Lignosulfonate-based macro/mesoporous solid protonic acids for acetalization of glycerol to bio-additives

A1 Originalartikel i en vetenskaplig tidskrift (referentgranskad)


Interna författare/redaktörer


Publikationens författare: Lakhya Jyoti Konwar, Ajaikumar Samikannu, Päivi Mäki-Arvela, Dan Boström, Jyri-Pekka Mikkola
Publiceringsår: 2018
Tidskrift: Applied Catalysis B: Environmental
Tidskriftsakronym: Appl. Catal., B
Volym: 220
Artikelns första sida, sidnummer: 314
Artikelns sista sida, sidnummer: 323
eISSN: 1873-3883


Abstrakt

The enclosed paper introduces a novel, scalable and environmentally benign process for making strongly acidic solid meso/macroporous carbon catalysts from Na-lignosulfonate (LS), a byproduct from sulfite pulping. Ice-templated LS was converted to strongly acidic macro/mesoporous solid protonic acids via mild pyrolysis (350–450 °C) and ion/H+ exchanging technique. The synthesized materials were extensively characterized by FT-IR, Raman, XRD, XPS, TGA, FE-SEM, TEM and N2-physisorption methods. These LS derived materials exhibited a macro/mesoporous and highly functionalized heteroatom doped (O, S) carbon structure with large amounts of surface OH, COOH and SO3H groups similar to the sulfonated carbon materials. Further, these carbon materials showed excellent potential as solid acid catalysts upon acetalization of glycerol with various bio-based aldehydes and ketones (acetone, methyl levulinate and furfural), easily outperforming the commercial acid exchange resins (Amberlite® IR120 and Amberlyst® 70). Most importantly, the optimum LS catalyst exhibiting a large specific surface area demonstrated exceptional potential for continuous solketal production (liquid phase atmospheric pressure operation) maintaining its activity (glycerol conversion ≥ 91%) and structural features even after 90 h time on stream.


Nyckelord

Chemical Engineering

Senast uppdaterad 2019-06-12 vid 03:36