Abstract
The equilibrium profiles for [1,5]-silatropic shifts in a series of 1,3-/1,1-disilyl substituted indenes were studied by NMR and computational methods based on density functional theory. Both methods indicate higher activation parameters for the [1,5]-shifts than observed in monosilyl substituted indene analogues.
Original language | Undefined/Unknown |
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Pages (from-to) | 9417–9422 |
Number of pages | 6 |
Journal | Tetrahedron |
Volume | 62 |
Issue number | 40 |
DOIs | |
Publication status | Published - 2006 |
MoE publication type | A1 Journal article-refereed |