Application of terpyridyl ligands to tune the optical and electrochemical properties of a conducting polymer

A1 Originalartikel i en vetenskaplig tidskrift (referentgranskad)


Interna författare/redaktörer


Publikationens författare: Grzegorz Lisak, Klaudia Wagner, Jonathan E. Barnsley, Andrei Veksha, Gregory Huff, Anastasia B. S. Elliott, Paweł
Wagner, Keith C. Gordon, Johan Bobacka, Gordon G. Wallace, Ari Ivaska, David L. Officer
Förläggare: ROYAL SOC CHEMISTRY
Publiceringsår: 2018
Tidskrift: RSC Advances
Tidskriftsakronym: RSC ADV
Volym: 8
Artikelns första sida, sidnummer: 29505
Artikelns sista sida, sidnummer: 29512
Antal sidor: 8
ISSN: 2046-2069


Abstrakt

We present a simple and effective way of using metal and metal-ligand modifications to tune the electrochemical and optical properties of conducting polymers. To that end, a polyterthiophene functionalized with terpyridine moieties was synthesized and then the resulting film's surface or bulk was modified with different metal ions, namely Fe2+, Zn2+ and Cu2+ and terpyridine. The modification of the terpyridine functionalized polyterthiophene film by Fe2+ increased the absorptivity and electrochemical capacitance of the conducting polymer, and improved its conjugation. Further modification by Zn2+ and Cu2+ resulted in dramatically different spectroelectrochemical properties of the film. Moreover, the influence of the solvents (ACN and 1:1 ACN:H2O) in conjunction with the metal ion applied for the modification was found crucial for the electrochemical and optical properties of the films.

Senast uppdaterad 2019-07-12 vid 02:50