Pd supported IRMOF-3: Heterogeneous, efficient and reusable catalyst for Heck reaction

A1 Originalartikel i en vetenskaplig tidskrift (referentgranskad)


Interna författare/redaktörer


Publikationens författare: Ayat Nuri, Nemanja Vucetic, Jan-Henrik Smått, Yagoub Mansoori, Jyri-Pekka Mikkola, Dmitry Yu Murzin
Förläggare: Springer
Publiceringsår: 2019
Tidskrift: Catalysis Letters
Tidskriftsakronym: Catal. Lett.
Volym: 149
Artikelns första sida, sidnummer: 1941
Artikelns sista sida, sidnummer: 1951
ISSN: 1572879X 1011372X
eISSN: 1572-879X


Abstrakt

IRMOF-3 with a high surface area prepared by a hydrothermal method was used for deposition of Pd(OAc)2 on IRMOF-3 particles. The final catalyst was characterized with FT-IR, nitrogen physisorption, thermogravimetry, scanning electron microscopy, transmission electron microscopy combined with energy dispersive X-ray analysis, wide angle X-ray diffraction spectroscopy and X-ray photoelectron spectroscopy. The prepared porous catalyst was effectively used in the Heck coupling reaction in the presence of an organic base. The reaction parameters such as the type of base, amounts of catalyst and solvents, temperature were optimized. The catalyst was then easily separated, washed, and reused 4 times without significant losses of catalytic activity.


Nyckelord

Heck reaction, IRMOF-3-Pd, Metal–organic-frameworks

Senast uppdaterad 2020-27-05 vid 04:28