Aided Process Engineering

Y2 - 24 May 2020 through 27 May 2020

ER -

A Simulation Case Study for Bio-based Hydrogen Production from Hardwood Hemicellulose

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Keywords

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