Heteroatom-substituted group 4 bis(indenyl)metallocenes

A1 Journal article (refereed)


Internal Authors/Editors


Publication Details

List of Authors: Leino R, Lehmus P, Lehtonen A
Publisher: WILEY-V C H VERLAG GMBH
Publication year: 2004
Journal: European Journal of Inorganic Chemistry
Journal acronym: EUR J INORG CHEM
Volume number: 2004
Issue number: 16
Start page: 3201
End page: 3222
Number of pages: 22
ISSN: 1434-1948


Abstract

The synthesis, characterization and applications of heteroatom-substituted group 4 bis(indenyl)metallocene complexes is reviewed. In recent years, an increasing number of group 4 metallocenes with electronically modified cyclopentadienyl ligands have been reported with, in some cases, considerably altered catalytic properties. This microreview focuses on bis(indenyl) complexes of titanium, zirconium and hafnium that contain nitrogen, oxygen and sulfur atoms directly bonded to the five- or six-membered rings of the indenyl ligand framework. The catalytic performance is briefly reviewed, with emphasis on catalytic olefin polymerization. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.


Keywords

indene, metallocenes, olefin polymerization, zirconium

Last updated on 2019-15-11 at 03:07