Solubility of softwood hemicelluloses

A1 Originalartikel i en vetenskaplig tidskrift (referentgranskad)


Interna författare/redaktörer


Publikationens författare: Saina Kishani, Francisco Vilaplana, Wenyang Xu, Chunlin Xu, Lars Wågberg
Förläggare: American Chemistry Society
Publiceringsår: 2018
Tidskrift: Biomacromolecules
Tidskriftsakronym: Biomacromolecules
Volym: 19
Nummer: 4
Artikelns första sida, sidnummer: 1245
Artikelns sista sida, sidnummer: 1255
eISSN: 1526-4602


Abstrakt

It is demonstrated that the molecular solubility of softwood hemicelluloses is significantly influenced by pretreatment of the fibers, extraction, and downstream processing. To quantify these effects, four hemicellulose samples were extracted from different thermomechanical pulps of Norway spruce. The molecular solubility of the samples was characterized by size and molar mass distributions, and the morphology of the molecules was studied using high resolution microscopy techniques. All extracted samples were well dispersed in aqueous media creating transparent dispersions, but dynamic light scattering measurements showed that molecular solubility can only be achieved using specific pretreatments and extractions. The procedure yields acetylated galactoglucomannan (AcGGM)-rich hemicelluloses with an average molar mass of 21–35 kDa and a diameter up to 10 nm but also shows that water is a poor solvent for this sample since an association is detected as soon as the concentration is about 20 g/L. These associated hemicellulose dispersions are still absolutely clear on visual inspection, underlining the need for careful measurement when assessing the solubility of wood hemicelluloses.


Senast uppdaterad 2019-20-11 vid 05:06