Preparation of chiral indenes containing β-pinenyl derived ligand substituents

A1 Journal article (refereed)


Internal Authors/Editors


Publication Details

List of Authors: Silver S, Johansson E, Sjoholm R, Leino R
Publisher: PERGAMON-ELSEVIER SCIENCE LTD
Publication year: 2004
Journal: Tetrahedron Letters
Journal acronym: TETRAHEDRON LETT
Volume number: 45
Issue number: 2
Start page: 249
End page: 252
Number of pages: 4
ISSN: 0040-4039


Abstract

A simple procedure for the preparation of new 1-, 2- and 1,3-chirally substituted indenes is described in which indenyllithium or 2-indenylmagnesium bromide is reacted with a beta-pinenyl derived chlorosilane. Synthesis of the ethylene bridged bis(indene) analogues of two of the new compounds is also described. (C) 2003 Elsevier Ltd. All rights reserved.


Keywords

chirality, indene, indenyl, metallocenes

Last updated on 2020-25-02 at 04:58