Bis(triisopropylsiloxyindenyl)zirconocenes

A1 Journal article (refereed)


Internal Authors/Editors


Publication Details

List of Authors: Luttikhedde HJG, Leino R, Lehtonen A, Nasman JH
Publisher: ELSEVIER SCIENCE SA
Publication year: 1998
Journal: Journal of Organometallic Chemistry
Journal acronym: J ORGANOMET CHEM
Volume number: 555
Issue number: 1
Start page: 127
End page: 134
Number of pages: 8
ISSN: 0022-328X


Abstract

The synthesis and characterization of 1- and 2-triisopropylsiloxy substituted bis(indenyl) zirconocenes is reported. The molecular structures of rac-[ethylenebis(2-(triisopropylsiloxy)-1-indenyl)]zirconium dichloride (6) and rac-[ethylenebis(2-(triisopropylsiloxy)-4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride (8) have been determined and reveal that complex (6) crystallizes in the indenyl-forward (II) conformation while (8) adopts the indenyl-backward (Y) conformation. (C) 1998 Elsevier Science S.A. All rights reserved.


Keywords

ansa-zirconocene, indenyl, triisopropylsiloxy

Last updated on 2019-17-09 at 06:51