Kinetic modeling of gas phase synthesis of ethyl chloride from ethanol and HCl in fixed bed reactor

A1 Journal article (refereed)


Internal Authors/Editors


Publication Details

List of Authors: Natalia Bukhanko, Johan Wärnå, Ajaikumar Samikannu, Jyri-Pekka Mikkola
Publication year: 2016
Journal: Chemical Engineering Science
Volume number: 142
Start page: 310
End page: 317
eISSN: 1873-4405


Abstract

Kinetic modeling of gas-phase synthesis of ethyl chloride from ethanol and hydrochloric acid over high porous Al2O3 and 2 wt% ZnCl2/Al2O3 catalysts was studied in a continuous plug flow reactor in the temperature range of 200–325 °C. Two rival kinetic models were proposed that both describe the kinetics well. The kinetic parameters of the reaction were determined and activation energy values for ethyl chloride formation from ethyl alcohol and diethyl ether reactions were calculated.

Last updated on 2019-21-11 at 04:59