Dissolution of mineral fiber in a formic acid solution: kinetics, modeling, and gelation of the resulting sol

A1 Originalartikel i en vetenskaplig tidskrift (referentgranskad)


Interna författare/redaktörer


Publikationens författare: Henrik Grénman, Fernando Ramirez, Kari Eränen, Johan Wärnå, Tapio Salmi, Dmitry Yu. Murzin
Förläggare: American Chemical Society
Publiceringsår: 2008
Tidskrift: Industrial & Engineering Chemistry Research
Tidskriftsakronym: Ind. Eng. Chem. Res.
Volym: 47
Nummer: 24
Artikelns första sida, sidnummer: 9834
Artikelns sista sida, sidnummer: 9841
Antal sidor: 8
ISSN: 0888-5885
eISSN: 1520-5045


Abstrakt

A new inorganic adhesive based on sol-gel technology has been developed recently. The sol is produced by dissolving a mineral material, with silica as the major compound, in formic acid. In this work, the kinetics and mechanisms of the solid-liquid reaction of the amorphous mineral raw material with formic acid were studied. The effect of different variables, such as temperature, acid concentration, and fiber load, were examined. Moreover, the influence of various parameters on the gelation rate of the resulting sol was investigated at different temperatures. The dissolution of the mineral fiber was found to be strongly dependent on the temperature and fiber load, but moderately dependent on the acid concentration as the pH of the solution was buffered by the formic acid. The kinetic model developed for the dissolution process accurately describes the experimental results and can thus be used for design and optimization of the process. The gelation studies showed that the temperature and the amount dissolved are the variables most affecting the gelation time. The knowledge of the gelation kinetics is important when striving for a high dry solid content in the sol, while still avoiding premature gelation in production, transport, and storage.

Senast uppdaterad 2019-23-10 vid 02:49